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CAS: 930-27-8
分子式: C5H6O
分子量: 82.10
沸点: 65-66℃
中文名称: 
3-甲基呋喃
β-甲基呋喃
英文名称: 
3-methyl-furan
3-methyl-fura
3-methylfuran
性质描述: 无色液体。沸点为65.5℃,相对密度0.932(18/4℃),折光率1.4255(18℃)。溶于乙醇和乙醚,不溶于水。
生产方法: 由3-甲基-2-呋喃羧酸加入干燥的喹啉中,加铜粉作催化剂。加热至约250℃,喹啉呈沸腾状态,反应逸出二氧化碳。反应后进行蒸馏,即得3-甲基呋喃,收率约85%。
用途: 有作有机合成中间体和溶剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M862541MACKLIN3-甲基呋喃(含稳定剂HQ)≥98%(GC)140元/250mg;   390元/1g;   1235元/5g;   3800元/25g;   展开
储存:2-8°C
状态:无色到几乎无色澄清液体
M0939TCI3-Methylfuran (stabilized with HQ)>98.0%(GC)1705元/1G;   5490元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C5H6O = 82.10
外观与形状(20℃)液体
储存温度0-10℃
应避免的情况加热
Reaxys-RN104217
PubChem物质ID87572921
SDBS (AIST Spectral DB)9353
MDL编号MFCD00060134

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点66 ℃
闪点-21 ℃
比重0.92
折射率1.43

安全信息

图形或危害标志
信号词危险
危险性说明H332 : 吸入有害。
H412 : 对水生生物有害并具有长期持续影响。
H225 : 高度易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P273 : 避免释放到环境中。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P271 : 只能在室外或通风良好之处使用。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#LU2630000

运输信息

UN编号UN1993
类别3
包装类别 II
监管条件代码(*)
273135J&K3-Methylfuran98%1473元/1G;   展开

基本信息

分子式C5H6O
分子量82.10
沸点65 -66
闪点-22
密度0.92
折光率(n20D)1.4310-1.4330
MDL编码MFCD00060134
Beilstein104217
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H225
H301
H311
防范说明P210
P240
P301+P310
P304+P340
UN号码1993
危险分类3
包装等级II
RTECSLU2630000
CDS019631Sigma-Aldrich3-MethylfuranAldrichCPR1487.65元/100 MG;   展开

产品说明

其他说明

Please note that sigma-aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. sigma-aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.
NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.

基本信息

经验(实验)分子式C5H6O
分子量82.10
MDL编号MFCD00060134
PubChem化学物质编号329792987

产品性质

SMILES stringCc1ccoc1
InChI1S/C5H6O/c1-5-2-3-6-4-5/h2-4H,1H3
InChI keyKJRRQXYWFQKJIP-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H302 - H331
预防措施声明P301 + P312 + P330 - P304 + P340 + P311
危险分类Acute Tox. 3 Inhalation - Acute Tox. 4 Oral
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)No data available
闪点(C)No data available
005088Fluorochem3-Methylfuran (stabilised with Hydroquinone)98%1738元/1g;   展开

基本信息

CAS Number930-27-8
MDL NumberMFCD00060134
Density0.92

安全信息

图形或危害标志
危险性说明 H225: Highly flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or powdered extinguishing agent for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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