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CAS: 89711-08-0
分子式: C7H13NO3
分子量: 159.18
英文名称: 
tert-butyl n-(2-oxoethyl)carbamate
推荐供应商
货号品牌产品名称规格包装、参考价格
N924289MACKLINN-Boc-2-氨基乙醛90%240元/1g;   720元/5g;   1700元/25g;   咨询
储存:−20°C,惰性气体,干燥
状态:无色或白色到黄色固体或液体
472654Sigma-AldrichN-Boc-2-aminoacetaldehyde95%1099.72元/1 G;   3532.05元/5 G;   6793.15元/25 G;   咨询

产品说明

一般描述

N -Boc-2-氨基乙醛是一种有机构件。与 Horner-Wadsworth-Emmons (HWE) 试剂反应,得到 γ-氨基丁酸 (GABA) 衍生的 α-酮酰胺/酯单元。

应用

使用最近报道的涉及甲醛和吡咯烷丙酸或二肽 L-Pro-β-Ala 催化的方案,该氨基醛的 α-亚甲基化以快速有效的方式进行。
也用于含 1,3-偶极环加成的吡咯烷的三组分合成。
N -Boc-2-氨基乙醛可用于以下用途:

  • 作为 (+)-负霉素全合成中的起始试剂。
  • ( E )-4-(( 叔 -丁氧基羰基)氨基)-2-烯酸乙酯的合成。
  • 2,2′ 的合成-联吡啶。

受保护的吡咯脯氨酸合成中的一个组成部分。

包装

1, 5, 25 g in glass bottle

基本信息

线性分子式HCOCH2NHCO2C(CH3)3
分子量159.18
MDL编号MFCD01321273
PubChem化学物质编号24870815
NACRESNA.22

产品性质

质量水平100
测定95%
折射率n20/D 1.455 (lit.)
储存温度−20℃
SMILES stringCC(C)(C)OC(=O)NCC=O
InChI1S/C7H13NO3/c1-7(2,3)11-6(10)8-4-5-9/h5H,4H2,1-3H3,(H,8,10)
InChI keyACNRTYKOPZDRCO-UHFFFAOYSA-N
Gene Informationhuman ... CTSK(1513)

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type N95 (US)
302648FluorochemN-Boc-2-Aminoacetaldehyde95%2002元/1g;   6138元/5g;   10846元/10g;   21956元/25g;   咨询

基本信息

CAS Number89711-08-0
MDL NumberMFCD01321273

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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