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CAS: 99-90-1
分子式: C8H7BrO
分子量: 199.04
沸点: 255 °C(lit.)
熔点: 108-110 °C(lit.)
中文名称: 
对溴乙酰苯
4-溴苯乙酮
对溴苯乙酮
4-溴代乙苯酰
4'-溴苯乙酮
英文名称: 
p-Bromoacetophenone
1-(4-bromophenyl)-Ethanone
1-(4-bromophenyl)-ethanon
1-Acetyl-4-bromobenzene
4-bromoacetophenone
Methyl p-bromophenyl ketone
4'-Bromoacetophenone
1-(4-Bromophenyl)ethanone
p-Bromophenyl methyl ketone
Ethanone,1-(4-bromophenyl)-
1-(4-Bromo-phenyl)-ethanone
展开更多英文名
性质描述: 白色片状结晶。熔点51℃,沸点255.5℃(97.9kPa),130℃(1.46kPa),117℃(0.93kPa)。溶于乙醇、乙醚、冰醋酸、苯、二硫化碳和石油醚,不溶于水。易随水蒸气挥发。
生产方法: 由溴苯与乙酐在三氯化铝存在下反应而得。将溴苯和干燥的二硫化碳加入反应器中,投入粉状的无水三氯化铝,加热至开始回流,停止加热,滴加乙酐,加完后再回流1h,蒸出二硫化碳,趁热将反应物倒入盐酸冰水混合液中,滤干,减压蒸馏即得成品。
用途: 有机合成中间体。用于染料、医药及试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802440MACKLIN4-溴苯乙酮98%28元/5g;   35元/25g;   66元/100g;   215元/500g;   1065元/2.5kg;   展开
储存:室温
状态:白色到灰白色粉末,晶体和/或块状
B0537TCI4'-Bromoacetophenone>98.0%(GC)270元/25G;   2405元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H7BrO = 199.05
外观与形状(20℃)固体
Reaxys-RN386015
PubChem物质ID87563558
SDBS (AIST Spectral DB)5919
Merck Index (14)1403
MDL编号MFCD00000105

技术规格

AppearanceWhite to Light yellow to Light orange powder to lump
Purity(GC)min. 98.0 %
Melting point50.0 to 54.0 ℃

物性(参考值)

熔点53 ℃
沸点256 ℃
溶解性(可溶于)醇,苯,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
234888J&K4'-Bromoacetophenone98%114元/25G;   362元/100G;   展开

基本信息

分子式C8H7BrO
分子量199.05
熔点49-51
沸点255
闪点113
密度1.5
MDL编码MFCD00000105
Beilstein386015
Merck14,1403
EINECS 编号202-799-3

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H334
H335
防范说明P261
P305+P351+P338
P342+P311
WGK3
TSCA
A12222Alfa Aesar4'-Bromoacetophenone98%511元/25g;   1347元/100g;   5701元/500g;   展开

应用
Labeled 4?’-Bromoacetophenone possess activity against positive phototaxis of Chlamydomonas cells. A fundamental starting material for organic synthesis.

备注
Store in cool, dry place in a tightly sealed container. Store away from oxidizing agent, bases.

基本信息

MDL
MFCD00000105

EINECS
202-799-3

分子式
C8H7BrO

分子量
199.05

熔点
49-53°

沸点
255-256°

闪点
>110°(230°F)

灵敏度
Ambient temperatures.

形态
Crystals

溶解性
Soluble in Chloroform. Insoluble in water.

Beilstein
386015

Merck
14,1403

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C10659Alfa Aesar4'-Bromoacetophenone98%589元/25g;   1143元/100g;   5466元/500g;   展开

基本信息

Ref#
10659

MDL
105

分子式
C8 H7 Br O

分子量
199.05

闪点
>100

形态
White to cream crystals

安全信息

危险等级
6.1

包装组
III

B56404Sigma-Aldrich4′-Bromoacetophenone98%282.97元/25 G;   721.28元/100 G;   展开

基本信息

线性分子式BrC6H4COCH3
分子量199.04
Beilstein386015
EC 号202-799-3
MDL编号MFCD00000105
PubChem化学物质编号24891845
NACRESNA.22

产品性质

质量水平100
测定98%
bp255 ℃ (lit.)
mp49-51 ℃ (lit.)
SMILES stringCC(=O)c1ccc(Br)cc1
InChI1S/C8H7BrO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3
InChI keyWYECURVXVYPVAT-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)212.0 °F
闪点(C)> 100 ℃
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
960869Amethyst4'-Bromoacetophenone98%, 用于合成89元/25G;   197元/100G;   568元/500G;   展开

基本信息

分子式C8H7BrO
分子量199.05
熔点49-51
沸点255
闪点113
MDL编码MFCD00000105
Beilstein386015
Merck14,1403
EINECS 编号202-799-3

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H334
H335
防范说明P261
P305+P351+P338
P342+P311
WGK3
TSCA
002964Fluorochem4'-Bromoacetophenone99%330元/100g;   1210元/500g;   展开

基本信息

CAS Number99-90-1
MDL NumberMFCD00000105
Boiling Point255-256℃
Melting Point48-54℃
Density1.647

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P285: In case of inadequate ventilation wear respiratory protection.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 + P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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