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CAS: 93-98-1
分子式: C13H11NO
分子量: 197.23
中文名称: 
苯甲酰苯胺
N-苯甲酰苯胺
苯甲酰替苯胺
N-苯基苯甲酰胺
英文名称: 
N-phenyl-benzamide
Benzanilid
N-benzoyl-aniline
Benzoylanilide
N-Phenylbenzamide
N-Phenylbenzoic acid amide
Benzamide,N-phenyl-
N-Benzoylaniline
n-phenyl-benzamid
benzanilide
性质描述: 无色或白色片状结晶。熔点162-164℃,沸点117℃(1.33kPa),相对密度1.135。几乎不溶于水,溶于乙醇,微溶于乙醚。能升华。
生产方法: 由苯胺与苯甲酸反应而得。将干燥的苯甲酸和新蒸过的苯胺在180-190℃反应2h,然后提高温度至225℃。开始时在反应过程蒸出水,随后蒸出苯胺,最后将馏分全部蒸出。将255℃以后蒸出的馏分冷却凝固,磨碎,得紫灰色粗品。粗品用稀盐酸洗涤除去剩余的苯胺,用水洗涤后再加氢氧化钠溶液除去剩余的苯甲酸。最后水洗,过滤,干燥,用乙醇重结晶而得精制的成品。
用途: 有机合成中间体,用于药物、染料、香料的生产。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B830232MACKLIN苯甲酰苯胺98%37元/5g;   83元/25g;   223元/100g;   952元/500g;   3709元/2.5kg;   展开
储存:室温,密封
状态:白色到灰色到黄绿色粉末
B0016TCIBenzanilide>98.0%(GC)130元/25G;   990元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C13H11NO = 197.24
外观与形状(20℃)固体
Reaxys-RN1102980
PubChem物质ID87563230
SDBS (AIST Spectral DB)7176
Merck Index (14)1061
MDL编号MFCD00003069

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Melting point163.0 to 167.0 ℃

物性(参考值)

熔点166 ℃
260322J&KBenzanilide98%1667元/1KG;   展开

基本信息

分子式C13H11NO
分子量197.24
熔点161-163
沸点117
MDL编码MFCD00003069
Beilstein1102980
Merck14,1061
EINECS 编号202-292-7

安全信息

WGK3
TSCA
A11086Alfa AesarBenzanilide98+%592元/100g;   2516元/500g;   展开

应用
Benzanilide is used to make dyes, active pharmaceutical ingredients and perfumes. It is also used to study the influence of beta-cyclodextrin on photorearrangement of acetanilide, benzanilide and ethyl phenyl carbonate. Further, it is used as an amide model compound to study the reaction between the amide and epoxy. In addition to this, it reacts with aryltriflates in the presence of palladium-based catalyst system to get N-(2,6-diarylbenzoyl)anilines.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003069

EINECS
202-292-7

分子式
C6H5NHCOC6H5

分子量
197.24

熔点
162-166°

沸点
117°/10mm

密度
1.32

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in diethyl ether. Insoluble in water.

Beilstein
1102980

Merck
14,1061

安全信息

TSCA

C14855Alfa AesarBenzanilide98%363元/50g;   318元/5g;   1037元/250g;   3189元/1kg;   展开

基本信息

Ref#
14855

MDL
3069

分子式
C13 H11 N O

分子量
197.24

形态
White to pale cream powder

108227Sigma-AldrichBenzanilide98%237.36元/5 G;   447.21元/100 G;   展开

产品说明

一般描述

苯甲酰苯胺在钯催化系统下与芳基三氟甲磺酸酯或溴化物发生二芳基化反应生成相应的的 N-(2,6-二芳基苯甲酰基)苯胺 。它用于制造染料和香水。

应用

用苯甲酰苯胺研究 β-环糊精对乙酰苯胺、苯甲酰苯胺和碳酸乙酯的光重排反应的影响 。它被用作酰胺模型化合物来研究酰胺与环氧化合物的反应 。

包装

100 g in poly bottle
5 g in glass bottle

基本信息

线性分子式C6H5CONHC6H5
分子量197.23
颜色索引号42095
Beilstein1102980
EC 号202-292-7
MDL编号MFCD00003069
PubChem化学物质编号24846656
NACRESNA.22

产品性质

质量水平100
测定98%
bp117 ℃/10 mmHg (lit.)
mp161-163 ℃ (lit.)
溶解性H2O: insoluble
diethyl ether: slightly soluble
SMILES stringO=C(Nc1ccccc1)c2ccccc2
InChI1S/C13H11NO/c15-13(11-7-3-1-4-8-11)14-12-9-5-2-6-10-12/h1-10H,(H,14,15)
InChI keyZVSKZLHKADLHSD-UHFFFAOYSA-N
Gene Informationhuman ... EPHX2(2053)
mouse ... Ephx2(13850)

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
242653FluorochemN-Phenylbenzamide95%330元/25g;   1474元/500g;   展开

基本信息

CAS Number93-98-1
MDL NumberMFCD00003069
Melting Point166℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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