[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 99-55-8
关键词:       仅模糊查询
CAS: 99-55-8
分子式: C7H8N2O2
分子量: 152.15
熔点: 103-106 °C(lit.)
中文名称: 
大红色基G
大红贝司
旗红贝司
2-氨基-4-硝基甲苯
5-硝基邻甲苯胺
2-甲基-5-硝基苯胺
旗红色基G
大红色基
5-硝基-2-甲苯胺
对硝基邻氨基甲苯
英文名称: 
Scarlet base G
Fast scarlet base
C.I. Azoic diazo component 12
5-nitro-o-toluidin
1-amino-2-methyl-5-nitrobenzene
2-amino-4-nitrotoluene
2-methyl-5-nitro-benzeneamine
2-methyl-5-nitroaniline
2-amino-4-nitro-toluene
2-methyl-5-nitrobenzenamine
3-nitro-6-methylaniline
4-nitro-2-aminotoluene
5-nitro-2-methylaniline
5-nitro-2-toluidine
5-nitro-o-toluidine
6-methyl-3-nitroaniline
amarthol fast scarlet g base
amarthol fast scarlet g salt
azoene fast scarlet gc base
azoene fast scarlet gc salt
azofix scarlet g salt
azogene fast scarlet g
azoic diazo component 12
2-methyl-5-nitro-benzenamin
c.i. 37105
dainichi fast scarlet g base
daito scarlet base g
devol scarlet b
devol scarlet g salt
diabase scarlet g
diazo fast scarlet g
fast red sg base
fast scarlet base g
fast scarlet base j
fast scarlet g
fast scarlet g base
fast scarlet g salt
fast scarlet gc base
fast scarlet j salt
fast scarlet m4nt base
fast scarlet t base
hiltonil fast scarlet g base
hiltonil fast scarlet g salt
hiltonil fast scarlet gc base
kayaku scarlet g base
lake scarlet g base
lithosol orange r base
methyl-2 nitro-5 aniline
mitsui scarlet g base
naphthanil scarlet g base
naphtoelan fast scarlet g base
naphtoelan fast scarlet g salt
nci-c01843
nitro-5 o-toluidine
nitrotoluidine (non-specific name)
pnot
rcra waste number u181
scarlet base ciba ii
scarlet base irga ii
scarlet base nsp
scarlet g base
sugai fast scarlet g base
symulon scarlet g base
展开更多英文名
性质描述: 黄色棱形结晶。熔点107℃。溶于醇、醚和丙酮,微溶于水。
生产方法: 采用邻甲苯胺为原料,经成盐、硝化、水析、溶解脱色、中和及脱水干燥而得。将相对密度为1.4的硝酸冷至20℃以下,在搅拌下加入干粉状的邻甲基乙酰苯胺,温度控制在70℃以下,冷却得黄色固体。将其加入硫酸回流,2h后冷却滤去不溶物,在40℃以下用40%氢氧化钠中和至pH=1-2,得黄色结晶。过滤、水洗,用乙醇重结晶即得5-硝基邻甲苯胺。原料消耗定额:邻甲苯胺876kg/t、硫酸(100%)4350kg/t、硝酸(98%)520kg/t、纯碱(98%)1700kg/t、活性炭1kg/t。
用途: 该品是坚固大红等染料的中间体。主要用作棉织物的染色和印花的显色剂(最主要用于染大红色布,即旗红布),也可用于丝绸和锦纶织物的染色。还可作有机颜料的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A794536MACKLIN2-氨基-4-硝基甲苯标准溶液1000μg/ml, in Purge and Trap Methanol1586元/1ml;   展开
储存:室温
A800357MACKLIN2-氨基-4-硝基甲苯98%29元/25g;   49元/100g;   140元/500g;   615元/2.5kg;   展开
储存:2~8°C
状态:黄色到金色到橙色粉末
N0115TCI2-Methyl-5-nitroaniline>98.0%(GC)(T)320元/25G;   3785元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C7H8N2O2 = 152.15
外观与形状(20℃)固体
Reaxys-RN879021
PubChem物质ID87573503
SDBS (AIST Spectral DB)1642
MDL编号MFCD00007741

技术规格

AppearanceWhite to Yellow to Orange powder to crystal
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point107.0 to 111.0 ℃

物性(参考值)

熔点109 ℃
溶解性(可溶于)乙醚,丙酮,苯,醇,氯仿

安全信息

图形或危害标志
信号词危险
危险性说明H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P311 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#XU8225000

运输信息

UN编号UN2660
类别6.1
包装类别 III
监管条件代码(*)
273296J&K2-Methyl-5-nitroaniline99%109元/25G;   359元/100G;   1430元/500G;   展开

基本信息

分子式C7H8N2O2
分子量152.15
熔点103-106
MDL编码MFCD00007741
Beilstein879021
EINECS 编号202-765-8

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H331
H351
H412
防范说明P261
P273
P280
P301+P310
P311
UN号码2660
危险分类6.1
包装等级III
WGK3
A17726Alfa Aesar2-Methyl-5-nitroaniline98+%893元/100g;   3789元/500g;   13330元/2500g;   展开

应用
It is applied in organic synthesis. 5-Nitro-o-toluidine finds application as an intermediate in the synthesis of Pigment Red 17 (C.I. 12 390) and Pigment Red 22 (C.I. 12 315). It is also employed in conjunction with certain C.I. coupling components. It also serves as a precursor for a wide assortment of azo dyes of various red, yellow, orange, violet, and brown hues. It can also be employed as analytical standard for the surfactant mediated transformations (-254nm) of 2,4-dinitrotoluene.

备注
C.I. 37105. Sensitive to moisture and light. Store away from oxidizing agents and bases. Keep the container tightly closed in a cool, dry place.

基本信息

MDL
MFCD00007741

EINECS
202-765-8

分子式
C7H8N2O2

分子量
152.15

熔点
105-108°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Insoluble in water. (<0.1 g/100 mL at 19°C). Solubility in methanol, almost transparency

Beilstein
879021

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H331-H351-H402-H412
Toxic if swallowed.Toxic in contact with skin.Toxic if inhaled.Suspected of causing cancer.Harmful to aquatic life.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P273-P280h-P309-P310-P302+P352
Avoid release to the environment.Wear protective gloves/clothing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.IF ON SKIN: Wash with plenty of soap and water.

安全信息

危险等级
6.1

包装组
III

危险类别
23/24/25-40-52/53
Toxic by inhalation, in contact with skin and if swallowed.Limited evidence of a carcinogenic effect.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
36/37-45-61
Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

RTECS
XU8225000

TSCA

M59386Sigma-Aldrich2-Methyl-5-nitroaniline98%547.13元/100 G;   展开

基本信息

线性分子式CH3C6H3(NO2)NH2
分子量152.15
Beilstein879021
EC 号202-765-8
MDL编号MFCD00007741
PubChem化学物质编号24897058
NACRESNA.22

产品性质

质量水平100
测定98%
mp103-106 ℃ (lit.)
SMILES stringCc1ccc(cc1N)[N+]([O-])=O
InChI1S/C7H8N2O2/c1-5-2-3-6(9(10)11)4-7(5)8/h2-4H,8H2,1H3
InChI keyDSBIJCMXAIKKKI-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08
警示用语:Danger
危险声明H301 + H311 + H331 - H351 - H412
预防措施声明P201 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
APP-9-156AccuStandard5-Nitro-o-toluidine ,100 μg/mL in Dichloromethane100 μg/mL in Dichloromethane309元/1mL;   展开
5-Nitro-o-toluidine2-甲基-5-硝基苯胺99-55-8100 µg/mL
AS-E0344AccuStandard5-Nitro-o-toluidine ,5.0 mg/mL in MeOH5.0 mg/mL in MeOH494元/1mL;   展开
5-Nitro-o-toluidine2-甲基-5-硝基苯胺99-55-85 mg/mL
RAC-03AccuStandard2-Amino-4-nitrotoluene,100 μg/mL in AcCN100 μg/mL in AcCN386元/1mL;   展开
2-Amino-4-nitrotoluene2-甲基-5-硝基苯胺99-55-8100 µg/mL
RAC-03-EA-0.1X-10MLAccuStandard2-Amino-4-nitrotoluene,10 μg/mL in Ethyl acetate10 μg/mL in Ethyl acetate309元/10mL;   展开
2-Amino-4-nitrotoluene2-甲基-5-硝基苯胺99-55-810 µg/mL
RAC-03-10XAccuStandard2-Amino-4-nitrotoluene,1000 μg/mL in AcCN1000 μg/mL in AcCN541元/1mL;   展开
2-Amino-4-nitrotoluene2-甲基-5-硝基苯胺99-55-8100 µg/mL
038255Fluorochem2-Methyl-5-nitroaniline95%264元/25g;   594元/100g;   2640元/500g;   展开

基本信息

CAS Number99-55-8
MDL NumberMFCD00007741
Melting Point>107 - <108℃
Density1

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
H351: Suspected of causing cancer ..
H412: Harmful to aquatic life with long lasting effects.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9