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CAS: 93-61-8
分子式: C8H9NO
分子量: 135.17
沸点: 243-244℃
熔点: 8-13℃
中文名称: 
N-甲基富马胺
N-甲基甲酰苯胺
N-甲酰-N-甲基苯胺
N-苯基-N-甲基甲酰胺
英文名称: 
n-methyl-n-phenyl-formamid
n-methylformanilide
N-methyl-N-phenyl-formamide
Formamide,N-methyl-N-phenyl-
N-Formyl-N-methylaniline
性质描述: 无色液体。熔点为14-15℃,沸点243℃,131℃(2.93kPa),128-129℃(2.0kPa),相对密度1.0948(20/4℃),折光率1.5589,闪点126℃。溶于乙醇、乙醚和丙酮,微溶于水。
生产方法: 1.由N-甲酰苯胺与硫酸二甲酯反应而得。将N-甲酰苯胺和硫酸二甲酯混合,搅拌冷却下滴加氢氧化钾溶液,温度控制在15℃以下。滴加完毕,在20-25℃继续搅拌1h,反应混合物呈微碱性。慢慢滴加浓氨水,分解过量的硫酸二甲酯。然后静置分层,取上层油状物减压蒸馏,收集130-133℃(2.13kPa)馏分,即为N-甲基甲酰苯胺,收率为90%左右。2.由N-甲基苯胺与甲酸反应而得。将N-甲基苯胺、甲酸和甲苯混合,加热蒸馏,蒸出水分后,温度升到108-110℃蒸出甲苯。将剩余物进行减压蒸馏,即得成品。
用途: 用作有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N813257MACKLIN甲基甲酰苯胺99%32元/25g;   62元/100g;   175元/500g;   688元/2.5kg;   展开
储存:室温
状态:无色到黄色到棕色液体
折射率:n20/D 1.561(lit.)
N742956MACKLIN甲基甲酰苯胺Standard for GC, ≥99.6%(GC)128元/5g;   展开
储存:室温
状态:液体
M0552TCIN-Methylformanilide>99.0%(GC)135元/25G;   245元/100G;   720元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C8H9NO = 135.17
外观与形状(20℃)液体
Reaxys-RN636496
PubChem物质ID87572585
SDBS (AIST Spectral DB)1286
MDL编号MFCD00003283

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 99.0 %

物性(参考值)

熔点14 ℃
沸点243 ℃
闪点129 ℃
比重1.10

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
557037J&KN-Methylformanilide99%149元/100G;   596元/500G;   1082元/1KG;   展开

基本信息

分子式C8H9NO
分子量135.17
熔点8-13
沸点243-244
闪点127
密度1.095
折光率(n20D)1.5610
MDL编码MFCD00003283
Beilstein636496
EINECS 编号202-262-3

安全信息

图形或危害标志
提示语Warning
危险说明H302
H317
H319
防范说明P280
P305+P351+P338
WGK2
TSCA
A11829Alfa AesarN-Methylformanilide99%908元/250g;   1590元/500g;   6858元/2500g;   25346元/10000g;   展开

应用
N-Methylformanilide is used as a formylating reagent for certain organometallics. It is in combination with phosphoryl chloride used for Vilsmeier-Haack reactions and in heterocycle syntheses. Further, it acts as a swelling agent in the dyeing process of meta-aramid fibers.

备注
Incompatible with oxidizing agents.

基本信息

MDL
MFCD00003283

EINECS
202-262-3

分子式
C8H9NO

分子量
135.17

熔点
9-13°

沸点
242-244°

闪点
126°(258°F)

密度
1.095

折射率
1.5610

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Immisible with water.

Beilstein
636496

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H317
Harmful if swallowed.May cause an allergic skin reaction.

Precautionary Statements
P261-P280g-P301+P312a-P321-P333+P313-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves.Wear protective gloves.Specific treatment (see label).If skin irritation or rash occurs: Get medical advice/attention.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-43
Harmful if swallowed.May cause sensitization by skin contact.

安全等级
23-24-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).Avoid contact with skin.Avoid contact with skin.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C12681Alfa AesarN-Methylformanilide99%621元/100g;   1433元/500g;   3669元/1kg;   26766元/10kg;   展开

基本信息

Ref#
12681

MDL
3283

分子式
C8 H9 N O

分子量
135.17

闪点
126

密度
1.09

M46802Sigma-AldrichN-Methylformanilide99%468.9元/100 G;   999.96元/500 G;   展开

基本信息

线性分子式HCON(CH3)C6H5
分子量135.16
Beilstein636496
EC 号202-262-3
MDL编号MFCD00003283
PubChem化学物质编号24896936
NACRESNA.22

产品性质

测定99%
折射率n20/D 1.561 (lit.)
bp243-244 ℃ (lit.)
mp8-13 ℃ (lit.)
密度1.095 g/mL at 25 ℃ (lit.)
SMILES stringCN(C=O)c1ccccc1
InChI1S/C8H9NO/c1-9(7-10)8-5-3-2-4-6-8/h2-7H,1H3
InChI keyJIKUXBYRTXDNIY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P280 - P301 + P312 + P330 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)260.6 °F - closed cup
闪点(C)127 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
8.06169Sigma-AldrichN-Methylformanilidefor synthesis508.16元/250 ML;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.094 - 1.096
Identity (IR): passes test

基本信息

线性分子式HCON(CH3)C6H5
分子量135.16
MDL编号MFCD00003283
EC索引号202-262-3

产品性质

质量水平200
蒸汽压2.66 Pa ( 25 ℃)
测定≥98.0% (GC)
pH值(酸碱度)3.5-5.5 (20 ℃ in H2O, saturated aqueous solution)
bp243-244 ℃/1013 hPa
mp8-13 ℃
转变温度flash point 126 ℃
密度1.095 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C8H9NO/c1-9(7-10)8-5-3-2-4-6-8/h2-7H,1H3
InChI keyJIKUXBYRTXDNIY-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H317
预防措施声明P261 - P264 - P270 - P280 - P301 + P312 - P302 + P352
危险分类Acute Tox. 4 Oral - Skin Sens. 1
储存分类代码10 - Combustible liquids
WGKWGK 2
闪点(F)260.6 °F - closed cup
闪点(C)127 ℃ - closed cup
964373AmethystN-Methylformanilide99%, 用于合成40元/25G;   85元/100G;   275元/500G;   1098元/2.5KG;   展开

基本信息

分子式C8H9NO
分子量135.17
熔点8-13
沸点243-244
闪点127
密度1.095
折光率(n20D)1.557 - 1.563
MDL编码MFCD00003283
Beilstein636496
EINECS 编号202-262-3

安全信息

图形或危害标志
提示语Warning
危险说明H302
H317
H319
防范说明P280
P305+P351+P338
WGK2
TSCA
208822FluorochemN-Methylformanilide95%286元/100g;   1210元/500g;   展开

基本信息

CAS Number93-61-8
MDL NumberMFCD00003283
Boiling Point243℃
Melting Point14℃
Density1.1

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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