| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| M813011 | MACKLIN | 4-甲硫基苯硼酸 | 97% | 30元/1g; 86元/5g; 410元/25g; | 展开 |
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| M1458 | TCI | 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride) | | 160元/1G; 665元/5G; | 展开 |
基本信息 | 分子式/分子量 | C7H9BO2S = 168.02 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 3247219 | | PubChem物质ID | 87573401 | | MDL编号 | MFCD00093410 |
技术规格 | Appearance | White to Orange to Green powder to crystal | | Purity(Neutralization titration) | 98.0 to 112.0 % |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 271311 | J&K | 4-(Methylthio)phenylboronic acid | 98% | 119元/1G; 476元/5G; 1210元/25G; | 展开 |
基本信息 | 分子式 | C7H9BO2S | | 分子量 | 168.02 | | 熔点 | 210-214 | | MDL编码 | MFCD00093410 | | Beilstein | 3247219 |
安全信息 |
| 05-1010 | Strem | 4-(Methylthiophenyl)boronic acid | min. 97% | 472元/1g; 1571元/5g; | 展开 |
Technical Notes: 1. Convenient catalyst for the enantios elective borane reduction of ketones at ambient temperatures. 2.Asymmetric synthesis of a-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphos phines. 3.Nickel- catalyzed cros s-couplings of benzylic pivalates with arylboroxines: Stereos pecific formation of diarylalkanes andtriarylmethanes. 4. Enantioselective reduction of prochiral ketones with NaBH./MeSOa/(S)-Me -CBS. References: 1. Org. Lett, 2014, 16, 5830. 2.J. Am. Chem. Soc., 2013, 135, 3307. 3.Synthetic Commun., 2014, 44, 151 5. |
| B23454 | Alfa Aesar | 4-(Methylthio)benzeneboronic acid | 97% | 807元/1g; 2841元/5g; 11253元/25g; | 展开 |
基本信息 MDL
MFCD00093410 分子式
C7H9BO2S 分子量
168.02 熔点
ca 208-212° 形态
Crystalline powder Beilstein
3247219 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| 456802 | Sigma-Aldrich | 4-(Methylthio)phenylboronic acid | ≥95% | 618.53元/5 G; | 展开 |
产品说明 应用 Reactant involved in: - Suzuki-Miyaura cross coupling reactions with 2-aryl-1-bromo-1-nitroethenes or alkynyl bromides
- Addition reactions with naphthyridine N-oxides
- Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives
- Sulfoxidation reactions
- Copper-catalyzed halogenation
包装 1, 5, 25 g in glass bottle 其他说明 含不定量的酸酐 基本信息 | 线性分子式 | CH3SC6H4B(OH)2 | | 分子量 | 168.02 | | Beilstein | 3247219 | | MDL编号 | MFCD00093410 | | PubChem化学物质编号 | 24869239 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | ≥95% | | 形式 | powder | | 杂质 | <15% anhydride | | mp | 210-214 ℃ (lit.) | | SMILES string | CSc1ccc(cc1)B(O)O | | InChI | 1S/C7H9BO2S/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5,9-10H,1H3 | | InChI key | IVUHTLFKBDDICS-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 011008 | Fluorochem | 4-(Methylthio)benzeneboronic acid | 97% | 220元/1g; 506元/5g; 990元/25g; 2684元/100g; | 展开 |
基本信息 | CAS Number | 98546-51-1 | | MDL Number | MFCD00093410 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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