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CAS: 95010-17-6
分子式: C6H9B3O3·C5H5N
分子量: 240.67
熔点: 49.0 to 53.0 deg-C
中文名称: 
2,4,6-三乙烯基环硼氧烷-吡啶络合物
乙烯硼酐吡啶络合物
英文名称: 
2,4,6-trivinylboroxin - pyridine complex
trivinylcyclotriboroxan - pyridine complex
推荐供应商
货号品牌产品名称规格包装、参考价格
T834687MACKLIN2,4,6-三乙烯基环硼氧烷-吡啶络合物98%292元/1g;   1115元/5g;   咨询
储存:-20°C
状态:白色到浅黄色粉末
T2498TCI2,4,6-Trivinylboroxin - Pyridine Complex>98.0%(T)730元/1G;   2565元/5G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C6H9B3O3・C5H5N = 240.67
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
包装和容器 1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN6787731
PubChem物质ID87560015
MDL编号MFCD03839440

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(GC)min. 95.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point49.0 to 53.0 ℃

物性(参考值)

熔点51 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
H28703Alfa AesarVinylboronic anhydride pyridine complex95%935元/1g;   6102元/5g;   8778元/25g;   咨询

应用
Reagent used for Suzuki-Miyaura cross-coupling, stereoselective synthesis via Palladium-catalyzed carboamination, Alkyl-connected 2-amino-6-vinylpurine (AVP) cross linking agent to cytosine base in RNA, Kaiser oxime resin-derived palladacycle as a recoverable polymeric precatalyst in Suzuki-Miyaura cross-coupling reactions in aqueous media and Kinetic resolution of phosphoryl and sulfonyl esters of binaphthol derivatives via Pd-catalyzed alcoholysis of their vinyl ethers.

备注
Moisture Sensitive, store away from water/moisture. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas.

基本信息

MDL
MFCD03839940

EINECS
672-662-4

分子式
C6H9B3O3

分子量
240.67

熔点
44-52°

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Powder

溶解性
Soluble in methanol.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
III

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

040866Fluorochem2,4,6-Trivinylcyclotriboroxane pyridine complex97%1386元/1g;   4180元/5g;   12518元/25g;   咨询

基本信息

CAS Number95010-17-6
MDL NumberMFCD03839940

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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