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CAS: 90-11-9
分子式: C10H7Br
分子量: 207.07
沸点: 279-281℃
熔点: -1--1℃
中文名称: 
A-溴萘
α-溴萘
1-溴代萘
1-溴萘
1-溴化萘
α-溴代萘
英文名称: 
1-Bromonaphthalene solution
1-bromo-naphthalene
α-bromonaphthalene
I-Bromnaphthalin
a-Bromnaphthalin
-Bromonaphthalene
Naphthalene,1-bromo-
1-Bromonaphthalene
1-bromo-Naphthalene
1-naphthyl bromide
alpha-bromonaphthalene
alpha-naphthyl bromide
1-bromo-naphthalen
展开更多英文名
性质描述: 无色或微黄色液体,蒸馏后能保持无色,但久置后变黑色。熔点-1℃,沸点281℃,146-149℃(2.13kPa),相对密度1.489(20/4℃),折射率1.6576,闪点110℃。能与醇、醚、四氯化碳相混溶,不溶于水。能随水蒸汽挥发。
生产方法: 由萘与溴反应而得。在反应锅中加入四氯化碳和萘,搅拌加热,在45℃慢慢加入溴素。加完后于70-80℃保温反应3-4h。蒸馏回收四氯化碳,将反应物洗涤、减压蒸馏、再洗涤、过滤、干燥而得成品。
用途: 有机合成原料,分析试剂,用作冷冻剂以及分子量大的物质的溶剂。也是干燥物品的热载体。亦可用于折射率测定。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B743011MACKLIN1-溴代萘Standard for GC, ≥99.5%(GC)128元/5g;   展开
储存:室温
状态:液体
B743012MACKLIN1-溴代萘99%42元/25g;   83元/100g;   265元/500g;   1200元/2.5kg;   展开
储存:室温
状态:液体
B802631MACKLIN1-溴代萘97%30元/25g;   54元/100g;   171元/500g;   846元/2.5kg;   2045元/12X500g;   展开
储存:室温
状态:无色到黄色棕色液体
折射率:n20/D 1.6570(lit.)
B0618TCI1-Bromonaphthalene>95.0%(GC)160元/25G;   420元/100G;   1195元/500G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C10H7Br = 207.07
外观与形状(20℃)液体
Reaxys-RN1906414
PubChem物质ID87563626
SDBS (AIST Spectral DB)1443
Merck Index (14)1425
MDL编号MFCD00003868

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

熔点-2 ℃
沸点282 ℃
比重1.48
折射率1.66
水溶性微溶
溶解性(可与之混溶)氯仿,乙醚,苯,醇

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#QJ1545000
224893J&K1-Bromonaphthalene99%121元/5ML;   295元/100ML;   1138元/500ML;   展开

基本信息

分子式C10H7Br
分子量207.07
熔点-2 - -1
沸点279-281
闪点>110
密度1.48
折光率(n20D)1.6570
MDL编码MFCD00003868
Beilstein1906414
Merck14,1425
EINECS 编号201-965-2

安全信息

图形或危害标志
提示语Warning
危险说明H302
H319
防范说明P305+P351+P338
WGK3
RTECSQJ1545000
TSCA
A14122Alfa Aesar1-Bromonaphthalene97%429元/50g;   790元/250g;   2508元/1000g;   展开

应用
1-Bromonaphthalene is used in organic synthesis and refractometry of fats. It is used in the preparation of N-aryl imidazoles and diaryl ethers. It is used to determine the refractive index of crystals and the water content of alcohols. It is utilized in the preparation of glutathione peroxidase-like antioxidant activity of diaryl diselenides. Further, it serves as a solvent for the exfoliation and dispersion of hexabenzocoronene. In addition to this, it is used as a refrigerant and a solvent molecular weight substance.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00003868

EINECS
201-965-2

分子式
C10H7Br

分子量
207.08

熔点
-2° to 0°

沸点
279-281°

闪点
>110°(230°F)

密度
1.485

折射率
1.6570

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with chloroform, ethanol, ether, benzene and ethyl acetate. Slightly miscible with water.

Beilstein
1906414

Merck
14,1425

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H319
Harmful if swallowed.Causes serious eye irritation.

Precautionary Statements
P280i-P264-P305+P351+P338-P301+P312a-P337+P313-P501a
Wear eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
23-26-36-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
QJ1545000

TSCA

C10715Alfa Aesar1-Bromonaphthalene96%1148元/100ml;   4498元/500ml;   14653元/2.5L;   展开

基本信息

Ref#
10715

MDL
3868

分子式
C10 H7 Br

分子量
207.07

闪点
>110

密度
1489

形态
Liquid

N9-500Alfa Aesar1 BROMONAPHTHALENE REAG 500ML3303元/500ml;   展开

基本信息

Ref#
F51585

B73104Sigma-Aldrich1-Bromonaphthalene97%401.57元/5 G;   641.9元/100 G;   1314.52元/500 G;   展开

产品说明

应用

1-溴萘一种溴代芳烃,可用于:

  • 与芳基三氟硼酸的钯催化Suzuki–Miyaura偶联反应,无需相转移催化剂或膦配体。
  • 通过Suzuki-Heck型偶联,与o-溴苯基硼酸和寡环溴芳烃反应,制备Indeno环并多环芳烃。
  • 与PhMgBr的Ni催化Kumada–Tamao–Corriu 交叉偶联反应。
  • 通过与芳基硼酸的钯催化Suzuki-Miyaura交叉偶联反应制备芳基萘。

包装

5, 100, 500 g in glass bottle

基本信息

经验(实验)分子式C10H7Br
分子量207.07
Beilstein1906414
EC 号201-965-2
MDL编号MFCD00003868
PubChem化学物质编号24891985
NACRESNA.22

产品性质

质量水平200
测定97%
形式liquid
折射率n20/D 1.6570 (lit.)
bp133-134 ℃/10 mmHg (lit.)
mp−2-−1 ℃ (lit.)
密度1.48 g/mL at 20 ℃ (lit.)
SMILES stringBrc1cccc2ccccc12
InChI1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI keyDLKQHBOKULLWDQ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H410
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
8.06210Sigma-Aldrich1-Bromonaphthalenefor synthesis412.33元/100 ML;   1266.9元/500 ML;   5838.7元/2.5 L;   展开

产品说明

分析说明

Assay
- GC, area%:
≥ 95 %
- 2-Bromonaphthaline: ≤ 5 %
Density (d 20 °C/ 4 °C): 1.478 - 1.487
Identity (IR): passes test

基本信息

经验(实验)分子式C10H7Br
分子量207.07
MDL编号MFCD00003868
EC索引号201-965-2

产品性质

蒸汽压0.013 hPa ( 20 ℃)
质量水平200
形式liquid
效能810 mg/kg LD50, oral (Rat)
bp281 ℃/1013 hPa
转变温度flash point 67 ℃
密度1.48 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI keyDLKQHBOKULLWDQ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H410
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
17640Sigma-Aldrich1-Bromonaphthalene≥95%961.03元/100 ML;   3258.86元/500 ML;   展开

产品说明

一般描述

The vibrational spectra of 1-bromonaphthalene has been studied.

应用

1-Bromonaphthalene was used as a solvent for the exfoliation and dispersion of hexabenzocoronene (HBC).

包装

100, 500 mL in glass bottle

基本信息

经验(实验)分子式C10H7Br
分子量207.07
Beilstein1906414
EC 号201-965-2
MDL编号MFCD00003868
eCl@ss39060108
PubChem化学物质编号57647656
NACRESNA.22

产品性质

质量水平100
测定≥95%
形式liquid
颜色slightly yellow to deep brown-yellow
折射率n20/D 1.6570 (lit.)
bp133-134 ℃/10 mmHg (lit.)
mp−2-−1 ℃ (lit.)
溶解性H2O: slightly soluble
alcohol: miscible
benzene: miscible
chloroform: miscible
diethyl ether: miscible
密度1.48 g/mL at 20 ℃ (lit.)
SMILES stringBrc1cccc2ccccc12
InChI1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI keyDLKQHBOKULLWDQ-UHFFFAOYSA-N

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 - H319 - H410
预防措施声明P264 - P270 - P273 - P280 - P301 + P312 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
222044Fluorochem1-Bromonaphthalene96%308元/25g;   1210元/250g;   1958元/500g;   3036元/1kg;   展开

基本信息

CAS Number90-11-9
MDL NumberMFCD00003868
Boiling Point133-134℃/10 mmHg
Density1.48

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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