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CAS: 94-66-6
分子式: C9H14O
分子量: 138.20
沸点: 94℃(23 t
中文名称: 
2-丙烯基环已酮
英文名称: 
2-(2-propenyl)-cyclohexanon
2-allylcyclohexanone
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A865380MACKLIN2-烯丙基环己-1-酮97%147元/1g;   561元/5g;   展开
储存:室温,干燥
状态:无色到浅黄色到浅橙色澄清液体
A2230TCI2-Allylcyclohexanone>97.0%(GC)620元/5G;   1850元/25G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C9H14O = 138.21
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN1859919
PubChem物质ID87561001
MDL编号MFCD00043548

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点94 ℃/23 mmHg
比重0.94
折射率1.47

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
206539J&K2-Allylcyclohexanone97%233元/1G;   931元/5G;   2328元/25G;   展开

基本信息

分子式C9H14O
分子量138.21
沸点94
闪点109
密度0.927
折光率(n20D)1.4690
MDL编码MFCD00043548
Beilstein1859919
EINECS 编号202-352-2

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H315
H319
H332
H335
防范说明P261
P280
P305+P351+P338
WGK3
RTECSAH3600000
TSCA
405752Sigma-Aldrich2-Allylcyclohexanone97%2056.1元/5 G;   展开

产品说明

一般描述

2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied.

应用

2-Allylcyclohexanone may be used in the synthesis of the following:

  • bicyclo[3.3.1]non-2-en-9-one
  • R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis

包装

1, 5 g in glass bottle

基本信息

线性分子式H2C=CHCH2C6H9(=O)
分子量138.21
EC 号202-352-2
MDL编号MFCD00043548
PubChem化学物质编号24865329
NACRESNA.22

产品性质

质量水平100
测定97%
折射率n20/D 1.469 (lit.)
bp94 ℃/23 mmHg (lit.)
密度0.927 g/mL at 25 ℃ (lit.)
SMILES stringC=CCC1CCCCC1=O
InChI1S/C9H14O/c1-2-5-8-6-3-4-7-9(8)10/h2,8H,1,3-7H2
InChI keyUPGHEUSRLZSXAE-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 + H312 + H332 - H315 - H319 - H335
预防措施声明P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
047760Fluorochem2-Allylcyclohexanone95%1518元/10g;   6072元/50g;   展开

基本信息

CAS Number94-66-6
MDL NumberMFCD00043548
Boiling Point94 ℃
Density0.927

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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