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CAS: 95-74-9
分子式: C7H8ClN
分子量: 141.60
沸点: 237-238 °C(lit.)
熔点: 25 °C
中文名称: 
2-氯-4-氨基甲苯
3-氯-4-甲基苯胺
邻氯对氨基甲苯
3-氯对甲苯胺
4-氨基-2-氯甲苯
英文名称: 
4-Amino-2-chloro toluene
3-chloro-4-methyl-Benzenamine
3-Chloro-4-methyl aniline
3-chloro-p-toluidin
1-amino-3-chloro-4-methylbenzene
2-chloro-4-aminotoluene
3-chloro-4-methylaniline
3-chloro-p-toluidine
3-chloro-4-methyl-benzenamin
drc 1347
nci-c02040
Benzenamine,3-chloro-4-methyl-
3-Chloro-4-methylbenzenamine
展开更多英文名
性质描述: 熔点26℃,沸点237-238.5℃,113-114℃(1.60kPa),闪点100℃,相对密度1.175 。
生产方法: 由对硝基甲苯经氯化、还原而得。1.氯化将硝基甲苯加入反应锅中,加热至75℃,投入无水三氯化铁和碘,搅拌10-20min后,于60℃开始通氯,氯化温度保持在55-70℃,当氯化物熔点>58.5℃在20min内不增长为止。赶气,升温到80-90℃,保持1.5-2h,得2-氯-4-硝基甲苯,收率98%。2.还原将配制好的硫化钠溶液加入反应锅内,在70-80℃加入上述2-氯-4-硝基甲苯,回流4h,温度为110±5℃,胺油纯度>98.5%、熔点>19℃时,蒸馏,得成品,收率90%。如果采用铁粉还原、反应温度100℃左右,反应物用甲苯萃取。收率约95%。
用途: 有机合成中间体,用于有机颜料中间体2B酸、农药绿麦隆的生产。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C804792MACKLIN3-氯-4-甲基苯胺97%38元/25g;   60元/100g;   143元/500g;   668元/2.5kg;   展开
储存:室温
状态:无色到棕色液体或白色到棕色固体
折射率:n20/D 1.584(lit.)
C0538TCI3-Chloro-4-methylaniline>97.0%(GC)120元/25G;   690元/500G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C7H8ClN = 141.60
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN636511
PubChem物质ID87565650
SDBS (AIST Spectral DB)3867
MDL编号MFCD00007773

技术规格

AppearanceWhite or Colorless to Light orange to Yellow powder to lump to clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

熔点22 ℃
沸点244 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H370 : 会损害器官。
H372 : 长期或反复接触会对器官造成损害。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P308+P311 : 如接触到或有疑虑:呼叫急救中心/医生。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#XU5111000

运输信息

UN编号UN2239
类别6.1
包装类别 III
监管条件代码(*)
333259J&K3-Chloro-4-methylaniline99%131元/50G;   355元/250G;   1169元/1KG;   展开

基本信息

分子式C7H8ClN
分子量141.60
熔点24-25
沸点237-238
闪点100
密度1.167
折光率(n20D)1.5840
MDL编码MFCD00007773
Beilstein636511
EINECS 编号202-446-3
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H315
H317
H319
H410
防范说明P273
P280
P301+P310
P305+P351+P338
P312
P501
UN号码2239
危险分类6.1
包装等级III
WGK3
RTECSXU5111000
TSCA
A15439Alfa Aesar3-Chloro-4-methylaniline98%1046元/250g;   3373元/1000g;   14176元/5000g;   展开

基本信息

MDL
MFCD00007773

EINECS
202-446-3

分子式
C7H8ClN

分子量
141.60

熔点
22-24°

沸点
236-238°

闪点
130°(266°F)

密度
1.180

折射率
1.5840

形态
Liquid

Beilstein
636511

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H373
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements
P260-P280-P305+P351+P338-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-33-36/38
Harmful by inhalation, in contact with skin and if swallowed.Danger of cumulative effects.Irritating to eyes and skin.

安全等级
26-28-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
XU5111000

TSCA

236322Sigma-Aldrich2-Chloro-4-aminotoluene98%290.46元/50 G;   展开

产品说明

应用

2-Chloro-4-aminotoluene has been used in the preparation of 2-chloro-4-cyanotoluene by Sandmeyer reaction with cuprous cyanide.

包装

50 g in glass bottle

基本信息

线性分子式ClC6H3(CH3)NH2
分子量141.60
Beilstein636511
EC 号202-446-3
MDL编号MFCD00007773
PubChem化学物质编号24854163
NACRESNA.22

产品性质

质量水平100
测定98%
折射率n20/D 1.584 (lit.)
bp237-238 ℃ (lit.)
mp24-25 ℃ (lit.)
密度1.167 g/mL at 25 ℃
储存温度2-8℃
SMILES stringCc1ccc(N)cc1Cl
InChI1S/C7H8ClN/c1-5-2-3-6(9)4-7(5)8/h2-4H,9H2,1H3
InChI keyRQKFYFNZSHWXAW-UHFFFAOYSA-N

安全信息

象形图GHS06GHS09
警示用语:Danger
危险声明H301 + H311 - H315 - H317 - H319 - H410
预防措施声明P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)212.0 °F - closed cup
闪点(C)100 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
024181Fluorochem3-Chloro-4-methylaniline98%264元/100g;   616元/250g;   1628元/1kg;   展开

基本信息

CAS Number95-74-9
MDL NumberMFCD00007773
Boiling Point237-238℃
Melting Point24-25℃
Density1.167

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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