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CAS: 90866-33-4
分子式: C6H11ClO3
分子量: 166.6
沸点: 93-95 °C (5 mmHg)
熔点: 93-95 °C
中文名称: 
(R)-(+)-4-氯-3-羟基丁酸乙酯
英文名称: 
ethyl(R)-4-chlorq-3-hydroxybutanoate
(R)-(+)-4-Chloro-3-hydroxybutyric acid ethyl ester
Ethyl(R)-4-Chloro-3-hydroxybutyrate
(R)-4-Chloro-3-hydroxybutyric Acid Ethyl Ester
(R)-(+)-ethyl-4-chloro 3-hydroxybutanoate
Ethyl(R)-(+)-4-chloro-3-hydroxybutyrate
推荐供应商
货号品牌产品名称规格包装、参考价格
R833371MACKLIN(R)4-氯-3-羟基丁酸乙酯90%(GC)31元/5g;   96元/25g;   咨询
储存:室温
状态:无色到黄色液体
折射率:n20/D 1.452
R729073MACKLIN(R)-4-氯-3-羟基丁酸乙酯98%180元/25g;   552元/100g;   2136元/500g;   咨询
储存:室温
折射率:n20/D 1.452
R804936MACKLIN|R|4-氯-3-羟基丁酸乙酯95%29元/1g;   40元/5g;   140元/25g;   432元/100g;   咨询
储存:室温
状态:无色到黄色液体
折射率:n20/D 1.452
440402J&KEthyl R-(+)-4-chloro-3-hydroxybutyrate96%397元/1G;   1129元/5G;   咨询

基本信息

分子式C6H11ClO3
分子量166.60
沸点93-95
闪点113
密度1.19
折光率(n20D)1.4530
比旋光度([α]20D)+11°to +17° (neat)
MDL编码MFCD00211242

安全信息

图形或危害标志
提示语Danger
危险说明H318
防范说明P280
P305+P351+P338
WGK3
TSCA否
L18553Alfa AesarEthyl (R)-(+)-4-chloro-3-hydroxybutyrate97%, ee 96%1399元/1g;   4568元/5g;   咨询

基本信息

MDL
MFCD00211242

分子式
C6H11ClO3

分子量
166.61

沸点
93-95°/5mm

闪点
>110°(230°F)

密度
1.190

折射率
1.4530

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H332-H315-H318
Harmful if swallowed.Harmful in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P337+P313
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.

安全信息

危险类别
20/21/22-38-41
Harmful by inhalation, in contact with skin and if swallowed.Irritating to skin.Risk of serious damage to eyes.

安全等级
26-36/37/39
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.

欧盟危险品标志

TSCA
否

460516Sigma-AldrichEthyl (R)-(+)-4-chloro-3-hydroxybutyrate96%315.58元/1 G;   咨询

产品说明

应用

Ethyl (R)-(+)-4-chloro-3-hydroxybutyrate is a chiral building block that can be used:

  • To prepare allyl stannane, a precursor for the total synthesis of macrolide iriomoteolide-1b.
  • As a starting material for the synthesis of a chiral g-αmino acid fragment, which in turn is used to prepare the immunosuppressive agent FR252921.

包装

1 g in glass bottle

基本信息

线性分子式ClCH2CH(OH)CH2CO2C2H5
分子量166.60
MDL编号MFCD00211242
PubChem化学物质编号24869705
NACRESNA.22

产品性质

质量水平100
测定96%
旋光性[α]23/D +14°, neat
光学纯度ee: 97% (GLC)
折射率n20/D 1.453 (lit.)
bp93-95 ℃/5 mmHg (lit.)
密度1.19 g/mL at 25 ℃ (lit.)
SMILES stringCCOC(=O)C[C@@H](O)CCl
InChI1S/C6H11ClO3/c1-2-10-6(9)3-5(8)4-7/h5,8H,2-4H2,1H3/t5-/m1/s1
InChI keyZAJNMXDBJKCCAT-RXMQYKEDSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H318
预防措施声明P280 - P305 + P351 + P338
危险分类Eye Dam. 1
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
079716Fluorochem(R)-Ethyl 4-chloro-3-hydroxybutanoate95%220元/1g;   264元/5g;   440元/10g;   968元/25g;   3718元/100g;   咨询

基本信息

CAS Number90866-33-4
MDL NumberMFCD00211242
Boiling Point93-95 ℃/5 mmHg(lit.)
Density1.19

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
防范说明 P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to local regulations.
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