| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| S854200 | MACKLIN | (S)-3,3'-双(三苯基硅基)联萘酚膦酸酯 | 98%,99%e.e. | 212元/100mg; 457元/250mg; 1778元/1g; 8195元/5g; | 咨询 |
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| 1476982 | J&K | (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate | 96% | 1619元/50MG; 3188元/100MG; | 咨询 |
基本信息 | 分子式 | C56H41O4PSi2 | | 分子量 | 865.07 | | 熔点 | 188-193 | | 比旋光度([α]20D) | +150 to +170 (C=1, CHCl3, 22℃) | | MDL编码 | MFCD09265079 |
安全信息 | 图形或危害标志 |  | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 |
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| 15-0341 | Strem | (S)-(+)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate | min. 98% | 945元/10mg; 7170元/100mg; | 咨询 |
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| Y14308 | Alfa Aesar | (S)-3,3'-Bis(triphenylsilyl)-1,1'-binaphthalene-2,2'-diyl hy | | 2402元/100mg; | 咨询 |
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| 680184 | Sigma-Aldrich | (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate | 96% | 2523.34元/100 MG; | 咨询 |
产品说明 应用 (S)-3,3′-Bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate can be used as a catalyst:
- In the synthesis of 1,3-dioxolochroman skeletons by reacting 3-methyl-2-vinylindoles with ortho-quinone methides.
- In the exo-selective cyclization of mupirocin methyl ester.
- In the kinetic resolution of cyclic aliphatic syn-1,3-diols, which are used as valuable building blocks.
包装 100 mg in clear glass bottle 基本信息 | 经验(实验)分子式 | C56H41O4PSi2 | | 分子量 | 865.07 | | MDL编号 | MFCD09265079 | | PubChem化学物质编号 | 24885544 | | NACRES | NA.22 |
产品性质 | 测定 | 96% | | 旋光性 | [α]22/D +210°, c = 1 in chloroform | | mp | 188-193 ℃ | | SMILES string | OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)[Si](c6ccccc6)(c7ccccc7)c8ccccc8)[Si](c9ccccc9)(c%10ccccc%10)c%11ccccc%11 | | InChI | 1S/C56H41O4PSi2/c57-61(58)59-55-51(62(43-25-7-1-8-26-43,44-27-9-2-10-28-44)45-29-11-3-12-30-45)39-41-23-19-21-37-49(41)53(55)54-50-38-22-20-24-42(50)40-52(56(54)60-61)63(46-31-13-4-14-32-46,47-33-15-5-16-34-47)48-35-17-6-18-36-48/h1-40H,(H,57,58) | | InChI key | BDQOCXQVIFQJRK-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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