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CAS: 90-44-8
分子式: C14H10O
分子量: 194.23
沸点: 721℃
熔点: 152-157℃
中文名称: 
蒽酮
9,10-二氢-9-氧蒽
9(10H)-蒽酮
英文名称: 
Anthranone
9,10-Dihydro-9-oxoanthracene
Anthrone;9,10-Dihydro-9-oxoanthracene;9(10H)-Anthracenone
9(10H)-Anthracenone
Anthrone
9-oxoanthracene
9,10-dihydro-9-oxo-anthracen
carbothrone
Anthrone,ACS
9,10-Dihydro-9-oxoan-thracene
性质描述: 该品为无色针状结晶体。熔点为155℃,溶于大多数有机溶剂和热氢氧化钠溶液,不溶于水。无荧光,所出现的荧光是由蒽酚所致。
生产方法: 由蒽醌经下列反应得到。将104g蒽醌、100g锡粒、750ml冰醋酸混合加热至沸,再逐次加入浓盐酸250ml(相对密度为1.19),约2h加完,此时蒽醌应全部溶于反应液中,否则,需补加锡粒和盐酸。再回流1.5h,脱色过滤,滤液用100ml水稀释,冷却至10℃,析出蒽酮结晶,过滤,用水洗使pH=7而得粗晶,干重80g。粗品可用丙酮或苯和石油醚(3:1)混合液重结晶,可得熔点为154-155℃的蒽酮约60g。
用途: 该品用于有机合成,用糖和动物体液中淀粉的比色测定。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A854516MACKLIN蒽酮90%50元/5g;   165元/25g;   412元/100g;   1469元/500g;   展开
储存:室温
状态:白色到黄色固体
A800666MACKLIN蒽酮试剂级, 96%33元/1g;   96元/5g;   268元/25g;   726元/100g;   2627元/500g;   8345元/2.5kg;   展开
储存:室温
状态:灰白色到黄色晶体或粉末
A0509TCIAnthrone>98.0%(GC)210元/5G;   890元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C14H10O = 194.23
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN1910173
PubChem物质ID87562120
SDBS (AIST Spectral DB)1528
Merck Index (14)691
MDL编号MFCD00001187

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Melting point154.0 to 160.0 ℃
Solubility in hot Toluenealmost transparency

物性(参考值)

熔点156 ℃
水溶性不溶
溶解性(可溶于)丙酮
溶解性(微溶于)乙醚
溶解度(极微溶)乙醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#CB8925500
030739Alfa AesarAnthroneACS989元/25g;   1762元/100g;   展开

应用
Used for determination of carbohydrates Anthrone is used for the determination of carbohydrates. It is used as a general reagent in the colorimetric determination of carbohydrates in yeast and plant extracts. It is involved in organic synthesis. It is utilized for the determination of sugar in body fluids. It finds application as a laxative.

Grade Specifications
Maximum level of impurities: Melting point no more than a 5� range including 156�, Sensitivity to carbohydrates P.T., Absorbance of reagent solution P.T., Solubility in ethyl acetate P.T.

备注
Light sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00001187

EINECS
201-994-0

分子式
C14H10O

分子量
194.23

熔点
155-158°

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in acetone, hot benzene, concentrated sulfuric acid, hot dilute alkali and most organic solvents. Insoluble in water.

Beilstein
1910173

Merck
14,691

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
CB8925500

TSCA

A19118Alfa AesarAnthrone96%968元/25g;   1896元/100g;   7274元/500g;   展开

应用
It finds its applications in organic synthesis. It is used for a popular cellulose assay and in the colorometric determination of carbohydrates in body fluids and of animal starch in liver tissue. The anthrones are used in pharmacy as laxative. They stimulate the motion of the colon and are responsible for less water reabsorption. They may only be used for a short amount of time, because long time use may lead to loss of electrolytes.

备注
Light Sensitive. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

基本信息

MDL
MFCD00001187

EINECS
201-994-0

分子式
C14H10O

分子量
194.23

熔点
153-160°

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in alcohol, benzene, and hot NaOH solutions. Insoluble in water

Beilstein
1910173

Merck
14,691

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
CB8925500

TSCA

C10496Alfa AesarAnthroneACS reagent1057元/25g;   2952元/100g;   展开

基本信息

Ref#
10496

MDL
1187

分子式
C14 H10 O

分子量
194.23

形态
Crystalline

8.01461Sigma-AldrichAnthronefor synthesis329.04元/10 G;   785.75元/100 G;   展开

产品说明

分析说明

Assay (LC-MS): ≥ 97.0 % (a/a)
Identity (IR): passes test

基本信息

经验(实验)分子式C14H10O
分子量194.23
MDL编号MFCD00001187
EC索引号201-994-0

产品性质

质量水平200
形式solid
mp151-156 ℃
溶解性 4.6 mg/L
堆积密度450 kg/m3
储存温度no temp limit
InChI1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2
InChI keyRJGDLRCDCYRQOQ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
319899Sigma-AldrichAnthroneACS reagent, 97%1255元/25 G;   3804.98元/100 G;   展开

产品说明

一般描述

蒽酮具有将含有醛的还原糖(例如链霉素中存在的链霉糖和N-乙酰基葡糖胺)还原成酸的能力。它呈红紫色。因此,它可用于定量检测链霉素。蒽酮被用于检测含有糖类的脂质以及液体培养基中的糖(例如蔗糖和海藻糖)含量。

包装

25, 100 g in poly bottle

基本信息

经验(实验)分子式C14H10O
分子量194.23
Beilstein1910173
EC 号201-994-0
MDL编号MFCD00001187
PubChem化学物质编号24859195
NACRESNA.47

产品性质

质量水平200
等级ACS reagent
测定97%
形式powder or crystals
mp154-157 ℃ (lit.)
溶解性ethyl acetate: 2%, clear, yellow
Amax≤0.045 at 620 nm in sulfuric acid
≤0.75 at 425 nm in sulfuric acid
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES stringO=C1c2ccccc2Cc3ccccc13
InChI1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2
InChI keyRJGDLRCDCYRQOQ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
52445SupelcoAnthroneanalytical standard966.61元/100 MG;   展开

产品说明

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

经验(实验)分子式C14H10O
分子量194.23
Beilstein1910173
EC 号201-994-0
MDL编号MFCD00001187
PubChem化学物质编号329757839
NACRESNA.24

产品性质

质量水平100
等级analytical standard
测定≥97% (GC)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp154-157 ℃ (lit.)
适用性conforms to structure for Infrared spectrum
格式neat
储存温度2-8℃
SMILES stringO=C1c2ccccc2Cc3ccccc13
InChI1S/C14H10O/c15-14-12-7-3-1-5-10(12)9-11-6-2-4-8-13(11)14/h1-8H,9H2
InChI keyRJGDLRCDCYRQOQ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
053522FluorochemAnthrone96%220元/1g;   330元/5g;   924元/25g;   展开

基本信息

CAS Number90-44-8
MDL NumberMFCD00001187

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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