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CAS: 93-91-4
分子式: C10H10O2
分子量: 162.18
沸点: 260-262°C
熔点: 54-58℃
中文名称: 
苯甲酰丙酮
1-苯基-1,3-丁二酮
1-苯基丁二酮-[1,3],α-乙酰苯乙酮
乙酰苯甲酰甲烷
英文名称: 
1-phenyl-butane-1,3-dione
1-Phenyl-1,3-butane dione
1,3-Butanedione,1-phenyl-
1-Phenyl-1,3-butanedione
Methyl phenacyl ketone
Acetyl benzoyl methane
-Acetyl acetophenone
1-Phenyl-1,3-bu-tanedione
Benzoylpropanone
HBA
Benzoylacetone
3-Butanedione, 1-phenyl-1
1-phenyl-3-butanedione
2-acetylacetophenone
acetoacetophenone
acetylbenzoylmethane
alpha-acetylacetophenone
benzoyl-aceton
1-benzoylacetone
展开更多英文名
性质描述: 无色结晶,熔点61℃,沸点261-262℃,相对密度1.090(60/4℃),折光率1.5678(77.8℃),难溶于水,易溶于苯、氯仿、四氯化碳、醇、醚及浓碱溶液,有持久的刺激性气味。
生产方法: 1.苯乙酮和乙酸乙酯反应将6g乙醇钠在冷却下加入20g乙酸乙酯,15min后再加入10g苯乙酮。当苯甲酰丙酮开始析出时,加入少量无水乙醚,4h后过滤,用乙醚洗涤、干燥。然后将其溶于水,用乙酸酸化即分离出苯甲酰丙酮10g。2.苯乙酮与乙酐反应将20g苯乙酮和34g乙酐,在冷却下加入乙酸钠(45g乙酸钠溶于100ml水)。然后用三氟化硼使其成饱和溶液。用水蒸气蒸馏,开始为油状物,冷却后则析出结晶,用乙醚萃取,干燥后再蒸馏得产品22.5g。3.苯甲酰氯与乙酰乙酸乙酯反应在溶剂乙醚中,苯甲酰氯与乙酰乙酸乙酯钠反应得到苯甲酰乙酰乙酸乙酯,再加水回流5小时,用水蒸气蒸馏得到苯甲酰丙酮。
用途: 分析试剂。优良的螯合萃取剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802179MACKLIN苯甲酰丙酮98%38元/5g;   156元/25g;   615元/100g;   3005元/500g;   展开
储存:室温
状态:白色到黄色到棕褐色粉末,晶体或块状
P0160TCI1-Phenyl-1,3-butanedione>98.0%(GC)335元/25G;   1155元/100G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C10H10O2 = 162.19
外观与形状(20℃)固体
Reaxys-RN742413
PubChem物质ID87574410
SDBS (AIST Spectral DB)5801
MDL编号MFCD00008786

技术规格

AppearanceWhite to Light yellow powder to crystaline
Purity(GC)min. 98.0 %
Melting point57.0 to 60.0 ℃
Solubility in Methanolalmost transparency

物性(参考值)

熔点57 ℃
沸点262 ℃

相关法规

RTECS#EK3540200
401915J&K1-Phenyl-1,3-butanedione98%99元/10G;   402元/50G;   1775元/250G;   5662元/1KG;   展开

基本信息

分子式C10H10O2
分子量162.19
熔点54-56
密度1.09
MDL编码MFCD00008786
Beilstein742413
EINECS 编号202-286-4

安全信息

WGK3
RTECSEK3540200
TSCA
A14537Alfa AesarBenzoylacetone98+%677元/50g;   9626元/1000g;   展开

应用
Benzoylacetone has been used as a 1,3-dicarbonyl compound model for studying keto-enol equilibria in aqueous acid and micellar solutions. Additionally, it has been studied using gas-phase electron diffraction and quantum chemistry. It is used as pharmaceutical intermediates.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00008786

EINECS
202-286-4

分子式
C10H10O2

分子量
162.19

熔点
55-60°

沸点
260-262°

密度
1.090

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Insoluble in water.

Beilstein
742413

安全信息

RTECS
EK3540200

TSCA

C10569Alfa Aesar1-Benzoylacetone98%2706元/50g;   13198元/250g;   展开

基本信息

Ref#
10569

MDL
8786

分子式
C10 H10 O2

分子量
162.19

密度
1.09

B11907Sigma-Aldrich1-Phenyl-1,3-butanedione99%1027.24元/10 G;   1477.78元/50 G;   3669.7元/250 G;   展开

基本信息

线性分子式C6H5COCH2COCH3
分子量162.19
Beilstein742413
EC 号202-286-4
MDL编号MFCD00008786
PubChem化学物质编号24891568
NACRESNA.22

产品性质

质量水平100
测定99%
mp54-56 ℃ (lit.)
密度1.09 g/mL at 25 ℃ (lit.)
SMILES stringCC(=O)CC(=O)c1ccccc1
InChI1S/C10H10O2/c1-8(11)7-10(12)9-5-3-2-4-6-9/h2-6H,7H2,1H3
InChI keyCVBUKMMMRLOKQR-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
106600FluorochemBenzoyl acetone98%220元/1g;   330元/10g;   550元/25g;   1320元/100g;   展开

基本信息

CAS Number93-91-4
MDL NumberMFCD00008786
Boiling Point260-262℃
Melting Point58-60℃
Density1.09

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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