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CAS: 95-69-2
分子式: C7H8ClN
分子量: 141.60
沸点: 241 °C(lit.)
熔点: 29 °C
中文名称: 
对氯邻甲苯胺
4-邻氯甲苯胺
4-氯邻甲苯胺
4-氯-2-甲基苯胺
2-氨基-5-氯甲苯
4-氯-2-甲苯胺
英文名称: 
benzenamine,-chloro-2-methyl-
benzenamine,-chloro-2-methyl-(4-cot)
4-Chloro-2-methylbenzenamine
Benzenamine,4-chloro-2-methyl-
o-Toluidine,4-chloro-
4-chloro-o-toluidin
2-amino-5-chlorotoluene
2-methyl-4-chloroaniline
3-chloro-6-aminotoluene
4-chloro-2-methylaniline
4-chloro-2-methylbenzeneamine
4-chloro-2-toluidine
4-chloro-6-methylaniline
4-chloro-o-toluidine
5-chloro-2-aminotoluene
amarthol fast red tr base
amino-2 chloro-5 toluene
asymmetric meta-chloro-ortho-toluidine
azoene fast red tr base
2-amino-5-chlortoluol
azoic diazo component 11, base
4-chloro-2-methyl-benzenamin
brentamine fast red tr base
chloro-4 o-toluidine
daito red base tr
deval red k
deval red tr
fast red 5ct base
fast red base tr
fast red tr
fast red tr base
fast red tr11
fast red tro base
kako red tr base
kambamine red tr
mitsui red tr base
p-chloro-o-toluidine
para-chloro-ortho-toluidine
red base ciba ix
red base irga ix
red base ntr
red tr base
red trbase
sanyo fast red tr base
tulabase fast red tr
展开更多英文名
性质描述: 灰白色固体或淡棕色油状液体。熔点29-30℃,沸点236-238℃(97.3kPa),折光率1.5848,闪点99℃,相对密度1.14。
生产方法: 由邻甲苯胺经氯化而得。可有多种氯化方法。邻甲苯胺盐酸盐以氯苯为溶剂,在50-60℃通氯反应可得4-氯邻甲苯胺。也可先经酰化,再经氯化、水解而得。将邻甲苯胺和氯苯混合搅拌,滴加乙酐,在70-80℃搅拌反应1.5h,冷却,于50℃左右通氯,此时突然生成大量白色固体。停止通氯,加入浓盐酸和水,于95℃搅拌回流反应2h。冷至室温,加碱液中和而得。收率70%以上。另一种方法是在酸性介质中,将邻甲苯胺盐酸盐与氯化氢和氧气的混合气体(或氯气和氧气)反应。
用途: 农药、医药和染料的重要中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C805257MACKLIN4-氯-2-甲基苯胺98%30元/5g;   68元/25g;   250元/100g;   1112元/500g;   展开
储存:2~8°C
状态:白色到棕色或紫色液体或固体
折射率:n20/D 1.583(lit.)
A0704TCI4-Chloro-2-methylaniline>98.0%(GC)(T)405元/25G;   850元/100G;   2550元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C7H8ClN = 141.60
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN878505
PubChem物质ID87562256
SDBS (AIST Spectral DB)3565
MDL编号MFCD00007842

技术规格

AppearanceWhite or Colorless to Light orange to Yellow powder to lump to clear liquid
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

熔点25 ℃
沸点241 ℃
水溶性实际上不溶

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 : 吞咽或皮肤接触有害。
H370 : 会损害器官。
H372 : 长期或反复接触会对器官造成损害。
H341 : 怀疑可造成遗传性缺陷。
H350 : 可能致癌。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P308+P311 : 如接触到或有疑虑:呼叫急救中心/医生。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#XU5000000

运输信息

UN编号UN2239
类别6.1
包装类别 III
监管条件代码(*)
161271J&K4-Chloro-2-methylaniline98%68元/5G;   272元/25G;   785元/100G;   展开

基本信息

分子式C7H8ClN
分子量141.60
熔点24-27
沸点241
闪点124
密度1.19
折光率(n20D)1.5830
MDL编码MFCD00007842
Beilstein878505
EINECS 编号202-441-6

安全信息

图形或危害标志
提示语Danger
危险说明H301
H311
H331
H341
H350
H410
防范说明P201
P261
P273
P280
P301+P310
P311
UN号码2239
危险分类6.1
包装等级III
WGK3
RTECSXU5000000
C10937Alfa Aesar4-Chloro-2-methylaniline98%689元/5g;   10383元/100g;   展开

基本信息

Ref#
10937

MDL
7842

分子式
C7 H8 Cl N

分子量
141.6

闪点
124

密度
1.19

安全信息

危险等级
6.1

包装组
III

590711Sigma-Aldrich4-Chloro-2-methylaniline98%554.01元/10 G;   展开

产品说明

应用

4-Chloro-2-methylaniline may be used in the synthesis of the following:

  • 2,8-dichloro-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f]-diazocine via reaction with paraformaldehyde in toluene
  • N-allylated derivative via palladium-catalyzed selective monoallylation with allyl alcohol
  • N-(4-chloro-2-methylphenyl)benzamide via reaction with benzoyl chloride

包装

10 g in glass bottle

基本信息

线性分子式ClC6H3(CH3)NH2
分子量141.60
Beilstein878505
EC 号202-441-6
MDL编号MFCD00007842
PubChem化学物质编号24881294
NACRESNA.22

产品性质

质量水平200
测定98%
折射率n20/D 1.583 (lit.)
bp241 ℃ (lit.)
mp24-27 ℃ (lit.)
密度1.19 g/mL at 25 ℃ (lit.)
SMILES stringCc1cc(Cl)ccc1N
InChI1S/C7H8ClN/c1-5-4-6(8)2-3-7(5)9/h2-4H,9H2,1H3
InChI keyCXNVOWPRHWWCQR-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08GHS09
警示用语:Danger
危险声明H301 + H311 + H331 - H341 - H350 - H410
预防措施声明P201 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)255.2 °F - closed cup
闪点(C)124 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RAC-06-EA-0.1X-10MLAccuStandard4-Chloro-o-toluidine,10 μg/mL in Ethyl acetate10 μg/mL in Ethyl acetate309元/10mL;   展开
4-Chloro-o-toluidine4-氯-2-甲基苯胺95-69-210 µg/mL
RAC-06AccuStandard4-Chloro-o-toluidine,100 μg/mL in AcCN100 μg/mL in AcCN386元/1mL;   展开
4-Chloro-o-toluidine4-氯-2-甲基苯胺95-69-2100 µg/mL
RAC-06-10XAccuStandard4-Chloro-o-toluidine,1000 μg/mL in AcCN1000 μg/mL in AcCN541元/1mL;   展开
4-Chloro-o-toluidine4-氯-2-甲基苯胺95-69-2100 µg/mL
024872Fluorochem4-Chloro-2-methylaniline98%220元/1g;   462元/25g;   1496元/100g;   5170元/500g;   展开

基本信息

CAS Number95-69-2
MDL NumberMFCD00007842
Boiling Point241℃
Melting Point24-27℃
Density1.19

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H331: Toxic if inhaled.
H341: Suspected of causing genetic defects ..
H350: May cause cancer ..
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P311: Call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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