| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| B820173 | MACKLIN | 叔丁基 2,2,2-三氯乙酰亚胺酯 | 97% | 27元/1g; 30元/5g; 140元/25g; 550元/100g; 2300元/500g; | 咨询 |
储存：2~8°C 状态：无色到淡黄色液体或固体 折射率：n20/D 1.456(lit.) |
| B1496 | TCI | tert-Butyl 2,2,2-Trichloroacetimidate | >95.0%(GC) | 490元/5ML; 1450元/25ML; | 咨询 |
基本信息 | 纯度/分析方法 | >95.0%(GC) | | 分子式/分子量 | C6H10Cl3NO = 218.50 | | 外观与形状(20℃) | 液体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (分解),加热 | | Reaxys-RN | 1770049 | | PubChem物质ID | 87564409 | | SDBS (AIST Spectral DB) | 50517 | | MDL编号 | MFCD00077410 |
技术规格 | Appearance | Colorless to Almost colorless clear liquid | | Purity(GC) | min. 95.0 % |
物性(参考值) | 熔点 | 20 ℃ | | 沸点 | 69 ℃/12 mmHg | | 闪点 | 55 ℃ | | 比重 | 1.22 | | 折射率 | 1.46 |
安全信息 | 图形或危害标志 |   | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。
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运输信息 | UN编号 | UN1993 | | 类别 | 3 | | 包装类别 | III | | 监管条件代码(*) | |
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| 462967 | J&K | tert-Butyl 2,2,2-Trichloroacetimidate | 97% | 61元/1G; 101元/5G; 304元/25G; | 咨询 |
基本信息 | 分子式 | C6H10Cl3NO | | 分子量 | 218.51 | | 熔点 | 21 | | 沸点 | 65 | | 闪点 | 55 | | 密度 | 1.221 | | 折光率(n20D) | 1.4560 | | MDL编码 | MFCD00077410 | | Beilstein | 1770049 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H226
H302
H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | UN号码 | 1993 | | 危险分类 | 3 | | 包装等级 | III | | WGK | 3 |
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| B22039 | Alfa Aesar | tert-Butyl 2,2,2-Trichloroacetimidate | 97% | 446元/1g; 1145元/5g; 4134元/25g; | 咨询 |
应用
tert-Butyl 2,2,2-trichloroacetimidate is used to produce di-tert-butyl peroxide at temperature of -5?°C. It may be used in the synthesis of N-α-Fmoc-phospho(1-nitrophenylethyl-2-cyanoethyl)-L-serine, caged building block. It may be used in the conversion of alcohols and carboxylic acids to their respective ethers and esters. 备注
Moisture sensitive. Store away from strong oxidizing agents, heat, water/ moisture. 基本信息 MDL
MFCD00077410 EINECS
000-000-0 分子式
C6H10Cl3NO 分子量
218.51 熔点
20-22° 沸点
64-66°/15mm 闪点
55°(131°F) 密度
1.222 折射率
1.4570 灵敏度
Keep Cold. Moisture Sensitive. 形态
Liquid 溶解性
Soluble in organic solvents, cyclo hexane. Beilstein
1770049 GHS危害和防范说明 GHS符号
Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
3 包装组
III 危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| C36933 | Alfa Aesar | tert-Butyl 2,2,2-Trichloroacetimidate | 95% | 851元/5g; 3375元/25g; 11642元/100g; | 咨询 |
基本信息 Ref#
36933 MDL
77410 分子式
C6 H10 Cl3 N O 分子量
218.51 闪点
55 密度
1222 安全信息 危险等级
3 包装组
III |
| 91077 | Sigma-Aldrich | tert-Butyl 2,2,2-trichloroacetimidate | purum, ≥97.0% (GC) | 566.31元/5 ML; | 咨询 |
产品说明 其他说明 用于由酸和醇分别经平稳选择性反应制备叔丁酯和醚的试剂 基本信息 | 线性分子式 | CCl3C(=NH)OC(CH3)3 | | 分子量 | 218.51 | | Beilstein | 1770049 | | MDL编号 | MFCD00077410 | | PubChem化学物质编号 | 329769997 |
产品性质 | 质量水平 | 200 | | 等级 | purum | | 测定 | ≥97.0% (GC) | | 折射率 | n20/D 1.456 (lit.)
n20/D 1.457 | | bp | 65 ℃/11 mmHg (lit.) | | mp | 21 ℃ (lit.) | | 密度 | 1.221 g/mL at 25 ℃ (lit.) | | 储存温度 | 2-8℃ | | SMILES string | CC(C)(C)OC(=N)C(Cl)(Cl)Cl | | InChI | 1S/C6H10Cl3NO/c1-5(2,3)11-4(10)6(7,8)9/h10H,1-3H3 | | InChI key | CQXDYHPBXDZWBA-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H226 - H302 - H315 - H319 - H335 | | 预防措施声明 | P210 - P233 - P240 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 | | 危险分类 | Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 3 - Flammable liquids | | WGK | WGK 3 | | 闪点(F) | 131.0 °F - closed cup | | 闪点(C) | 55 ℃ - closed cup | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
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| 940120 | Amethyst | tert-Butyl 2,2,2-Trichloroacetimidate | 97%, 用于合成 | 57元/1G; 95元/5G; 286元/25G; 728元/100G; | 咨询 |
基本信息 | 分子式 | C6H10Cl3NO | | 分子量 | 218.51 | | 熔点 | 21 | | 沸点 | 65 | | 闪点 | 55 | | 密度 | 1.221 | | 折光率(n20D) | 1.4560 | | MDL编码 | MFCD00077410 | | Beilstein | 1770049 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H226
H302
H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | UN号码 | 1993 | | 危险分类 | 3 | | 包装等级 | III | | WGK | 3 |
|
| 013128 | Fluorochem | tert-Butyl-2,2,2-trichloroacetimidate | 97% | 330元/5g; 858元/25g; 2948元/100g; | 咨询 |
基本信息 | CAS Number | 98946-18-0 | | MDL Number | MFCD00077410 | | Boiling Point | 183.3℃ | | Melting Point | 21℃ | | Density | 1.22 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
| | 防范说明 | P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use CO2, dry powder or foam for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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