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CAS: 91-60-1
分子式: C10H18S
分子量: 160.24
沸点: 286℃
熔点: 79-80℃
中文名称: 
2-硫代萘酚
β-巯基萘
2-萘基硫酚
2-萘硫醇
β-萘硫酚
2-巯基萘
硫代乙萘酚
硫代-2-萘酚
2-萘硫酚
英文名称: 
2-Metcaptonaphthalene
-Thionaphthol
2-Naphthalenethiol
2-mercaptonaphthalene
2-naphthyl mercaptan
2-naphthyl thiol
2-thionaphthol
beta-mercaptonaphthalene
beta-naphthalenethiol
beta-naphthyl mercaptan
beta-thionaphthol
mercaptan beta-naphtalenique
naphthalene-2-thiol
naphthalenethiol (non-specific name)
renacit 1
rpa 2
rpa no. 2
thio-beta-naphthol
thionaphthol
usaf cy-4
vulcamel tbn
Thio-2-naphthol
展开更多英文名
性质描述: 无色结晶。熔点81℃。沸点286℃,146.3℃(1.33kPa)。易溶于乙醇、乙醚、石油醚,微溶于水。能随水蒸气挥发,在空气中易氧化成硫化物。具有令人厌恶的气味。
生产方法: 先将2-萘酚与二甲氨基硫代甲酰氯在碱存在反应制得O-2萘基二甲氨基硫代甲酸酯,经精制各加热至270-275℃,反应45min。冷却后加入氢氧化钾溶液和乙二醇的混合液中,加热回流1h。经盐酸化,氯仿提取,减仿提取,减压蒸馏,即得2-萘硫酚。
用途: 在橡胶工业中用作再生活化剂,适于低温使用,但活化效果不及芒香族二硫化物,而且使再生胶带有难闻的气味。一般用量为0.1-1.5%,该品也可用作防老剂、增塑剂和有机合成的中间体。2-萘硫酚有毒,能引起皮炎和溃疡。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N814523MACKLIN2-萘硫酚99%32元/1g;   95元/5g;   346元/25g;   1154元/100g;   展开
储存:室温,密封
状态:白色至淡黄色固体
折射率:1.589-1.591
N0020TCI2-Naphthalenethiol>98.0%(GC)(T)1200元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C10H8S = 160.23
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN636389
PubChem物质ID87573431
SDBS (AIST Spectral DB)6630
Merck Index (14)6379
MDL编号MFCD00004086

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Iodometric Titration)min. 98.0 %
Melting point79.0 to 83.0 ℃

物性(参考值)

熔点81 ℃
沸点211 ℃/100 mmHg
水溶性微溶
溶解性(可溶于)乙醇,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#QK3930000
129833J&K2-Naphthalenethiol98%286元/5G;   1140元/25G;   展开

基本信息

分子式C10H8S
分子量160.24
熔点79-81
沸点286
MDL编码MFCD00004086
Beilstein636389
Merck14,6379
EINECS 编号202-082-5

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H332
防范说明P280
P301+P312
P302+P352
P304+P340
WGK3
RTECSQK3930000
TSCA
A12125Alfa Aesar2-Thionaphthol98%998元/10g;   4365元/50g;   18581元/250g;   展开

应用
2-Thionaphthol was used in the preparation of cholesterol monolayer and multilayer Langmuir- Blodgett (LB) films. The magnetic resonance shift for a self-assembled monolayer of 2-naphthalenethiol was studied that suggested considerable promise in flexible and transparent photonic devices for biological and chemical sensing.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00004086

EINECS
202-082-5

分子式
C10H8S

分子量
160.24

熔点
79-83°

沸点
286°

密度
1.55

灵敏度
Air Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in alcohol, dipropylene glycol. Soluble in water 34.4 mg/L @ 25°C.

Beilstein
636389

Merck
14,6379

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
QK3930000

TSCA

270849Sigma-Aldrich2-Naphthalenethiol99%1038.66元/5 G;   1604.75元/25 G;   展开

产品说明

一般描述

对自组装单层 2-萘硫醇的磁共振位移的研究表明,2-萘硫醇在用于生物和化学传感的柔性和透明光子器件中具有广阔的应用前景。

应用

2-萘硫醇用于制备胆固醇单层和多层 Langmuir-Blodgett(LB)膜。采用循环伏安法和电化学阻抗谱研究了这些薄膜的电化学阻抗性能。

包装

5, 25 g in glass bottle

基本信息

线性分子式C10H7SH
分子量160.24
Beilstein636389
EC 号202-082-5
MDL编号MFCD00004086
PubChem化学物质编号24856405
NACRESNA.22

产品性质

质量水平100
测定99%
bp286 ℃ (lit.)
mp79-81 ℃ (lit.)
溶解性diethyl ether: very soluble(lit.)
ethanol: very soluble(lit.)
petroleum ether: very soluble(lit.)
water: slightly soluble(lit.)
SMILES stringSc1ccc2ccccc2c1
InChI1S/C10H8S/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7,11H
InChI keyRFCQDOVPMUSZMN-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
227409FluorochemNaphthalene-2-thiol95%352元/5g;   1210元/25g;   3960元/100g;   展开

基本信息

CAS Number91-60-1
MDL NumberMFCD00004086

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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