CAS 930601-66-4; 乙腈(环戊二烯基)[2(-(二-异丙基膦基)-4-(叔丁基)-1-甲基-1h-咪唑]钌(ii)六氟磷酸盐; acetonitrile(cyclopentadienyl)[2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1h-imidazole]ruthenium(ii) hexafluorophosphate

CAS:

930601-66-4

中文名称:

乙腈(环戊二烯基)[2(-(二-异丙基膦基)-4-(叔丁基)-1-甲基-1h-咪唑]钌(ii)六氟磷酸盐

英文名称:

acetonitrile(cyclopentadienyl)[2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1h-imidazole]ruthenium(ii) hexafluorophosphate

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货号	品牌	产品名称	规格	包装、参考价格	详情
44-0017	Strem	Acetonitrile(cyclopentadienyl)[2-(di-i-propylphosphino)-4-(t-butyl)-1-methyl-1H-imidazole]ruthenium(II) hexafluorophosphate	min. 98%	1605元/100mg; 6420元/500mg;	展开
Technical Note: 1."Zipper" catalyst for alkene isomerization over up to 30 double bond positions (Ref. 1). Selective isomerization over one position also possible (Ref. 2, 3). Depending on substrate structure, H/D exchange at accessible allylic positions can be accompanied by is omerization (Ref. 4). References : 1. J Am. Chem. Soc..2007, 129, 9592. 2.Topics in Catalysis, 2010, 53, 1015. 3. J. Am. Chem. Soc.2012, 134, 10357.

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