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CAS: 97239-80-0
分子式: C22H36FeP2
分子量: 418.32
熔点: 50-52 °C(lit.)
英文名称: 
1,1'-bis(diisopropylphosphino)ferrocene
Bis[(diisopropylphosphino)cyclopentadienyl]iron
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B803056MACKLIN1,1'-双(二异丙基膦)二茂铁98%30元/250mg;   80元/1g;   321元/5g;   1502元/25g;   5888元/100g;   展开
储存:室温
状态:橙色到棕色粉末或晶体
B2710TCI1,1'-Bis(diisopropylphosphino)ferrocene>98.0%(T)320元/100MG;   1415元/1G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C22H36FeP2 = 418.32
外观与形状(20℃)固体
PubChem物质ID87558606

技术规格

AppearanceOrange to Amber to Dark red powder to crystal
Purity(Chelometric Titration)min. 98.0 %
Melting point48.0 to 52.0 ℃

物性(参考值)

熔点50 ℃
107328J&K1,1'-Bis(diisopropylphosphino)ferrocene98%135元/100mg;   542元/500mg;   展开

基本信息

分子式C22H36FeP2
分子量418.32
熔点50-52
闪点110
MDL编码MFCD02684559

安全信息

WGK3
26-0275Strem1,1'-Bis(di-i-propylphosphino)ferrocenemin. 98%765元/500mg;   2295元/2g;   9180元/10g;   展开

Technical Notes:

1. Ruthenium- catalyzed hydrohydroxyalkylation of 1, 1-disubstituted allenes

2. Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of co.

3. Pd-catalyzed carbonylative a-arylation of ketones with aryl iodides

4. Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters

5. Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation

578266Sigma-Aldrich1,1′-Bis(diisopropylphosphino)ferrocene97%1527.78元/500 MG;   展开

基本信息

经验(实验)分子式C22H36FeP2
分子量418.31
MDL编号MFCD02684559
PubChem化学物质编号24880916
NACRESNA.22

产品性质

质量水平100
测定97%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp50-52 ℃ (lit.)
官能团phosphine
SMILES string[Fe].CC(C)P([C]1[CH][CH][CH][CH]1)C(C)C.CC(C)P([C]2[CH][CH][CH][CH]2)C(C)C
InChI1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChI keyLPBBEMRSRONKMN-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
545321Fluorochem1,1'-Bis(diisopropylphosphino)ferrocene97%220元/250mg;   418元/1g;   1342元/5g;   4862元/25g;   展开

基本信息

CAS Number97239-80-0
MDL NumberMFCD02684559
Melting Point53℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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