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CAS: 98-03-3
分子式: C5H4OS
分子量: 112.15
沸点: 198℃
中文名称: 
2-噻吩甲醛
2-噻吩醛
2-噻吩基甲醛
噻酚-2-甲醛
噻吩-2-甲醛
英文名称: 
2-Thiophenecarboxaldehyde
2-formylthiophene
2-thienaldehyde
2-thienylaldehyde
2-thienylcarboxaldehyde
2-thiophenealdehyde
alpha-formylthiophene
alpha-thiophenecarboxaldehyde
thiophene-2-carbaldehyde
2-Thiophenecarbaldehyde
Thiophen-2-aldehyd
Thenaldehyde
Thiophene-2-carboxaldehyde
2-Thiophenaldehyde
2-thiophenaldeyde(stabilized with hq)
2-thiophene carboxaldehyde
Thiphene-2-aldehyde
2-Thienal
展开更多英文名
性质描述: 油状液体。沸点198℃,93-94℃(2.67kPa),44-45℃(0.133kPa),相对密度1.215(21/21),折光率1.5920,闪点77℃。易溶于醇、苯、醚,微溶于水。有类似杏仁味。
生产方法: 由噻吩与二甲基甲酰胺在三氯氧磷存在下缩合,经水解、中和、精制而得。将噻吩和二甲基甲酰胺加入反应锅中,在15℃以下缓缓加入三氯氧磷,逐渐升温至80-90℃,保温3h后,冷却至30℃,加入冰水水解。再经30%氧氧化钠中和,静置分层,水层用四氯化碳提取,提取液经洗涤脱水、回收溶剂、减压蒸馏,得2-噻吩吩醛。
用途: 用来在有机化合物中引入噻吩基团,例如,将噻吩基团引入二甲基四氢嘧啶。所得产物与双羟萘酸成盐即得制广谱驱虫药噻嘧啶。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819150MACKLIN2-噻吩甲醛98%33元/25ml;   64元/100ml;   270元/500ml;   1300元/2.5L;   展开
储存:2~8°C
状态:无色到黄色或棕色液体
T0725TCI2-Thiophenecarboxaldehyde (stabilized with HQ)>98.0%(GC)140元/25ML;   380元/100ML;   1250元/500ML;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C5H4OS = 112.15
外观与形状(20℃)液体
储存温度0-10℃
应避免的情况加热
Reaxys-RN105819
PubChem物质ID87576586
SDBS (AIST Spectral DB)4170
MDL编号MFCD00005429

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点198 ℃
闪点78 ℃
比重1.23
折射率1.59
水溶性可溶
溶解性(可溶于)乙醚
溶解性(不溶于)乙醇

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#XM8135000
124605J&K2-Thiophenecarboxaldehyde98%72元/25G;   124元/100G;   464元/500G;   展开

基本信息

分子式C5H4OS
分子量112.15
熔点<10
沸点196-198
闪点78
密度1.22
折光率(n20D)1.5910
MDL编码MFCD00005429
Beilstein105819
EINECS 编号202-629-8
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSXM8135000
TSCA
A14344Alfa AesarThiophene-2-carboxaldehyde98+%588元/100g;   2791元/500g;   5097元/1000g;   展开

应用
Thiophene-2-carboxaldehyde is used in the preparation of beta-aryl-beta-amino acids and urea derivatives. It acts as an arylation reagent. Further, it is used in the synthesis of unsaturated ketones, which serve as antiviral and cytotoxic agents. In addition to this, it is used as an intermediate to manufacture pharmaceuticals and aromatic compounds.

备注
Store in a cool place. Incompatible with strong bases, strong oxidizing agents and strong reducing agents.

基本信息

MDL
MFCD00005429

EINECS
202-629-8

分子式
C5H4OS

分子量
112.15

沸点
196-198°

闪点
78°(172°F)

密度
1.220

折射率
1.5910

灵敏度
Keep Cold. Air Sensitive.

形态
Liquid

溶解性
Miscible with chloroform, alcohol, ether, dimethylsulfoxide, ethyl acetate and most organic solvents. Immiscible with water.

Beilstein
105819

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H319
Combustible liquid.Harmful if swallowed.Causes serious eye irritation.

Precautionary Statements
P210e-P280a-P305+P351+P338-P301+P312a-P403+P235-P501a
Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store in a well-ventilated place. Keep cool.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36
Harmful if swallowed.Irritating to eyes.

安全等级
26-36
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing.

欧盟危险品标志

RTECS
XM8135000

TSCA

T32409Sigma-Aldrich2-Thiophenecarboxaldehyde98%294.34元/25 G;   405.04元/100 G;   展开

基本信息

经验(实验)分子式C5H4OS
分子量112.15
Beilstein105819
EC 号202-629-8
MDL编号MFCD00005429
PubChem化学物质编号24900117
NACRESNA.22

产品性质

质量水平200
测定98%
折射率n20/D 1.591 (lit.)
bp198 ℃ (lit.)
75-77 ℃/11 mmHg (lit.)
密度1.2 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES string[H]C(=O)c1cccs1
InChI1S/C5H4OS/c6-4-5-2-1-3-7-5/h1-4H
InChI keyCNUDBTRUORMMPA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)170.6 °F - closed cup
闪点(C)77 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
PHR2083SupelcoPyrantel Impurity CPharmaceutical Secondary Standard; Certified Reference Material5369.15元/50 MG;   展开

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards

分析说明

These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAB9058 in the Documents slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

经验(实验)分子式C5H4OS
分子量112.15
Beilstein105819
MDL编号MFCD00005429
NACRESNA.24

产品性质

等级certified reference material
pharmaceutical secondary standard
形式liquid
CofAcurrent certificate can be downloaded
包装pkg of 50 mg
折射率n20/D 1.591 (lit.)
bp198 ℃ (lit.)
75-77 ℃/11 mmHg (lit.)
密度1.2 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES string[H]C(=O)c1cccs1
InChI1S/C5H4OS/c6-4-5-2-1-3-7-5/h1-4H
InChI keyCNUDBTRUORMMPA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P264 - P270 - P301 + P312 + P330 - P501
危险分类Acute Tox. 4 Oral
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
Y0002158Pyrantel Impurity CCRS, European Pharmacopoeia (EP) Reference Standard1523.69元/ ;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

包装

Unit quantity: 30 mg. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

其他说明

Sales restrictions may apply.

基本信息

经验(实验)分子式C5H4OS
分子量112.15
Beilstein105819
MDL编号MFCD00005429

产品性质

manufacturer/tradenameEDQM
折射率n20/D 1.591 (lit.)
bp198 ℃ (lit.)
75-77 ℃/11 mmHg (lit.)
密度1.2 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES string[H]C(=O)c1cccs1
InChI1S/C5H4OS/c6-4-5-2-1-3-7-5/h1-4H
InChI keyCNUDBTRUORMMPA-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)170.6 °F - closed cup
闪点(C)77 ℃ - closed cup
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