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CAS: 99-56-9
分子式: C6H7N3O2
分子量: 153.14
熔点: 196-201℃
中文名称: 
4-硝基-1,2-苯二胺
4-硝基邻苯二胺
英文名称: 
1,2-Benzenediamine,4-nitro-
1,2-benzenediamine,-nitro-
o-phenylenediamine,-nitro-
2-Benzenediamine, 4-nitro-1
4-nitro-o-phenylenediamin
4-nitro-2-benzenediamine
1,2-diamino-4-nitrobenzene
2-amino-4-nitroaniline
3,4-diaminonitrobenzene
4-n-o-pda
4-nitro-1,2-benzenediamine
4-nitro-1,2-diaminobenzene
4-nitro-1,2-fenylendiamin
4-nitro-1,2-phenylenediamine
4-nitro-o-phenylene-diamine
4-nitro-o-phenylenediamine
4-nitrobenzene-1,2-diamine
4-nitrophenylenediamine
4-no
4-nop
4-nopd
4ndb
c.i. 76020
ci 76020
nci-c03941
p-nitro-o-phenylenediamine
展开更多英文名
性质描述: 暗红色针状结晶。熔点201℃,溶于乙醇、丙酮及盐酸溶液,难溶于水。
生产方法: 将23.8g2,4-二硝基苯胺、240ml95%乙醇及120ml浓氨水的混合物加热到45℃,搅拌下通入硫化氢气体,维持在45-55℃反应。反应毕,冷却,析出4-硝基邻苯二胺。将过滤得到的粗品溶于盐酸,加活性炭脱色,趁热过滤,滤液用浓氨水中和,过滤,水洗,干燥,即得成品,收率52-58%。
用途: 用于合成α-酮酸;检测硒的试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N814755MACKLIN4-硝基邻苯二胺97%30元/5g;   41元/25g;   83元/100g;   329元/500g;   1588元/2.5kg;   展开
储存:室温
状态:橙色到红色到红棕色粉末或晶体
D0103TCI4-Nitro-1,2-phenylenediamine>97.0%(GC)(T)205元/25G;   500元/100G;   展开

基本信息

纯度/分析方法>97.0%(GC)(T)
分子式/分子量C6H7N3O2 = 153.14
外观与形状(20℃)固体
Reaxys-RN608106
PubChem物质ID87566843
SDBS (AIST Spectral DB)10068
Merck Index (14)6622
MDL编号MFCD00007724

技术规格

AppearanceYellow to Amber to Dark red powder to crystal
Purity(GC)min. 97.0 %
Purity(Nonaqueous Titration)min. 97.0 %

物性(参考值)

熔点201 ℃
水溶性实际上不溶
溶解性(可溶于)乙醇,丙酮,二甲基甲酰胺,氯仿,苯

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H317 : 可能造成皮肤过敏反应。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P272 : 受沾染的工作服不得带出工作场地。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#ST2975000
136703J&K4-Nitro-o-phenylenediamine98%85元/25G;   209元/100G;   795元/500G;   展开

基本信息

分子式C6H7N3O2
分子量153.14
熔点199-201
MDL编码MFCD00007724
Beilstein608106
Merck14,6623
EINECS 编号202-766-3

安全信息

图形或危害标志
提示语Warning
危险说明H302
H317
防范说明P280
WGK3
RTECSST2975000
TSCA
L04693Alfa Aesar4-Nitro-o-phenylenediamine97%1061元/100g;   3924元/500g;   展开

应用
4-Nitro-o-phenylenediamine is used to study the in vitro activation of 4-nitro-o-phenylenediamine into a potent mutagen in Salmonella typhimurium strain TA98

备注
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00007724

EINECS
202-766-3

分子式
C6H7N3O2

分子量
153.14

熔点
199-203°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in water (1.2 g/L at 20°C).

Beilstein
608106

Merck
14,6623

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H317
Harmful if swallowed.May cause an allergic skin reaction.

Precautionary Statements
P261-P280g-P301+P312a-P321-P333+P313-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves.Wear protective gloves.Specific treatment (see label).If skin irritation or rash occurs: Get medical advice/attention.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-43
Harmful if swallowed.May cause sensitization by skin contact.

安全等级
24-37-60
Avoid contact with skin.Avoid contact with skin.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
ST2975000

TSCA

C14884Alfa Aesar4-Nitro-o-phenylenediamine98%2288元/100g;   10782元/500g;   展开

基本信息

Ref#
14884

MDL
7724

分子式
C6 H7 N3 O2

分子量
153.14

形态
Red powder

108898Sigma-Aldrich4-Nitro-o-phenylenediamine98%458.35元/5 G;   881.35元/100 G;   展开

产品说明

应用

4-硝基邻苯二胺被用于研究 体外 活化 4-硝基邻苯二胺为 鼠伤寒沙门氏菌 菌株 TA98 的有效诱变剂 。

包装

5, 100 g in glass bottle

生化/生理作用

4-硝基邻苯二胺是一种直接作用的诱变剂 。

基本信息

线性分子式O2NC6H3(NH2)2
分子量153.14
Beilstein608106
EC 号202-766-3
MDL编号MFCD00007724
eCl@ss39030501
PubChem化学物质编号24846835
NACRESNA.22

产品性质

质量水平100
测定98%
mp199-201 ℃ (lit.)
溶解性1 N HCl: ethanol, 1:1: soluble 50 mg/mL
SMILES stringNc1ccc(cc1N)[N+]([O-])=O
InChI1S/C6H7N3O2/c7-5-2-1-4(9(10)11)3-6(5)8/h1-3H,7-8H2
InChI keyRAUWPNXIALNKQM-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P280 - P301 + P312 + P330 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
077317Fluorochem4-Nitro-o-phenylenediamine95%220元/1g;   286元/25g;   572元/100g;   展开

基本信息

CAS Number99-56-9
MDL NumberMFCD00007724

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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