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CAS: 94-53-1
分子式: C8H6O4
分子量: 166.13
熔点: 229-231℃
中文名称: 
哌呢酸
胡椒基酸
3,4-亚甲基二氧基苯甲酸
英文名称: 
1,3-benzodioxole-5-carboxylic acid
3,4-dioxymethylenebenzoic acid
3,4-methylene dioxybenzoic acid
5-benzodioxolecarboxylic acid
heliotropic acid
piperonylic acid
性质描述: 白色棱状或针状结晶。熔点229℃。微溶于水、氯仿、冷乙醇、乙醚。
生产方法: 胡椒醛用高锰酸钾在70-80℃氧化,以90-96%的产率得到胡椒基酸。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P831313MACKLIN胡椒酸98%30元/5g;   55元/25g;   189元/100g;   795元/500g;   展开
储存:室温,密封
状态:白色到黄色和米黄色粉末,晶体或块状
P0459TCIPiperonylic Acid>98.0%(GC)(T)550元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C8H6O4 = 166.13
外观与形状(20℃)固体
Reaxys-RN150206
PubChem物质ID87574653
Merck Index (14)7477
MDL编号MFCD00005830

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点230 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#DF4912765
242538J&KPiperonylic Acid99%77元/5G;   236元/25G;   623元/100G;   展开

基本信息

分子式C8H6O4
分子量166.13
熔点229-231
MDL编码MFCD00005830
Beilstein150206
Merck14,7477
EINECS 编号202-342-8

安全信息

图形或危害标志
提示语Danger
危险说明EUH070
H302
H315
H318
H335
防范说明P261
P280
P305+P351+P338
WGK3
RTECSDF4912765
TSCA
A14105Alfa AesarPiperonylic Acid98+%1256元/25g;   4181元/100g;   19407元/500g;   展开

应用
Piperonylic acid is used as pharmaceutical intermediate.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00005830

EINECS
202-342-8

分子式
C8H6O4

分子量
166.13

熔点
230-235°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Slightly soluble in water.

Beilstein
150206

Merck
14,7477

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
DF4912765

TSCA

C13137Alfa AesarPiperonylic Acid99%633元/5g;   3410元/25g;   13030元/100g;   展开

基本信息

Ref#
13137

MDL
5830

分子式
C8 H6 O4

分子量
166.13

P49805Sigma-AldrichPiperonylic Acid99%573.19元/5 G;   802.37元/25 G;   展开

基本信息

经验(实验)分子式C8H6O4
分子量166.13
Beilstein150206
EC 号202-342-8
MDL编号MFCD00005830
PubChem化学物质编号24898575
NACRESNA.22

产品性质

质量水平100
测定99%
mp229-231 ℃ (lit.)
SMILES stringOC(=O)c1ccc2OCOc2c1
InChI1S/C8H6O4/c9-8(10)5-1-2-6-7(3-5)12-4-11-6/h1-3H,4H2,(H,9,10)
InChI keyVDVJGIYXDVPQLP-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
022643Fluorochem3,4-(Methylenedioxy)benzoic Acid98%220元/1g;   220元/10g;   440元/25g;   1408元/100g;   展开

基本信息

CAS Number94-53-1
MDL NumberMFCD00005830

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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