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CAS: 92136-39-5
分子式: C8H13NO2
分子量: 155.2
熔点: 40-44 °C
中文名称: 
n-(叔丁氧羰基)炔丙胺
n-boc-炔丙胺
2-丙烯基氨基甲酸叔丁酯
英文名称: 
n-(tert-butoxycarbonyl)propargylamine
n-boc-propargylamine
tert-butyl 2-propynylcarbamate
2-propynylcarbamic acid tert-butyl ester
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N836841MACKLINN-BOC-炔丙基铵97%29元/1g;   45元/5g;   210元/25g;   750元/100g;   展开
储存:2~8 °C,密封,干燥
状态:黄色到棕色固体
B4472TCIN-(tert-Butoxycarbonyl)propargylamine>98.0%(GC)220元/1G;   700元/5G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H13NO2 = 155.20
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,加热
Reaxys-RN4306103
PubChem物质ID253662096
MDL编号MFCD07367245

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(GC)min. 98.0 %
Melting point40.0 to 44.0 ℃

物性(参考值)

熔点42 ℃
沸点170 ℃/14 mmHg
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
H53406Alfa AesarN-Boc-propargylamine97%709元/1g;   2655元/5g;   8688元/25g;   展开

应用
N-Boc-propargylamine is used to prepare triazolobenzylidene-thiazolopyrimidines. which act as CDC25 phosphatase inhibitors. Further, it is used for the synthesis of beta-glucan polysaccharide analogs. In addition to this, it is involved in the Pauson-Khand (PK) reaction of norbornadiene and N-Boc-propargylamine to prepare 4,5-disubstituted cyclopentenones .

备注
Moisture sensitive. Incompatible with oxidizing agents. Store in a cool place.

基本信息

MDL
MFCD07367245

分子式
C8H13NO2

分子量
155.20

熔点
40-44°

闪点
93°(199°F)

灵敏度
Keep Cold. Moisture Sensitive. Store under Nitrogen.

形态
Solid

溶解性
Soluble in chloroform.

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335-H402-H412
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Harmful to aquatic life.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38-52/53
Harmful if swallowed.Irritating to eyes, respiratory system and skin.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-36/37-60-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA

687146Sigma-AldrichN-Boc-propargylamine97%931.54元/5 G;   展开

基本信息

经验(实验)分子式C8H13NO2
分子量155.19
MDL编号MFCD07367245
PubChem化学物质编号329761104

产品性质

质量水平100
测定97%
mp40-44 ℃
储存温度2-8℃
SMILES stringCC(C)(C)OC(=O)NCC#C
InChI1S/C8H13NO2/c1-5-6-9-7(10)11-8(2,3)4/h1H,6H2,2-4H3,(H,9,10)
InChI keyDSPYCWLYGXGJNJ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)199.9 °F
闪点(C)93.3 ℃
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
040190FluorochemN-Boc-Prop-2-ynylamine97%286元/1g;   880元/5g;   2684元/25g;   8184元/100g;   展开

基本信息

CAS Number92136-39-5
MDL NumberMFCD07367245
Melting Point40-44℃

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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