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CAS: 90-59-5
分子式: C7H4Br2O2
分子量: 279.92
熔点: 80-84℃
中文名称: 
3,5-二溴邻羟基苯醛
3,5-二溴水杨醛
英文名称: 
3,5-dibromo-2-hydroxy-benzaldehyd
3,5-dibromo-2-hydroxybenzaldehyde
3,5-dibromosalicylaldehyde
dalyde
3,5-dibromo-salicylaldehyd
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D807048MACKLIN3,5-二溴水杨醛98%29元/2g;   37元/10g;   155元/50g;   666元/250g;   展开
储存:室温,密封
状态:黄色粉末晶体和/或块状
D0188TCI3,5-Dibromosalicylaldehyde>98.0%(T)(HPLC)305元/5G;   855元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C7H4Br2O2 = 279.92
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1424739
PubChem物质ID87566906
SDBS (AIST Spectral DB)1548
Merck Index (14)3027
MDL编号MFCD00003318

技术规格

AppearanceWhite to Orange to Green powder to crystaline
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %
Melting point81.0 to 85.0 ℃

物性(参考值)

熔点83 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H400 : 对水生生物毒性极大。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#CU5609000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
416499J&K3,5-Dibromosalicylaldehyde98%512元/10G;   2044元/50G;   8158元/250G;   展开

基本信息

分子式C7H4Br2O2
分子量279.91
熔点82-84
MDL编码MFCD00003318
Beilstein1424739
Merck14,3027
EINECS 编号202-003-4

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
H400
防范说明P261
P273
P305+P351+P338
UN号码3077
危险分类9
包装等级III
WGK3
RTECSCU5609000
TSCA
A13729Alfa Aesar3,5-Dibromosalicylaldehyde98%1338元/10g;   5308元/50g;   21234元/250g;   展开

应用
3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes. It can be used in the synthesis of Schiff base and can be used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Air Sensitive.

基本信息

MDL
MFCD00003318

EINECS
202-003-4

分子式
C7H4Br2O2

分子量
279.93

熔点
81-84°

灵敏度
Air Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in methanol 25 mg/mL. Insoluble in water.

Beilstein
1424739

Merck
14,3027

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
CU5609000

TSCA

C15340Alfa Aesar3,5-Dibromosalicylaldehyde98%650元/1g;   1665元/25g;   7509元/100g;   展开

基本信息

Ref#
15340

MDL
3318

分子式
C7 H4 Br2 O2

分子量
279.91

形态
Yellow cryst powder

122130Sigma-Aldrich3,5-Dibromosalicylaldehyde98%715.3元/10 G;   展开

产品说明

一般描述

3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes.

应用

3,5-Dibromosalicylaldehyde was used in the synthesis of Schiff base, 15N-Labeled N-(3,5-dibromosalicylidene)-methylamine. It was used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).

包装

10 g in glass bottle

基本信息

线性分子式Br2C6H2-2-(OH)CHO
分子量279.91
EC 号202-003-4
MDL编号MFCD00003318
PubChem化学物质编号24847478
NACRESNA.22

产品性质

质量水平200
测定98%
mp82-83.5 ℃ (lit.)
溶解性methanol: soluble 25 mg/mL, clear, yellow to brown
SMILES stringOc1c(Br)cc(Br)cc1C=O
InChI1S/C7H4Br2O2/c8-5-1-4(3-10)7(11)6(9)2-5/h1-3,11H
InChI keyJHZOXYGFQMROFJ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H315 - H319 - H335 - H400
预防措施声明P273 - P302 + P352 - P305 + P351 + P338
危险分类Aquatic Acute 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
216619Fluorochem3,5-Dibromosalicylaldehyde95%242元/10g;   484元/25g;   1738元/100g;   展开

基本信息

CAS Number90-59-5
MDL NumberMFCD00003318
Melting Point83℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H400: Very toxic to aquatic life.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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