[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 916320-82-6
关键词:       仅模糊查询
CAS: 916320-82-6
分子式: C16H12Cl2N2O4
分子量: 367.18
中文名称: 
双(4-氯苄基)偶氮二甲酸酯
偶氮二甲酸二(对氯苄基)酯
英文名称: 
di-(4-chlorobenzyl)azodicarboxylate
dcad
bis(4-chlorobenzyl)azodicarboxylate
推荐供应商
货号品牌产品名称规格包装、参考价格
D853035MACKLIN偶氮二甲酸二(对氯苄基)酯97%31元/1g;   117元/5g;   522元/25g;   1922元/100g;   咨询
储存:2-8°C
状态:白色到橙色到棕褐色固体,粉末,晶体,块状
680850Sigma-AldrichDi-(4-chlorobenzyl)azodicarboxylate97%416.35元/1 G;   3955.33元/10 G;   咨询

产品说明

一般描述

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

应用

Reactant for preparation of:

  • Amino thioesters via guanidine-catalyzed biomimetic enantioselective decarboxylative Mannich and amination reactions of malonic acid half thioesters
  • Hydroacylation reaction of aldehydes in Ionic liquid (IL) medium
  • DCAD (di-p-chlorobenzyl azodicarboxylate) for Mitsunobu coupling reactions

双(4-氯苄基)偶氮二甲酸酯 (DCAD) 是 DEAD 和 DIAD 的新型稳定固体替代物,可用于多种 Mitsunobu 偶联反应,生成易于分离并且可回收利用的副产物肼。

包装

1, 10 g in glass bottle

基本信息

经验(实验)分子式C16H12Cl2N2O4
分子量367.18
MDL编号MFCD27995640
PubChem化学物质编号24885598

产品性质

测定97%
mp108-112 ℃
SMILES stringO=C(/N=N\C(OCC1=CC=C(Cl)C=C1)=O)OCC2=CC=C(Cl)C=C2
InChI1S/C16H12Cl2N2O4/c17-13-5-1-11(2-6-13)9-23-15(21)19-20-16(22)24-10-12-3-7-14(18)8-4-12/h1-8H,9-10H2/b20-19-
InChI keyUIFGGABIJBWRMG-VXPUYCOJSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H317
预防措施声明P280
危险分类Skin Sens. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
095825FluorochemDi-(4-chlorobenzyl)azodicarboxylate99%286元/1g;   902元/5g;   2838元/25g;   8338元/100g;   咨询

基本信息

CAS Number916320-82-6
MDL NumberMFCD09265148
Melting Point108-112℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9