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CAS: 96-21-9
分子式: C3H6Br2O
分子量: 217.89
沸点: 219℃
中文名称: 
1,3-二溴-2-丙醇
英文名称: 
alpha,alpha'-Dibromohydrin
Glycerol alpha,alpha'-Dibromohydrin
1,3-Dibromopropyl alcohol
-Dibromohydrin
1,3-Dibromo-isopropyl alcohol
1,3-dibromo-2-propanol
1,3-dibromohydrin
1,3-dibromo-2-propano
alpha,gamma-dibromohydrin
alpha-dibromohydrin
glycerol 1,3-dibromohydrin
glycerol alpha,gamma-dibromohydrin
glycerol-alpha,gamma-dibromohydrine
1,3-dibromo-propan-2-ol
展开更多英文名
性质描述: 无色或微黄色油状液体。沸点219℃(部分分解),124℃(5kPa),相对密度2.1202(25/4℃),折光率1.5495(25℃)。溶于醇、醚,不溶于水。有特殊气味,久置于空气中会氧化变黄。
生产方法: 由甘油与赤磷、溴反应而得。将甘油、赤磷混合均匀,在搅拌下滴加溴,放热反应,温度在80℃左右。溴加完后放置过夜,经减压蒸馏,馏出物以10%海波洗两次,用无水碳酸钠干燥,滤去干燥剂后分馏,收集110-112℃(2.66kPa)馏分即为成品。
用途: 作溶剂,用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D806310MACKLIN1,3-二溴-2-丙醇95%39元/1g;   116元/5g;   536元/25g;   1800元/100g;   展开
储存:2~8°C
状态:无色到浅黄色液体
折射率:n20/D 1.552(lit.)
D0187TCI1,3-Dibromo-2-propanol (stabilized with Copper chip)>95.0%(GC)825元/25ML;   2195元/100ML;   6665元/500ML;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C3H6Br2O = 217.89
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气,加热
Reaxys-RN1732074
PubChem物质ID87566905
SDBS (AIST Spectral DB)3033
MDL编号MFCD00000216

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点215 ℃
闪点46 ℃
比重2.13
折射率1.55

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H341 : 怀疑可造成遗传性缺陷。
H351 : 怀疑致癌。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P201 : 使用前取得专用说明。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#UB0200000

运输信息

UN编号UN1987
类别3
包装类别 III
监管条件代码(*)
C40654Alfa Aesar1,3-Dibromo-2-propanol95%1955元/25g;   6824元/100g;   展开

基本信息

Ref#
40654

MDL
216

分子式
C3 H6 Br2 O

分子量
217.89

闪点
46

密度
2.13

安全信息

危险等级
6.1

包装组
II

372404Sigma-Aldrich1,3-Dibromo-2-propanoltechnical grade, 95%357.28元/5 G;   1233.67元/25 G;   展开

产品说明

一般描述

1,3-Dibromo-2-propanol is a dihalogenated alcohol. It is reported as bifunctional crosslinking reagent.

应用

1,3-Dibromo-2-propanol may be used in the following studies:

  • To prepare the thioether ligand, used in the synthesis of palladium-phosphorus/sulfur nanoparticles.
  • Preparation of 2-(alkoxy)propenyl bromide.
  • Synthesis of 1,3-propanediamine derivatives connected to carbohydrates (sugar-pendant diamines).
  • Chemical crosslinking of nine single substitution cysteine mutants of staphylococcal nuclease.
  • Preparation of 1,3-dinitrooxy-2-propanol, via reaction with AgNO3 in MeCN at 80℃.

包装

5, 25 g in glass bottle

基本信息

线性分子式BrCH2CH(OH)CH2Br
分子量217.89
EC 号202-489-8
MDL编号MFCD00000216
PubChem化学物质编号24863033
NACRESNA.22

产品性质

等级technical grade
质量水平100
测定95%
折射率n20/D 1.552 (lit.)
bp82-83 ℃/7 mmHg (lit.)
密度2.136 g/mL at 25 ℃ (lit.)
SMILES stringOC(CBr)CBr
InChI1S/C3H6Br2O/c4-1-3(6)2-5/h3,6H,1-2H2
InChI keyKIHQZLPHVZKELA-UHFFFAOYSA-N

安全信息

象形图GHS02GHS06GHS08
警示用语:Danger
危险声明H226 - H301 - H315 - H319 - H335 - H351
预防措施声明P201 - P210 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)116.6 °F - closed cup
闪点(C)47 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
242654Fluorochem1,3-Dibromopropan-2-ol95%396元/1g;   814元/5g;   1276元/25ml;   3718元/100ml;   展开

基本信息

CAS Number96-21-9
MDL NumberMFCD00000216
Boiling Point82 - 83 ℃
Density2.136

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H351: Suspected of causing cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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