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CAS: 90-05-1
分子式: C7H8O2
分子量: 124.14
沸点: 205℃
熔点: 27-29℃
中文名称: 
2-甲氧基酚
邻羟基茴香醚
1-羟基-2-甲氧基苯
愈创木酚
1,2-甲氧基苯酚
邻甲氧基苯酚
邻羟基苯甲醚
愈疮木酚
邻甲氧基酚
甲基儿茶酚
英文名称: 
Phenol,1,2-methoxy-
Gatechol methyl ether
2-methoxy-phenol
Catechol(mono)methyl ether
Phenol,2-methoxy-
Guaiacol
1,2-methoxy-Phenol
o-methoxy-pheno
1-hydroxy-2-methoxybenzene
2-hydroxyanisole
2-methoxy phenol
2-methoxy-4-propenylphenol
2-methoxyphenol
4-propenylguaiacol
ai3-05615
anastil
fema no 2532
guaiastil
guaicol
guaicolina
guajacol
guajakol
guajakol (czech)
guajol
guasol
methylcatechol
nsc 3815
o-guaiacol
o-hydroxyanisole
o-methoxyphenol
o-methyl catechol
2-methoxy-pheno
propenylguaiacol
pyrocatechol methyl ester
pyrocatechol methyl ether
pyrocatechol monomethyl ether
pyroguaiac acid
展开更多英文名
性质描述: 无色或微黄色结晶或无色至淡黄色透明油状液体,可燃。在木材干馏油中的酸性成分含60%-90%的杂酚油。其中主要是愈创木酚。露置空气或日光中逐渐变成暗色。熔点32℃(31-32℃),沸点205℃(204-206℃),106.5℃(3.2kPa),53-55℃(0.53kPa),相对密度(19/4℃):晶体1.129;液体约1.112,凝固点28℃(但大大低于此温度时仍可长时间保持液态),折射率1.5429,闪点(开杯)82℃。略溶于水和苯,易溶于甘油,与乙醇、乙醚、氯仿、油类、冰醋酸混溶。遇三氯化铁变蓝色。有特殊芳香气味。
生产方法: 在自然界中愈创木酚存在于愈创树脂或松油中,在木材干馏所得的杂酚油中,愈创木酚是主要的成分,将杂酚油分馏可得该品。日本大阪精化公司以邻硝基氯苯为原料,制成邻硝基苯甲醚,进而还原为邻氨基苯甲醚,最后制得该品。我国生产方法与此大致相同。原料消耗定额:含氨基苯甲醚1250kg/t、硫酸(93%)1500kg/t、亚硝酸钠700kg/t、硫酸铜400kg/t。
用途: 在医药上用以制造愈创木酚磺酸钙,在香料工业上用以制造香兰素和人造麝香等。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
G902353MACKLIN愈创木酚分析对照品,≥99.5%128元/100mg;   展开
储存:室温
状态:无色到浅黄色和粉色液体或固体
折射率:n20/D 1.543(lit.)
G810532MACKLIN愈创木酚>99.0%(GC)29元/25g;   31元/100g;   99元/500g;   410元/2.5kg;   1499元/10kg;   1175元/12X500g;   展开
储存:室温
状态:无色到浅黄色和粉色液体或固体
折射率:n20/D 1.543(lit.)
M0121TCIGuaiacol>98.0%(GC)170元/25G;   530元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7H8O2 = 124.14
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN508112
PubChem物质ID87572226
SDBS (AIST Spectral DB)1942
Merck Index (14)4553
MDL编号MFCD00002185

技术规格

AppearanceWhite or Colorless to Light yellow powder to lump to clear liquid
Purity(GC)min. 98.0 %
Solubility in Methanolalmost transparency

物性(参考值)

熔点28 ℃
沸点205 ℃
折射率1.54
水溶性微溶
溶解性(易溶于)苯,甲苯,醇,氯仿,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H332 : 吞咽或吸入有害。
H313 : 皮肤接触可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H336 : 可能造成昏昏欲睡或眩晕。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#SL7525000
247796J&KGuaiacol99%196元/250G;   329元/1KG;   展开

基本信息

分子式C7H8O2
分子量124.14
熔点27-29
沸点205
闪点82
密度1.129
折光率(n20D)1.5430
MDL编码MFCD00002185
Beilstein508112
Merck14,4553
EINECS 编号201-964-7

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
防范说明P305+P351+P338
WGK1
RTECSSL7525000
TSCA
A16319Alfa Aesar2-Methoxyphenol98+%514元/250g;   1487元/1000g;   5878元/5000g;   展开

应用
2-Methoxyphenol acts as an expectorant. It is used as an anti-oxidant as well as an anti-skinning agent for paints. It serves as a precursor to flavorants such as eugenol and vanillin. Further, it is used as an intermediate in the chemical synthesis of active pharmaceuticals, flavoring and perfumery products. In addition to this, it is also used as an indicator in chemical reactions that produce oxygen.

备注
Air and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00002185

EINECS
201-964-7

分子式
C7H8O2

分子量
124.14

熔点
28-31°

沸点
204-206°

闪点
82°(179°F)

密度
1.129

折射率
1.5430

灵敏度
Air Sensitive. Light Sensitive. Ambient temperatures.

形态
Solid

溶解性
Miscible with carbon tetrachloride, alcohol, chloroform, ether, oils, glacial acetic acid and sodium hydroxide solution. Slightly miscible with water and petroleum ether.

Beilstein
508112

Merck
14,4553

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P305+P351+P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险类别
22-36/38
Harmful if swallowed.Irritating to eyes and skin.

安全等级
26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

欧盟危险品标志

RTECS
SL7525000

TSCA

C12019Alfa AesarGuaiacol99+%587元/250g;   1312元/1kg;   4762元/5kg;   展开

基本信息

Ref#
12019

MDL
2185

分子式
C7 H8 O2

分子量
124.14

闪点
82

密度
1.12

形态
White to pale brown solid

W253200Sigma-AldrichGuaiacolnatural, ≥99%, FG433.21元/;   908.07元/1 KG;   2832.49元/5 KG;   5358.34元/10 KG;   展开

产品说明

一般描述

愈创木酚是一种香精化合物,天然存在于番茄和在橡木桶中熟化的葡萄酒中。

应用

愈创木酚可用于制备香兰素,一种广泛使用的食品香味剂。

包装

5, 10 kg in poly drum
1 kg in glass bottle

生化/生理作用

愈创木酚和2,4,6-三氯苯甲醚是造成葡萄酒软木污染的原因。已经开发了一种用于提取和定量两种化合物的方法。

基本信息

线性分子式(CH3O)C6H4OH
分子量124.14
FEMA编号2532
Beilstein508112
EC 号201-964-7
欧洲委员会编号173
MDL编号MFCD00002185
PubChem化学物质编号24901124
Flavis编号4.005
NACRESNA.21

产品性质

质量水平400
等级FG
Halal
Kosher
natural
agencyfollows IFRA guidelines
meets purity specifications of JECFA
reg. complianceEU Regulation 1223/2009
EU Regulation 1334/2008 & 178/2002
FDA 21 CFR 172.515
蒸汽密度4.27 (vs air)
蒸汽压0.11 mmHg ( 25 ℃)
测定≥99%
形式liquid
solid
折射率n20/D 1.543 (lit.)
bp205 ℃ (lit.)
mp26-29 ℃ (lit.)
密度1.129 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查medicinal; woody; smoky; spicy; vanilla
application(s)flavors and fragrances
食品过敏原no known allergens
致敏芳香化合物no known allergens
SMILES stringCOc1ccccc1O
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
G5502Sigma-AldrichGuaiacoloxidation indicator720.51元/100 G;   937.12元/250 G;   1394.54元/500 G;   2069.1元/1 KG;   展开

产品说明

一般描述

愈创木酚是一种酚类化合物,可作为超氧自由基的清除剂。它由愈创木或木炭油木制成。愈创木酚作为不同增味剂的前体,如香草醛和烘焙咖啡。它被用作治疗牙髓和牙周组织的抗菌、镇痛和镇静药物。愈创木酚增强体内细胞增殖。

应用

Guaiacol已被使用:

  • 作为过氧化物酶的底物来确定其活性
  • 作为确定漆酶活性的底物
  • 作为过氧化物酶(POD)活性试验的试剂

包装

1 kg in glass bottle
100, 250, 500 g in glass bottle

生化/生理作用

愈创木酚和2,4,6-三氯苯甲醚是造成葡萄酒软木污染的原因。已经开发了一种用于提取和定量两种化合物的方法。
愈创木酚具有抑制前列腺素生物合成的性能,不会引起胃肠道系统的损害,与传统NSAID(非甾体类抗炎药)不同。

注意

在室温下可能是液体。

基本信息

线性分子式(CH3O)C6H4OH
分子量124.14
Beilstein508112
EC 号201-964-7
MDL编号MFCD00002185
PubChem化学物质编号24895212
NACRESNA.77

产品性质

蒸汽密度4.27 (vs air)
质量水平100
蒸汽压0.11 mmHg ( 25 ℃)
测定≥98.0%
形式liquid
solid
折射率n20/D 1.543 (lit.)
bp205 ℃ (lit.)
mp26-29 ℃ (lit.)
密度1.129 g/mL at 25 ℃ (lit.)
SMILES stringCOc1ccccc1O
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
PHR1136SupelcoGuaiacolPharmaceutical Secondary Standard; Certified Reference Material1162.78元/1.5 G;   展开

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards.

应用

These Secondary Standards are qualified as Certified Reference Materials. These are suitable for use in several analytical applications including but not limited to pharma release testing, pharma method development for qualitative and quantitative analyses, food and beverage quality control testing, and other calibration requirements.
Guaiacol may be used as a pharmaceutical reference standard for the determination of the analyte in pharmaceutical formulations by high performance liquid chromatography (HPLC) and electroanalytical techniques.

生化/生理作用

愈创木酚和2,4,6-三氯苯甲醚是造成葡萄酒软木污染的原因。已经开发了一种用于提取和定量两种化合物的方法。

分析说明

These secondary standards offer multi-traceability to the USP, EP (PhEur) and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAB3328 in the slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

线性分子式(CH3O)C6H4OH
分子量124.14
Beilstein508112
EC 号201-964-7
MDL编号MFCD00002185
PubChem化学物质编号329823156
NACRESNA.24

产品性质

质量水平300
等级certified reference material
pharmaceutical secondary standard
蒸汽密度4.27 (vs air)
蒸汽压0.11 mmHg ( 25 ℃)
CofAcurrent certificate can be downloaded
technique(s)HPLC: suitable
gas chromatography (GC): suitable
折射率n20/D 1.543 (lit.)
bp205 ℃ (lit.)
mp26-29 ℃ (lit.)
密度1.129 g/mL at 25 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
pharmaceutical (small molecule)
格式neat
药典可追溯性traceable to PhEur Y0000619
traceable to USP 1300004
储存温度2-8℃
SMILES stringCOc1ccccc1O
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
1300004USPGuaiacolUnited States Pharmacopeia (USP) Reference Standard3231.47元/1 G;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.
For further information and support please go to the website of the issuing Pharmacopoeia.

生化/生理作用

愈创木酚和2,4,6-三氯苯甲醚是造成葡萄酒软木污染的原因。已经开发了一种用于提取和定量两种化合物的方法。

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

Sales restrictions may apply.

基本信息

线性分子式(CH3O)C6H4OH
分子量124.14
Beilstein508112
MDL编号MFCD00002185
PubChem化学物质编号329749967
NACRESNA.24

产品性质

等级pharmaceutical primary standard
蒸汽密度4.27 (vs air)
蒸汽压0.11 mmHg ( 25 ℃)
manufacturer/tradenameUSP
折射率n20/D 1.543 (lit.)
bp205 ℃ (lit.)
mp26-29 ℃ (lit.)
密度1.129 g/mL at 25 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringCOc1ccccc1O
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P301 + P312 + P330 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)Not applicable
闪点(C)Not applicable
Y0000619GuaiacolEuropean Pharmacopoeia (EP) Reference Standard1572.27元/ ;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

生化/生理作用

愈创木酚和2,4,6-三氯苯甲醚是造成葡萄酒软木污染的原因。已经开发了一种用于提取和定量两种化合物的方法。

包装

Unit quantity: 1500 mg. Subject to change. The product is delivered as supplied by the issuing Pharmacopoeia. For the current unit quantity, please visit the EDQM reference substance catalogue.

注意

Please find SDS provided by EDQM here..

其他说明

Sales restrictions may apply.

基本信息

线性分子式(CH3O)C6H4OH
分子量124.14
Beilstein508112
MDL编号MFCD00002185
PubChem化学物质编号329831054
NACRESNA.24

产品性质

等级pharmaceutical primary standard
agencyEP Reference Standard
蒸汽密度4.27 (vs air)
蒸汽压0.11 mmHg ( 25 ℃)
manufacturer/tradenameEDQM
折射率n20/D 1.543 (lit.)
bp205 ℃ (lit.)
mp26-29 ℃ (lit.)
密度1.129 g/mL at 25 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringCOc1ccccc1O
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P301 + P312 + P330 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 1
闪点(F)179.6 °F - closed cup
闪点(C)82 ℃ - closed cup
8.18339Sigma-Aldrich2-Methoxyphenolfor synthesis187.51元/5 ML;   402.61元/250 ML;   展开

产品说明

分析说明

Identity (IR): passes test
Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.132 - 1.134
Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

基本信息

经验(实验)分子式C7H8O2
分子量124.14
MDL编号MFCD00002185
EC索引号201-964-7

产品性质

质量水平200
蒸汽压0.1 hPa ( 25 ℃)
测定≥98.0% (GC)
形式solid
自燃温度750 ℃
效能520 mg/kg LD50, oral (Rat)
4600 mg/kg LD50, skin (Rabbit)
pH值(酸碱度)5.4 (20 ℃, 10 g/L in H2O)
bp205 ℃/1013 hPa
mp28-32 ℃
转变温度flash point 82 ℃
密度1.13 g/cm3 at 21 ℃
储存温度2-30℃
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)194.0 °F - closed cup
闪点(C)90 ℃ - closed cup
V900769Sigma-AldrichGuaiacolVetec, reagent grade, 98%572.91元/500 G;   展开

产品说明

包装

500 g in glass bottle

生化/生理作用

愈创木酚和2,4,6-三氯苯甲醚是造成葡萄酒软木污染的原因。已经开发了一种用于提取和定量两种化合物的方法。

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

线性分子式(CH3O)C6H4OH
分子量124.14
Beilstein508112
EC 号201-964-7
MDL编号MFCD00002185
PubChem化学物质编号329830138

产品性质

等级reagent grade
蒸汽密度4.27 (vs air)
蒸汽压0.11 mmHg ( 25 ℃)
产品线Vetec
测定98%
折射率n20/D 1.543 (lit.)
bp205 ℃ (lit.)
mp26-29 ℃ (lit.)
密度1.129 g/mL at 25 ℃ (lit.)
SMILES stringCOc1ccccc1O
InChI1S/C7H8O2/c1-9-7-5-3-2-4-6(7)8/h2-5,8H,1H3
InChI keyLHGVFZTZFXWLCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319
预防措施声明P264 - P270 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)179.6 °F - closed cup
闪点(C)82 ℃ - closed cup
241127Fluorochem2-Methoxyphenol95%264元/25g;   440元/100g;   展开

基本信息

CAS Number90-05-1
MDL NumberMFCD00002185
Boiling Point205℃
Melting Point28.2-32℃
Density1.13

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
防范说明 P264: Wash hands and face thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P321: Specific treatment (see ' First aid. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P501: Dispose of contents/container to hazardous or special waste collection point..
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