CAS 922711-75-9; (11br)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二甲基-2-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英; (11br)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

CAS:

922711-75-9

分子式:

C₄₀H₃₃O₄P

分子量:

608.7

熔点:

＞350°C

中文名称:

(11br)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二甲基-2-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英

英文名称:

(11br)-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

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货号	品牌	产品名称	规格	包装、参考价格	详情
R854235	MACKLIN	(R)-3,3'-双(2-萘基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘酚膦酸酯	98%	174元/25mg; 320元/100mg; 638元/250mg; 2438元/1g;	展开
储存：室温,干燥
15-1378	Strem	(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin	98%, (99% ee)	1530元/25mg; 4590元/100mg;	展开
Technical Notes: 1.The preparation of binaphthol monophosphoric acid derivatives. 2.Organocatalyst developed for the diastereo- and enantioselective 1 4-conjugate addn. of a variety of ß-ketoesters to nitroolefins, employed in the addn. re action, providing the corre sponding nitroalkanes in high yield (up to 97%) with moderate diastereoselectivities (up to 2.6:1 dr) and enantioselectivities (up to 58% ee). References: 1.JP 4725757, EP 1038877, US 6274745, 2000-3-21. 2. Lett. in Org. Chem., 2010, 7, 219-225.