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CAS: 95-14-7
分子式: C6H5N3
分子量: 119.12
沸点: 204℃(15
熔点: 94-99℃
中文名称: 
苯丙三唑
1H-苯并三唑
苯三氮唑
苯丙三氮唑
苯并三氮唑
1,2,3-苯并三氮唑
苯并三氮杂茂
连三氮杂茚
苯三唑
苯并三唑
1,2,3苯骈三氮唑
苯骈三氮唑钠BTANA
展开更多中文名
英文名称: 
1H-Benzotriazole(1,2,3)
1,2,3-BENZOTRIAZOLE-Na
1,2,3-Benzotriazole
Benztriazol
benzotriazol
1H-Benzotriazole
1,2,-aminozophenylene
1,2,3-triaza-1h-indene
1,2,3-triazaindene
1,2-aminoazophenylene
1h-1,2,3-benzotriazole
1,2,3-benzotriazole-1h-benzotriazole
2,3-diazaindol
1h-benzo
2,3-diazaindole
1h-benzo triazole
azimidobenzene
aziminobenzene
benzene azimide
benzisotriazole
benztriazole
cobratec #99
cobratec 99
nci-c03521
nsc-3058
u-6233
BTA
展开更多英文名
性质描述: 白色到浅粉色针状结晶。熔点98.5℃,沸点204℃(2.0kPa),159℃(0.267kPa)。溶于醇、苯、甲苯、氯仿及二甲基甲酰胺,微溶于水。在空气中氧化逐渐变红。在真空中蒸馏时能发生爆炸。
生产方法: 由邻苯三胺与亚硝酸钠反应而得。将邻苯二胺加入50℃水中溶解,再加入冰醋酸,降温至5℃,加入亚硝酸钠搅拌反应。反应物渐渐变成暗绿色,温度升至70-80℃,溶液变为桔红色,于室温放置2h,冷却,滤出结晶,用冰水洗涤,干燥得粗品,将粗品减压蒸馏,收集201-204℃(2.0kPa)的馏分,再用苯重结晶,可得熔点为96-97℃的产品,产率80%左右。曾有报道用亚硝酸钠处理多菌灵的缩合废水而得副产物苯并三氮唑。
用途: 在电镀中用以表面纯化银、铜、锌,有防变色作用。BTA与铜原子形成共价键和配位键,相互多替成链状聚合物,在铜加表面组成多层保护膜,使铜的表面不起氧化还原反应,不发生氢气,起防蚀作用。对铅、铸铁、镍、锌等金属材料也有同样效果。BTA可与多种缓蚀剂配合,提高缓蚀效果。也可与多种阻垢剂、杀菌灭藻剂配合使用,尤其对封闭用循环冷却水系统缓蚀效果甚佳,在汽车用防冻剂乙二醇和水中,涂料中添加BTA都能挥发保护材料的作用。BTA为良好的紫外光吸收剂,对紫外光敏感的制品可起到稳定的作用,例如防止重氮染料褪色,用BTA处理纸、编织物、胶片、金属硬币等薄片制品可以防止变色。在机械加工过程中,将BTA加入研磨油、切削油中,可以使加工的铜件不变色。该品还可用作分析试剂,与氨水及二胺四乙酸合用,可用于选择性地测定银、铜、锌。也可用作摄影防灰雾剂及有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
H801876MACKLIN苯骈三氮唑试剂级, 97%30元/100g;   86元/500g;   275元/2.5kg;   1080元/10kg;   2650元/25kg;   展开
储存:室温
状态:白色到灰白色粉末或晶体
H801875MACKLIN苯骈三氮唑99%46元/100g;   126元/500g;   379元/2.5kg;   展开
储存:室温
状态:白色到灰白色粉末或晶体
B0094TCI1,2,3-Benzotriazole>98.0%(T)(HPLC)140元/25G;   420元/100G;   615元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C6H5N3 = 119.13
外观与形状(20℃)固体
Reaxys-RN112133
PubChem物质ID87563293
SDBS (AIST Spectral DB)1529
Merck Index (14)1108
MDL编号MFCD00005699

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Argentometric Titration)min. 98.0 %
Melting point96.0 to 100.0 ℃

物性(参考值)

熔点98 ℃
沸点204 ℃/15 mmHg
最大吸收波长279(THF) nm
水溶性微溶
在水中的溶解度19.8 g/l   25 ℃
溶解性(可溶于)苯,二甲基甲酰胺,醇,甲苯,氯仿
溶解性(微溶于)丙酮

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H332 : 吞咽或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#DM1225000
128045J&KBenzotriazole99%76元/100G;   228元/500G;   展开

基本信息

分子式C6H5N3
分子量119.12
熔点97-99
沸点204
闪点170
MDL编码MFCD00005699
Beilstein112133
Merck14,1108
EINECS 编号202-394-1

安全信息

图形或危害标志
提示语Warning
危险说明H302
H319
H332
H412
防范说明P273
P305+P351+P338
WGK1
RTECSDM1225000
TSCA
A15423Alfa Aesar1H-Benzotriazole99%380元/50g;   1322元/250g;   5286元/1000g;   展开

应用
1H-Benzotriazole is an anticorrosive agent, which is useful in aircraft deicing and antifreeze fluids. It is also employed in dishwasher detergents. Further, it is used as a restrainer in photographic emulsions and also useful as a reagent for the determination of silver in analytical chemistry. It also serves as a corrosion inhibitor in the atmosphere and underwater. Further, it is utilized in the synthesis of amines from glyoxal.

备注
Store in a cool place. Incompatible with strong oxidizing agents and heavy metals.

基本信息

MDL
MFCD00005699

EINECS
202-394-1

分子式
C6H5N3

分子量
119.13

熔点
96-99°

沸点
204°/15mm

闪点
212°(413°F)

密度
1.360

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in water, benzene, toluene, chloroform, ethanol and N,N-dimethylformamide.

Beilstein
112133

Merck
14,1108

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H332-H319-H402-H412
Harmful if swallowed.Harmful if inhaled.Causes serious eye irritation.Harmful to aquatic life.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P273-P280h-P305+P351+P338
Avoid release to the environment.Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
9

包装组
III

危险类别
20/22-36-52/53
Harmful by inhalation and if swallowed.Irritating to eyes.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
9-26-36-60-61
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
DM1225000

TSCA

B11400Sigma-AldrichBenzotriazoleReagentPlus®, 99%496.77元/100 G;   1478.81元/500 G;   2038.98元/750 G;   展开

产品说明

包装

100, 500, 750 g in poly bottle

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C6H5N3
分子量119.12
Beilstein112133
EC 号202-394-1
MDL编号MFCD00005699
PubChem化学物质编号57653915
NACRESNA.21

产品性质

质量水平200
蒸汽密度4.1 (vs air)
蒸汽压0.04 mmHg ( 20 ℃)
产品线ReagentPlus®
测定99%
mp97-99 ℃ (lit.)
SMILES stringc1ccc2[nH]nnc2c1
InChI1S/C6H5N3/c1-2-4-6-5(3-1)7-9-8-6/h1-4H,(H,7,8,9)
InChI keyQRUDEWIWKLJBPS-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H411
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)338.0 °F - closed cup
闪点(C)170 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
76457SupelcoBenzotriazoleanalytical standard898.82元/50 MG;   展开

产品说明

一般描述

Benzotriazoles are high production volume chemicals that are widely used for industrial and domestic applications.

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Benzotriazole has been used as a reference standard for the determination of the analyte in river and wastewater samples by liquid chromatography combined with mass spectrometry (LC-MS). It has also been used as a reference standard for the identification of the analyte in aqueous matrices and biosolid samples by gas chromatography-mass spectrometry (GC-MS).

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

基本信息

经验(实验)分子式C6H5N3
分子量119.12
Beilstein112133
EC 号202-394-1
MDL编号MFCD00005699
PubChem化学物质编号329767131
NACRESNA.24

产品性质

质量水平100
等级analytical standard
蒸汽密度4.1 (vs air)
蒸汽压0.04 mmHg ( 20 ℃)
测定≥98.0% (GC)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp97-99 ℃ (lit.)
application(s)environmental
pharmaceutical
格式neat
SMILES stringc1ccc2[nH]nnc2c1
InChI1S/C6H5N3/c1-2-4-6-5(3-1)7-9-8-6/h1-4H,(H,7,8,9)
InChI keyQRUDEWIWKLJBPS-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H411
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)338.0 °F - closed cup
闪点(C)170 ℃ - closed cup
8.22315Sigma-Aldrich1H-Benzotriazolefor synthesis402.89元/100 G;   1156.95元/500 G;   15035.2元/25 KG;   展开

产品说明

分析说明

含量(HPLC,area%): ≥ 99.0 %(a/a)
熔程(下限值): ≥ 95 °C
熔程(上限值): ≤ 99 °C
同一性(IR):通过测试

基本信息

经验(实验)分子式C6H5N3
分子量119.12
MDL编号MFCD00005699
EC索引号202-394-1

产品性质

蒸汽压0.053 hPa ( 20 ℃)
质量水平200
测定≥99.0% (HPLC)
形式solid
自燃温度400 ℃
效能560 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rabbit)
pH值(酸碱度)6.0-7.0 (20 ℃, 100 g/L in H2O, suspension)
bp350 ℃/1013 hPa
mp99 ℃
转变温度flash point 212 ℃
密度1.36 g/cm3 at 20 ℃
堆积密度500 kg/m3
储存温度2-30℃
InChI1S/C6H5N3/c1-2-4-6-5(3-1)7-9-8-6/h1-4H,(H,7,8,9)
InChI keyQRUDEWIWKLJBPS-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H411
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)338.0 °F - closed cup
闪点(C)170 ℃ - closed cup
V900003Sigma-AldrichBenzotriazoleVetec, reagent grade, 98%113元/500 G;   186.39元/100 G;   展开

产品说明

包装

100, 500 g in poly bottle

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

经验(实验)分子式C6H5N3
分子量119.12
Beilstein112133
EC 号202-394-1
MDL编号MFCD00005699
PubChem化学物质编号329829438

产品性质

等级reagent grade
蒸汽密度4.1 (vs air)
蒸汽压0.04 mmHg ( 20 ℃)
产品线Vetec
测定98%
mp97-99 ℃ (lit.)
SMILES stringc1ccc2[nH]nnc2c1
InChI1S/C6H5N3/c1-2-4-6-5(3-1)7-9-8-6/h1-4H,(H,7,8,9)
InChI keyQRUDEWIWKLJBPS-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H411
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)338.0 °F - closed cup
闪点(C)170 ℃ - closed cup
579202AmethystBenzotriazole99%, 试剂级67元/100G;   145元/500G;   展开

基本信息

分子式C6H5N3
分子量119.12
熔点97-99
沸点204
闪点170
MDL编码MFCD00005699
Beilstein112133
Merck14,1108
EINECS 编号202-394-1

安全信息

图形或危害标志
提示语Warning
危险说明H302
H319
H332
H412
防范说明P273
P305+P351+P338
WGK1
RTECSDM1225000
TSCA
BR1010FluorochemBenzotriazole fine powder99.8%440元/250g;   924元/1kg;   展开

基本信息

CAS Number95-14-7
MDL NumberMFCD00005699
Boiling Point204℃
Melting Point94-100℃
Density1.36

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H411: Toxic to aquatic life with long lasting effects.
防范说明 P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P391: Collect spillage.
P501: Dispose of contents/container to local regulations.
BR1010CFluorochemBenzotriazole Needle Crystal99.8%770元/1kg;   展开

基本信息

CAS Number95-14-7
MDL NumberMFCD00005699
Boiling Point204℃
Melting Point97℃
Density1.36

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H412: Harmful to aquatic life with long lasting effects.
防范说明 P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P501: Dispose of contents/container to local regulations.
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