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CAS: 92-69-3
分子式: C12H10O
分子量: 170.21
沸点: 307℃
熔点: 163℃
中文名称: 
对苯基苯酚
(1,1'-二苯基)-4-酚
4-羟基联苯
对羟基联苯
对苯基酚
4-苯基酚
英文名称: 
[1,1'-biphenyl]-4-ol
4-hydroxy-bipheny
p-biphenylol
p-hydroxybiphenyl
p-hydroxydiphenyl
para-hydroxydiphenyl
para-phenylphenol
para-xenol
paraxenol
tetrosin p 300
biphenyl-4-ol
4-Hydroxy-biphenyl
4-hydroxy diphenyl
l,l-biphenyl,hydroxyderivs
p-Phenylphenol
(1,1'-Biphenyl)-4-ol
4-Hydroxydiphenyl
4-biphenylol
4-diphenylol
4-hydroxybiphenyl
4-phenylphenol
展开更多英文名
性质描述: 白色针状或片状结晶。熔点164-165℃,沸点305-308℃。闪点165℃。易溶于醇和醚,溶于碱溶液。能升华。
生产方法: 可从磺化法生产苯酚的蒸馏残渣中回收。
用途: 用作染料、树脂和橡胶的中间体。该品合成的红光增感、绿光增感染料是彩色影片的主要原料之一,也用作分析试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P997313MACKLIN对羟基联苯试液15mg/ml198元/100ml;   展开
储存:室温, 避光
状态:液体
P787427MACKLIN对羟基联苯标准溶液100μg/mL in Methanol278元/1ml;   展开
储存:2-8°C
P787428MACKLIN对羟基联苯标准溶液1000μg/mL in Methanol307元/1ml;   展开
储存:2-8°C
P815375MACKLIN对羟基联苯99%35元/25g;   96元/100g;   346元/500g;   1368元/2.5kg;   展开
储存:2~8°C
状态:白色到棕褐色粉末或片状
P0201TCI4-Phenylphenol>99.0%(GC)165元/25G;   430元/100G;   1155元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C12H10O = 170.21
外观与形状(20℃)固体
Reaxys-RN1907452
PubChem物质ID87574447
SDBS (AIST Spectral DB)3219
Merck Index (14)7305
MDL编号MFCD00002347

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 99.0 %
Melting point164.0 to 168.0 ℃

物性(参考值)

熔点165 ℃
沸点321 ℃
水溶性不溶
在水中的溶解度56.2 mg/l   20 ℃
溶解性(易溶于)乙醚,醇,氯仿

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H411 : 对水生生物有毒并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#DV5850000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
225018J&K4-Hydroxybiphenyl99%75元/25G;   238元/100G;   472元/500G;   展开

基本信息

分子式C12H10O
分子量170.21
熔点164-166
沸点321
闪点160
MDL编码MFCD00002347
Beilstein1907452
Merck14,7305
EINECS 编号202-179-2

安全信息

图形或危害标志
提示语Warning
危险说明H315
H411
防范说明P261
P273
P305+P351+P338
UN号码3077
危险分类9
包装等级III
WGK2
RTECSDV5850000
TSCA
A10817Alfa Aesar4-Phenylphenol98%505元/100g;   1656元/500g;   5757元/2500g;   展开

应用
Fluorescence and phosphorescence quantum yields and fluorescence and phosphorescence lifetimes were obtained for 4-phenylphenol adsorbed on filter paper with either NaCl, NaBr, or NaI at 296 and 93 K. The solid-surface fluorescence and phosphorescence quantum yield values and phosphorescence lifetime values were obtained for p-aminobenzoic acid (PABA) and 4-phenylphenol adsorbed on α-cyclodextrin/NaCl mixtures. 4-Phenylphenol is used as an antioxidant and is a potential EDC.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD00002347

EINECS
202-179-2

分子式
C12H10O

分子量
170.21

熔点
164-168°

沸点
305-308°

闪点
165°(329°F)

灵敏度
Ambient temperatures.

形态
Powder/flakes

溶解性
Soluble in water (0.7 mg/ml at 20°C), ether, most common organic solvents, methanol, and chloroform.

Beilstein
1907452

Merck
14,7305

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335-H401-H411
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
36/37/38-51/53
Irritating to eyes, respiratory system and skin.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-37-57
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Use appropriate container to avoid environmental contamination.

欧盟危险品标志

RTECS
DV5850000

TSCA

C15871Alfa Aesar4-Phenylphenol97%1159元/250g;   4317元/1kg;   展开

基本信息

Ref#
15871

MDL
2347

分子式
C12 H10 O

分子量
170.21

闪点
165

形态
White to pale brown powder/flakes

安全信息

危险等级
9

包装组
III

134341Sigma-Aldrich4-Phenylphenol97%285.97元/5 G;   407.35元/100 G;   展开

产品说明

一般描述

4-苯基苯酚经酶促聚合,聚合物发展的特点是基质辅助激光解吸电离飞行时间质谱。它是制备 4-烷基取代的酚醛树脂的中间体。

应用

4-苯基苯酚可用于合成新型聚磷腈聚电解质,作为单壁碳纳米管在水中的分散剂。

包装

100 g in poly bottle
5 g in glass bottle

基本信息

线性分子式C6H5C6H4OH
分子量170.21
Beilstein1907452
EC 号202-179-2
MDL编号MFCD00002347
eCl@ss39023323
PubChem化学物质编号24848146
NACRESNA.22

产品性质

质量水平100
测定97%
bp321 ℃ (lit.)
mp164-166 ℃ (lit.)
溶解性methanol: soluble 50 mg/mL, clear, colorless
SMILES stringOc1ccc(cc1)-c2ccccc2
InChI1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H
InChI keyYXVFYQXJAXKLAK-UHFFFAOYSA-N
Gene Informationrat ... Ar(24208)

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H317 - H411
预防措施声明P261 - P264 - P272 - P273 - P280 - P302 + P352
危险分类Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)320.0 °F - closed cup
闪点(C)160 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
424625Sigma-Aldrich4-Phenylphenolpurified by sublimation, 99%513.07元/1 G;   展开

产品说明

一般描述

4-Phenylphenol (4-hydroxybiphenyl, 4-HBP), a biaryl compound, is a weakly acidic 4-arylphenol. A study on its crystalline structure has been reported. Its rapid, green synthesis via a Pd(0)-catalyzed Suzuki cross-coupling reaction in water has been reported. The standard molar enthalpy of formation of 4-phenylphenol has been evaluated using combustion calorimetry. The solid-matrix luminescence properties for 4-phenylphenol adsorbed on filter paper has been investigated. A study conducted using the yeast two-hybrid assay suggests that it shows estrogenic activity.

应用

4-Phenylphenol may be used in the following studies:

  • As a reactant in the synthesis of new azobenzene sulfonic acid dopants by diazotized coupling reaction with sulphanilic acid diazonium salt.
  • As a starting material in the synthesis of 2,6-poly(4-phenylphenol).
  • As a ligand in the synthesis of aluminum (III) bis(2-methyl-8-quninolinato)-4-phenylphenolate (BAlq).

包装

1 g in poly bottle

基本信息

线性分子式C6H5C6H4OH
分子量170.21
Beilstein1907452
EC 号202-179-2
MDL编号MFCD00002347
PubChem化学物质编号24866580
NACRESNA.22

产品性质

质量水平100
测定99%
纯化方式sublimation
bp321 ℃ (lit.)
mp164-166 ℃ (lit.)
溶解性water: soluble 0.7 g/L at 20 ℃
SMILES stringOc1ccc(cc1)-c2ccccc2
InChI1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H
InChI keyYXVFYQXJAXKLAK-UHFFFAOYSA-N
Gene Informationrat ... Ar(24208)

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H317 - H411
预防措施声明P261 - P264 - P272 - P273 - P280 - P302 + P352
危险分类Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)320.0 °F - closed cup
闪点(C)160 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
CRM69184Supelco4-Phenylphenolcertified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland1452.12元/100 mg;   展开

产品说明

一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

法律信息

TraceCERT is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式C6H5C6H4OH
分子量170.21
Beilstein1907452
MDL编号MFCD00002347

产品性质

质量水平300
等级certified reference material
TraceCERT®
产品线TraceCERT®
保质期limited shelf life, expiry date on the label
bp321 ℃ (lit.)
mp164-166 ℃ (lit.)
格式neat
SMILES stringOc1ccc(cc1)-c2ccccc2
InChI1S/C12H10O/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9,13H
InChI keyYXVFYQXJAXKLAK-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H317 - H411
预防措施声明P261 - P264 - P272 - P273 - P280 - P302 + P352
危险分类Aquatic Chronic 2 - Skin Irrit. 2 - Skin Sens. 1B
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)320.0 °F - closed cup
闪点(C)160 ℃ - closed cup
973262Amethyst4-Hydroxybiphenyl99%, 用于合成54元/25G;   96元/100G;   172元/250G;   299元/500G;   1164元/2.5KG;   展开

基本信息

分子式C12H10O
分子量170.21
熔点164-166
沸点321
闪点160
MDL编码MFCD00002347
Beilstein1907452
Merck14,7305
EINECS 编号202-179-2

安全信息

图形或危害标志
提示语Warning
危险说明H315
H411
防范说明P261
P273
P305+P351+P338
UN号码3077
危险分类9
包装等级III
WGK2
RTECSDV5850000
TSCA
HBP-003NAccuStandard4-Hydroxybiphenyl232元/100mg;   展开
4-Hydroxybiphenyl4-羟基联苯92-69-3
HBP-003SAccuStandard4-Hydroxybiphenyl,100 μg/mL in Methanol100 μg/mL in Methanol232元/1mL;   展开
4-Hydroxybiphenyl4-羟基联苯92-69-3100 µg/mL
094138Fluorochem4-Phenylphenol95+%264元/25g;   726元/100g;   1342元/500g;   展开

基本信息

CAS Number92-69-3
MDL NumberMFCD00002347
Boiling Point305-308℃
Melting Point164-170℃
Density1.297

安全信息

图形或危害标志
危险性说明 EUH401: To avoid risks to human health and the environment, comply with the instructions for use.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H411: Toxic to aquatic life with long lasting effects.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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