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CAS: 95-16-9
分子式: C7H5NS
分子量: 135.19
沸点: 231℃
熔点: 2℃
中文名称: 
苯并噻唑
1,3-硫氮杂茚
间氮硫杂茚
英文名称: 
Benzothiazole
1-thia-3-azaindene
benzosulfonazole
Benzthiazole
benzothiazol
Benzo[d]thiazole
fema number 3256
o-2857
usaf ek-4812
vangard bt
性质描述: 微黄色液体。熔点2℃,沸点231℃,131℃(4.53kPa),相对密度1.2460(20/4℃),折光率1.6379。溶于乙醇、二硫化碳,微溶于水。能随水蒸气挥发。具中性反应,似唑啉气味。
生产方法: 由N,N-二甲基苯胺与硫磺反应而得。将N,N-二甲基苯胺和硫磺一起加热回流,反应8h后蒸馏。收集200-260℃馏分,将其溶于浓盐酸中,过滤。向滤液加入硝酸铵水溶液,析出苯并噻唑硝酸盐,过滤后将滤饼溶于水中,加氨水至碱性,析出结晶,过滤干燥后减压蒸馏,收集131℃(4.53kPa)馏分即得成品。
用途: 用作照相材料、有机合成中间体,也可用为农业植物资源研究的试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802261MACKLIN苯并噻唑≥96%28元/25g;   39元/100g;   70元/500g;   114元/1kg;   558元/5kg;   展开
储存:2~8°C
状态:黄色到棕色液体
折射率:n20/D 1.642(lit.)
B886032MACKLIN苯并噻唑99%(HPLC)33元/25g;   60元/100g;   152元/500g;   440元/2.5kg;   展开
储存:2~8°C
状态:无色到浅黄色澄清液体
折射率:n20/D 1.642(lit.)
B0092TCIBenzothiazole>96.0%(GC)165元/25ML;   375元/100ML;   1020元/500ML;   展开

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C7H5NS = 135.18
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN109468
PubChem物质ID87563291
SDBS (AIST Spectral DB)1723
Merck Index (14)1107
MDL编号MFCD00005775

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

熔点2 ℃
沸点231 ℃
闪点107 ℃
比重1.25
折射率1.64
水溶性实际上不溶
在水中的溶解度4.3 g/l  
溶解性(可溶于)乙醚,醇,丙酮

安全信息

图形或危害标志
信号词危险
危险性说明H311 : 皮肤接触会中毒。
H302 : 吞咽有害。
H316 : 造成轻微皮肤刺激。
H320 : 造成眼刺激。
H402 : 对水生生物有害。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#DL0875000

运输信息

UN编号UN2810
类别6.1
包装类别 III
监管条件代码(*)
217972J&KBenzothiazole99%121元/50G;   393元/250G;   展开

基本信息

分子式C7H5NS
分子量135.19
熔点2
沸点231
闪点113
密度1.238
折光率(n20D)1.6420
MDL编码MFCD00005775
Beilstein109468
Merck14,1107
EINECS 编号202-396-2

安全信息

图形或危害标志
提示语Warning
危险说明H302
H311
H319
H332
防范说明P260
P281
P305+P351+P338
UN号码2810
危险分类6.1
包装等级III
WGK2
RTECSDL0875000
TSCA
A10380Alfa AesarBenzothiazole97%444元/50g;   933元/250g;   3364元/1000g;   展开

应用
It is an interesting carbonyl equivalent and reacts with aldehydes or ketones to generate α-hydroxy carbonyl compounds. Benzothiazole is used as a chemical intermediate in organic synthesis. It is a precursor of rubber accelerators and a component of cyanine dyes. It is also used as a flavoring substance. It is also used as a flavor, antimicrobial agent, and component of cyanine dyes. Its derivatives are used as rubber accelerators.

备注
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00005775

EINECS
202-396-2

分子式
C7H5NS

分子量
135.19

熔点

沸点
230°

闪点
107°(224°F)

密度
1.241

折射率
1.6420

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Slightly soluble in water. Soluble in alcohol, carbon disulfide

Beilstein
109468

Merck
14,1107

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H332-H319
Toxic if swallowed.Toxic in contact with skin.Harmful if inhaled.Causes serious eye irritation.

Precautionary Statements
P261-P280-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-36
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
DL0875000

TSCA

C14639Alfa AesarBenzothiazole97%583元/5ml;   1282元/250ml;   4118元/1L;   9969元/2.5L;   展开

基本信息

Ref#
14639

MDL
5775

分子式
C7 H5 N S

分子量
135.18

闪点
>112

密度
1.23

安全信息

危险等级
6.1

包装组
III

101338Sigma-AldrichBenzothiazole96%333.12元/5 G;   465.99元/100 G;   1021.24元/500 G;   展开

产品说明

应用

备受关注的羰基等价物。与醛类或酮类反应可生成 α-羟基羰基化合物。

包装

5, 100, 500 g in glass bottle

基本信息

经验(实验)分子式C7H5NS
分子量135.19
Beilstein109468
EC 号202-396-2
MDL编号MFCD00005775
PubChem化学物质编号24846538
NACRESNA.22

产品性质

蒸汽密度4.66 (vs air)
质量水平100
蒸汽压34 mmHg ( 131 ℃)
测定96%
折射率n20/D 1.642 (lit.)
bp231 ℃ (lit.)
mp2 ℃ (lit.)
密度1.238 g/mL at 25 ℃ (lit.)
SMILES stringc1ccc2scnc2c1
InChI1S/C7H5NS/c1-2-4-7-6(3-1)8-5-9-7/h1-5H
InChI keyIOJUPLGTWVMSFF-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311 - H319 - H332
预防措施声明P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
W325600Sigma-AldrichBenzothiazole≥96%, FG398.74元/;   1377.75元/1 KG;   12839.5元/10 KG;   28597元/25 KG;   展开

产品说明

一般描述

Benzothiazole, a volatile sulfur-containing heterocyclic compound, is one of the key odorants of heated milk. It is also reported to occur as a flavor component of miso, coconut meat and cooked-beef.

包装

10, 25 kg in composite drum
1 kg in glass bottle

法律信息

For R&D Use and/or Food Manufacturing only

基本信息

经验(实验)分子式C7H5NS
分子量135.19
FEMA编号3256
Beilstein109468
EC 号202-396-2
欧洲委员会编号11594
MDL编号MFCD00005775
PubChem化学物质编号24901589
Flavis编号15.016
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
agencymeets purity specifications of JECFA
reg. complianceEU Regulation 1334/2008 & 178/2002
蒸汽密度4.66 (vs air)
蒸汽压34 mmHg ( 131 ℃)
测定≥96%
杂质≤0.1% aniline
折射率n20/D 1.642 (lit.)
bp231 ℃ (lit.)
mp2 ℃ (lit.)
密度1.238 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查coffee; meaty; nutty; brown; vegetable; sulfurous
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringc1ccc2scnc2c1
InChI1S/C7H5NS/c1-2-4-7-6(3-1)8-5-9-7/h1-5H
InChI keyIOJUPLGTWVMSFF-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311 - H319
预防措施声明P264 - P270 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)224.6 °F - Pensky-Martens closed cup
闪点(C)107 ℃ - Pensky-Martens closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
61427SupelcoBenzothiazoleanalytical standard870.78元/100 MG;   展开

产品说明

一般描述

苯并噻唑是一种天然存在的双环类杂芳族化合物,具有多种药理活性,包括抗癌、抗微生物、抗惊厥、抗病毒、抗结核、抗疟疾、抗蠕虫、止痛、抗炎、抗糖尿病和杀真菌作用。它也是茶叶和蔓越莓的香气成分。

应用

苯并噻唑可用作分析标准品,用于通过各种色谱技术测定服装纺织品样品、环境水样品和葡萄/葡萄酒中的分析物。

其他说明

离子迁移率:121.0 Å2 [M+H]+ 的 TWCCSN2

碰撞截面(CCS)测量由Waters公司完成,使用的是SYNAPT XS质谱仪。
有关离子迁移率如何测量离子的 CCS 的描述和概述,请访问 ims.waters.com

关于SYNAPT XS质谱仪的更多信息可以在IMS微网站和产品网页上找到。

TWCCS的测量值预计在该参考值的2%以内。

P/N 61427 是Waters Extractables & Leachables UNIFI 科学图书馆的一部分,可从 Waters Marketplace 下载。

基本信息

经验(实验)分子式C7H5NS
分子量135.19
Beilstein109468
EC 号202-396-2
MDL编号MFCD00005775
PubChem化学物质编号329759489
NACRESNA.24

产品性质

质量水平100
等级analytical standard
蒸汽密度4.66 (vs air)
蒸汽压34 mmHg ( 131 ℃)
测定≥97.0% (GC)
保质期limited shelf life, expiry date on the label
杂质≤0.1% aniline
≤5.0% water
折射率n20/D 1.639-1.645
n20/D 1.642 (lit.)
bp231 ℃ (lit.)
mp2 ℃ (lit.)
密度1.238 g/mL at 25 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
格式neat
SMILES stringc1ccc2scnc2c1
InChI1S/C7H5NS/c1-2-4-7-6(3-1)8-5-9-7/h1-5H
InChI keyIOJUPLGTWVMSFF-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311 - H319 - H332
预防措施声明P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
093451FluorochemBenzo[d]thiazole95%220元/1g;   286元/25g;   748元/100g;   2332元/500ml;   展开

基本信息

CAS Number95-16-9
MDL NumberMFCD00005775
Density1.238

安全信息

图形或危害标志
危险性说明 EUH401: To avoid risks to human health and the environment, comply with the instructions for use.
H302: Harmful if swallowed.
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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