CAS 951776-24-2; [1,3-双(2,6-二异丙基苯基)咪唑-2-亚基][双三氟甲烷磺酰亚胺]金(i); [1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(i)

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CAS:

951776-24-2

分子式:

C₂₉H₃₆AuF₆N₃O₄S₂

分子量:

865.7008

中文名称:

[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基][双三氟甲烷磺酰亚胺]金(i)

英文名称:

[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(i)

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货号

品牌

产品名称

规格

包装、参考价格

详情

B918888

MACKLIN

[1,3-双(2,6-二异丙基苯基)咪唑-2-亚基][双(三氟甲磺酰基)酰亚胺]金(I)

98%

359元/100mg; 781元/250mg; 2666元/1g;

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储存：2-8°C，密闭，干燥

79-0245

Strem

[1,3-Bis(2,6-di-i-propylphenyl)imidazol-2-ylidene][bis(trifluoromethanesulfonyl)imide]gold(I)

min. 95%

855元/100mg; 3390元/500mg;

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Technical Notes:

1. Gold catalyst used for the hydroarylating cyclization of 1 ,2 bis(2-iodoethynyl)benzenes.

2. Gold catalyst used for the carbocyclization of phenols with a terminal alkyne.

3.Intermolecular C-H activation through the gold(I)-catalyzed reaction of iodoalkynes.

4. Reaction of ynamide with benzyl azides.

References:

1. Adv. Synth. Catal, 2015, 357, 500.

2.Adv. Synth. Catal., 2014 356, 2417.

3.Angew. Chem. Int. Ed., 2015, 54, 3052.

4. J. Am. Chem. Soc., 2015, 137, 9567.

753343

Sigma-Aldrich

[1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene] [bis(trifluoromethanesulfonyl)imide]gold(I)

95%

602.24元/100 MG; 2444.14元/500 MG;

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产品说明

包装

100, 500 mg in glass bottle

应用

Selective Au(I) catalyst for hydroaminations.

基本信息

经验(实验)分子式	C₂₉H₃₇AuF₆N₃O₄S₂
分子量	866.71
MDL编号	MFCD22572651
PubChem化学物质编号	329766355
NACRES	NA.22

产品性质

测定	95%
reaction suitability	core: gold reagent type: catalyst
mp	202-287 ℃ (decomposition)
SMILES string	CC(C)c1cccc(C(C)C)c1N2C=CN(C2=[Au]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F)c3c(cccc3C(C)C)C(C)C
InChI	1S/C27H36N2.C2F6NO4S2.Au/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h9-16,18-21H,1-8H3;;/q;-1;+1
InChI key	FLIVFZVCPOQPDV-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

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