[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 99-11-6
关键词:       仅模糊查询
CAS: 99-11-6
分子式: C6H5NO4
分子量: 155.1098
熔点: 300℃
中文名称: 
2,6-二羟基异烟酸
柠嗪酸
2,6-二羟基吡啶-4-羧酸
二缩一酰胺柠檬酸
二羟氮苯甲酸
二缩-酰胺柠檬酸
2,6-二羟基-4-吡啶羧酸
英文名称: 
citrazinic acfd
Citrazinnic Acid
Citrazinic acid
1,2-Dihydro-6-hydroxy-2-oxo-4-pyridinecarboxylic acid
2,6-dihydroxy-4-Pyridinecarboxylic acid
2,6-Dihydroxy-4-Pyridinecarboxylic acid
2,6-dihydroxy-isonicotinic aci
2,6-dihydroxy-4-carboxypyridine
2,6-dihydroxyisonicotinic acid
1,2-dihydro-6-hydroxy-2-oxo-4-pyridinecarboxylic aci
1,2-dihydro-6-hydroxy-2-oxo-isonicotinic aci
kyselina citrazinova
2,6-Dihydroxypyridine-4-carboxylic acid
4-Pyridinecarboxylic acid,2,6-dihydroxy-
展开更多英文名
性质描述: 淡黄色针状结晶或粉末,300℃以上炭化但不熔化。可溶于氢氧化钠或碳酸钠溶液,放置后转为蓝色,微溶于盐酸盐,几乎不溶于冷水。见光或露置空气中颜色逐渐变深。
生产方法: 由柠檬酸经酯化、氨解、闭环而得。酯化反应在硫酸存在下进行,经48h脱水后,回收溶剂和乙醇,残留物经水洗、碱洗、水洗至pH为6,得柠檬酸三乙酯粗品。加入氨水,通氨至饱和。放置以后,再通氨饱和,每天饱和一次,共三次,滤出结晶,将所得柠檬酸三甲酸胺于硫酸存在下120℃左右保温3h,慢慢倒入蒸馏水中,得粗品,再用酸碱精制而得柠嗪酸。采用柠檬酸三甲酯的制备方法大致与上述过程相同。在柠檬酸三甲酯中加入氨水,于室温放置约48h,浓缩后,加75%硫酸,放置12h,于130℃加热10min,用水稀释,过滤沉淀物即得粗品。将粗品溶于氨水,加盐酸即得沉淀,过滤,水洗,干燥。收率为69%。
用途: 用于药物、染料和彩色胶片成色剂的合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C805088MACKLIN柠嗪酸97%(T)110元/25g;   380元/100g;   1725元/500g;   展开
储存:室温
状态:黄色到橙色到棕色粉末或晶体
C0571TCICitrazinic Acid>96.0%(T)150元/25G;   2190元/500G;   展开

基本信息

纯度/分析方法>96.0%(T)
分子式/分子量C6H5NO4 = 155.11
外观与形状(20℃)固体
Reaxys-RN383736
PubChem物质ID87565673
SDBS (AIST Spectral DB)4496
Merck Index (14)2325
MDL编号MFCD00006274

技术规格

AppearanceWhite to Amber to Dark green powder to crystal
Purity(HPLC)min. 93.0 area%
Purity(Neutralization titration)min. 96.0 %

物性(参考值)

水溶性不溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#NS1400000
C16701Alfa AesarCitrazinic Acid98%889元/100g;   展开

基本信息

Ref#
16701

MDL
6274

分子式
C6 H5 N O4

分子量
155.11

形态
Pale yellow to brown powder

153281Sigma-Aldrich2,6-Dihydroxypyridine-4-carboxylic Acid97%283.58元/25 G;   696.84元/100 G;   展开

产品说明

应用

2,6-Dihydroxypyridine-4-carboxylic acid (citrazinic acid) was used to prepare 2,6-dibromo-4-(hexoxymethyl)pyridine. It was also used to synthesize the derivatives of oxazinones and pyrimidinones.

包装

25, 100 g in glass bottle

基本信息

经验(实验)分子式C6H5NO4
分子量155.11
Beilstein383736
EC 号202-731-2
MDL编号MFCD00006274
PubChem化学物质编号24849298
NACRESNA.22

产品性质

质量水平100
测定97%
mp>300 ℃ (lit.)
SMILES stringOC(=O)c1cc(O)nc(O)c1
InChI1S/C6H5NO4/c8-4-1-3(6(10)11)2-5(9)7-4/h1-2H,(H,10,11)(H2,7,8,9)
InChI keyCSGQJHQYWJLPKY-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
056519Fluorochem6-Hydroxy-2-oxo-1,2-dihydro-pyridine-4-carboxylic acid95%220元/10g;   374元/25g;   1034元/100g;   展开

基本信息

CAS Number99-11-6
MDL NumberMFCD00134947
Melting Point>300℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9