CAS 95408-45-0; [1,1'-双(二叔丁基膦)二茂铁]二氯化钯(ii); [1,1'-bis(di-tert-butylphosphino)ferrocene]palladium(ii) dichloride

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B804121

MACKLIN

1,1'-双(二-叔丁基膦)二茂铁二氯合钯

98%

51元/250mg; 186元/1g; 924元/5g; 4126元/25g;

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储存：-20°C, 密封, 避光
状态：米黄色到棕色到暗红棕色粉末

B3160

TCI

[1,1'-Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride

>98.0%(T)

1110元/1G; 4065元/5G;

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基本信息

纯度/分析方法	>98.0%(T)
分子式/分子量	C₂₆H₄₄Cl₂FeP₂Pd = 651.75
外观与形状(20℃)	固体
PubChem物质ID	87560219

技术规格

Appearance	Orange to Amber to Dark red powder to crystal
Purity(Argentometric Titration)	min. 98.0 %

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

795991

J&K

PdCl2(dtbpf)

16% 钯, Umicore制造

987元/250MG; 2765元/1G;

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基本信息

分子式	C₂₆H₄₄FeP₂·PdCl₂
分子量	651.75
熔点	203-208
MDL编码	MFCD08064219
存储条件	Store at 2-8℃

安全信息

防范说明	P262
WGK	3

46-0445

Strem

Dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II)

99%

990元/100mg; 2535元/500mg; 7065元/2g; 24735元/10g;

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Technical Notes:

1.See 26-0270.

2.Catalyst for the borylation of aryl halides.

3.ß-AIkyI Suzuki-Miyaura cross -coupling reactions with potassium alkyltrifluoroborates.

4.Catalyst for modified Negishi coupling.

5.Synthesis of polyheterocycles by a Pd -catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.

6.Catalyst for Stille allylation.

7.Catalyst for the amination of aryl

bromides

References:

1. J. Org. Chem., 2000, 65, 164.

2.J. Org. Chem., 2003, 74, 5534.

3.Org. L ett., 2002, 4, 375.

4.Angew. Chem. Int. Ed., 2003, 42, 47 74.

5.J. Am. Chem. Soc., 2008, 130, 1 6854.

6.J. Org. Chem., 2009, 74, 6867.

46-2030

Strem

Palladium(II) acetate/1,1'-bis(di-t-butylphosphino)ferrocene/potassium phosphate admixture

CatKit single-use vials - 2.02 wt% Pd(OAc)2

1260元/5×1vial; 5010元/25×1vial;

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Technical Note:

1.Convenient, pre weighed vial of palladium catalyst/base admixture useful for screening reactions. The vial contains 453mg of admixture, which will deliver 4 mole% of palladium catalyst and 2 equivalents of base, to a reaction using 1 mmole of substrate.

701602

Sigma-Aldrich

[1,1′-Bis(di-tert-butylphosphino)ferrocene]dichloropalladium(II)

98%

1120.11元/250 MG; 3958.32元/1 G; 9351.19元/5 G;

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产品说明

一般描述

[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II) (PdCl₂(dtbpf))可催化Suzuki和Heck反应。这种预催化剂是由Johnson Matthey′s Catalysis and Chiral Technologies公司的一组研究人员合成的。它是各种Pd催化交叉偶联反应的活性催化剂。
[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II) 是一种空气稳定的、高活性和多功能的催化剂。它是交叉偶联反应的有效催化剂。它能催化精细化学品和药物化学品的各种偶联反应。它常被用作Suzuki反应的均相催化剂。
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。点击此处，查看更多详情。

应用

钯催化交叉偶联反应应用指南
[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II) 被用于制备[PdCl₂(二膦基金属茂)]配合物。据报道，这些配合物是Buchwald-Hartwig反应的催化剂前体。
它也被用于催化TPGS-750-M中发生的环保型Suzuki交叉偶联反应。

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
[1,1′-双(二-叔丁基膦基)二茂铁]二氯合钯(II)(PdCl₂(dtbpf))可催化各种芳族和杂芳族卤化物与甲基亚氨基二乙酸衍生物(MIDA硼酸酯)在室温下(在不含有机溶剂的条件下)的Suzuki交叉偶联反应。它可以催化查耳酮合成过程中的交叉偶联反应。

包装

250 mg in glass bottle
1, 5, 50 g in glass bottle

基本信息

经验(实验)分子式	C₂₆H₄₄Cl₂FeP₂Pd
分子量	651.75
MDL编号	MFCD08064219
PubChem化学物质编号	329762308
NACRES	NA.22

产品性质

质量水平	200
测定	98%
形式	powder
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
环保替代产品特性	Catalysis Learn more about the Principles of Green Chemistry.
mp	203-208 ℃
环保替代产品分类	Aligned
储存温度	−20℃
SMILES string	[Fe].Cl[Pd]Cl.CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.CC(C)(C)P([C]2[CH][CH][CH][CH]2)C(C)(C)C
InChI	1S/2C13H22P.2ClH.Fe.Pd/c21-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h27-10H,1-6H3;2*1H;;/q;;;;;+2/p-2
InChI key	JQZFOBWXNREQLO-UHFFFAOYSA-L

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

044345

Fluorochem

1,1'-Bis(di-tert-butylphosphino) ferrocene palladium chloride

98%

2530元/1g; 8690元/5g;

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基本信息

CAS Number	95408-45-0
MDL Number	MFCD08064219
Melting Point	200-202℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .