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CAS: 95407-69-5
分子式: C10H20NO2
分子量: 186.27
熔点: 40.5-44℃
中文名称: 
4-甲氧基-四甲基哌啶氧自由基
英文名称: 
4-methoxy-2,2,6,6-tetramethylpiperidinyl-1-oxy
methoxytetramethylpiperidineoxyl
4-Methoxy-TEMPO
4-Methoxy-2,2,6,6-tetramethyl-1-piperidinyloxy,free radical
4-Methoxy-TEMPO,free radical
4-Methoxy-2,2,6,6-tetramethylpiperidinyloxy,free radical
4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M858130MACKLIN4-甲氧基-2,2,6,6-四甲基哌啶1-氧基 自由基 [氧化反应的催化剂]>98.0%(GC)(T)213元/1g;   890元/5g;   4250元/25g;   展开
储存:室温,干燥
状态:橙色到琥珀色到暗红色粉末到晶体
M1197TCI4-Methoxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Free Radical [Catalyst for Oxidation]>98.0%(GC)(T)470元/1G;   1395元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C10H20NO2 = 186.28
外观与形状(20℃)固体
Reaxys-RN4740399
PubChem物质ID87573157
MDL编号MFCD00270334

技术规格

AppearanceOrange to Amber to Dark red powder to crystal
Purity(GC)min. 98.0 %
Purity(Iodometric Titration)min. 98.0 %
Melting point40.0 to 45.0 ℃

物性(参考值)

熔点43 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
514586Sigma-Aldrich4-Methoxy-TEMPO97%1717.71元/5 G;   展开

产品说明

一般描述

4-甲氧基-TEMPO(4-甲氧基-2,2,6,6-四甲基-1-哌啶基氧基)是通常用于醇(伯/仲)的氧化反应的氨基甲苯基自由基。它已被提出作为受阻胺光稳定剂(HALS)模型化合物。通过电子自旋共振(ESR)和电喷雾电离质谱(ESI-MS)研究了其与光催化纳米二氧化钛的辐照稀释悬浮液的反应。

应用

4-甲氧基-TEMPO 在通过有氧氧化反应合成 2-取代的苯并恶唑的过程中可用作催化剂。

包装

5 g in glass bottle

基本信息

经验(实验)分子式C10H20NO2
分子量186.27
MDL编号MFCD00270334
PubChem化学物质编号24873570
NACRESNA.22

产品性质

质量水平200
测定97%
mp40.5-44 ℃ (lit.)
储存温度2-8℃
SMILES stringCOC1CC(C)(C)N([O])C(C)(C)C1
InChI1S/C10H20NO2/c1-9(2)6-8(13-5)7-10(3,4)11(9)12/h8H,6-7H2,1-5H3
InChI keySFXHWRCRQNGVLJ-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
547099Fluorochem4-Methoxy-TEMPO95%396元/250mg;   924元/1g;   3674元/5g;   展开

基本信息

CAS Number95407-69-5
MDL NumberMFCD00270334

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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