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CAS: 97-08-5
分子式: C6H3Cl2NO4S
分子量: 256.06
熔点: 57-60℃
中文名称: 
4-氯-3-硝基苯磺酰基氯
4-氯-3-硝基苯磺酰(基)氯
4-氯-3-硝基苯磺酰氯
3-硝基-4-氯苯磺酰氯
英文名称: 
Benzenesulfonyl chloride,4-chloro-3-nitro-
4-chloro-3-nitro-benzenesulfonyl chlorid
4-chloro-3-nitrobenzenesulfonyl chloride
4-Chloro-3-nitrobenzene sulfonyl chloride
性质描述: 熔点59-60℃。
生产方法: 由邻硝基氯苯经氯磺化得到。在氯磺化锅内加入氯磺酸,在60℃以下,1h内加入熔融的邻硝基氯苯。在60℃保温1h,升温至103-107℃保温6h,降温至40℃,加冰冷却,控制在25℃以下过滤。水洗至pH为5,得2-硝基氯苯-4-磺酰氯。
用途: 染料中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C844357MACKLIN4-氯-3-硝基苯磺酰氯97%28元/1g;   33元/5g;   95元/25g;   展开
储存:2-8°C
状态:白色到灰白色到灰色到米黄色到棕色粉末或晶体或块状
C1887TCI4-Chloro-3-nitrobenzenesulfonyl Chloride>96.0%(GC)(T)520元/5G;   1905元/25G;   展开

基本信息

纯度/分析方法>96.0%(GC)(T)
分子式/分子量C6H3Cl2NO4S = 256.05
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN1978600
PubChem物质ID87558530

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 96.0 %
Purity(Argentometric Titration)min. 96.0 %
Melting point58.0 to 62.0 ℃

物性(参考值)

熔点60 ℃
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 II
监管条件代码(*)
586976J&K4-Chloro-3-nitrobenzenesulfonyl Chloride98%131元/1G;   351元/5G;   1447元/25G;   展开

基本信息

分子式C6H3Cl2NO4S
分子量256.06
熔点59-60
MDL编码MFCD00007440
Beilstein1978600
EINECS 编号202-558-2

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
TSCA
B21632Alfa Aesar4-Chloro-3-nitrobenzenesulfonyl Chloride98%933元/5g;   3370元/25g;   10805元/100g;   展开

基本信息

MDL
MFCD00007440

EINECS
202-558-2

分子式
C6H3Cl2NO4S

分子量
256.07

熔点
58-61°

形态
Crystalline powder

Beilstein
1978600

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

C59408Sigma-Aldrich4-Chloro-3-nitrobenzenesulfonyl Chloride96%2039.65元/25 G;   展开

产品说明

应用

4-Chloro-3-nitrobenzenesulfonyl chloride can be used:

  • In the preparation of functionalized 1H-indenes via copper-catalyzed arylative cyclization.
  • As a precursor in the synthesis of N-arylsulfonyl-3-acylindole arylcarbonyl hydrazone derivatives that show potential nematicidal activity.
  • As a key starting material in the synthesis of sulfonamide analogs of ferrostatin-1 (fer-1), which possess good ferroptosis inhibition property.
  • In the synthesis of 4-chloro-3-nitrobenzene thiol.

包装

25 g in glass bottle

基本信息

线性分子式ClC6H3(NO2)SO2Cl
分子量256.06
EC 号202-558-2
MDL编号MFCD00007440
PubChem化学物质编号24892822
NACRESNA.22

产品性质

质量水平100
测定96%
mp59-60 ℃ (lit.)
SMILES string[O-][N+](=O)c1cc(ccc1Cl)S(Cl)(=O)=O
InChI1S/C6H3Cl2NO4S/c7-5-2-1-4(14(8,12)13)3-6(5)9(10)11/h1-3H
InChI keySEWNAJIUKSTYOP-UHFFFAOYSA-N
214625Fluorochem4-Chloro-3-nitrobenzene-1-sulfonyl chloride95%264元/1g;   418元/5g;   1100元/25g;   3850元/100g;   展开

基本信息

CAS Number97-08-5
MDL NumberMFCD00007440
Melting Point59 - 60

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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