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CAS: 940880-69-3
分子式: C35H30N2O2
分子量: 510.62
中文名称: 
(S)-7,7双[(4S)-(苯基)恶唑-2-基)-2,2,3,3-四氢-1,1,6,6'-二醇
(S)-7,7’-bis[(4S)-(phenyl)oxazol-2-yl)]-2,2’,3,3’-tetrahydro-1,1’-spirobiindane
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货号品牌产品名称规格包装、参考价格详情
S906645MACKLIN(4S,4'S)-2,2'-[(1R)-2,2',3,3'-四氢-1,1'-螺二[1H-茚]-7,7'-二基]双[4,5-二氢-4-苯基恶唑]98%1972元/50mg;   展开
储存:2-8°C
07-5195Strem(S)-7,7’-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2’,3,3’-tetrahydro-1,1’-spirobiindanemin. 97%900元/25mg;   2685元/100mg;   展开

Technical Notes:

1.Chiral ligands for copper- catalyzed asymmetric insertions of carbenoids into N- H bond of anilines.

2.Chiral ligands for copper or palladium-catalyzed asymmetric insertions of carbenoids into o -H bond of phenols.

3.Chiral ligands for copper or iron-catalyzed asymmetric insertions of carbenoids into o H bond of water.

4.Chiral ligands for copper-catalyzed asymmetric insertions of carbenoids into S-H bonds of arylmethylene mercaptans.

References: 1.J. Am. Chem. Soc. 2007. 129, 5834 5835 2.J.Am. Chem.Soc.2012, 134 436442. 3.J. Am. Chem. Soc. 2007. 129, 12616 -12617. 4.Angew. Chem., Int. Ed.. 2013, 52, 2555. 5.Angew. Chem., Int. Ed., 2014, 53, 2978 6.Angew. Chem. Int. Ed., 2008, 47, 932 -934. 7.Nature Chemistry, 2010, 2, 546 551. 8.Chem. Commun.. 2009, 5362.
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