CAS 89343-06-6; (triisopropylsil yl)acetylene

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品牌

产品名称

规格

包装、参考价格

T823869

MACKLIN

三异丙基硅基乙炔

97%

28元/1ml; 45元/5ml; 189元/25ml; 740元/100ml; 3316元/500ml;

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储存：2~8℃
状态：无色到黄色液体
折射率：n20/D 1.4527(lit.)

T1683

TCI

Triisopropylsilylacetylene

>95.0%(GC)

685元/5ML; 2380元/25ML;

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基本信息

纯度/分析方法	>95.0%(GC)
分子式/分子量	C₁₁H₂₂Si = 182.38
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,湿气 (分解)
Reaxys-RN	3536241
PubChem物质ID	87577422
MDL编号	MFCD00075452

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 95.0 %

物性(参考值)

沸点	100 ℃/20 mmHg
闪点	56 ℃
比重	0.82
折射率	1.45

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H226 : 易燃液体和蒸气。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P233 : 保持容器密闭。 P243 : 采取防止静电放电的措施。 P241 : 使用防爆的电气/通风/照明设备。 P242 : 只能使用不产生火花的工具。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号	UN1993
类别	3
包装类别	III
监管条件代码(*)

511888

J&K

(Triisopropylsilyl)acetylene

97%

537元/5G; 2211元/25G;

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基本信息

分子式	C₁₁H₂₂Si
分子量	182.38
沸点	50-52
闪点	56
密度	0.813
折光率(n20D)	1.4527
MDL编码	MFCD00075452

安全信息

图形或危害标志
提示语	Warning
危险说明	H226 H315 H319 H335
防范说明	P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	III
WGK	3

H53405

Alfa Aesar

Triisopropylsilylacetylene

97%

680元/5g; 2766元/25g;

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应用
Triisopropylsilylacetylene is used as a reagent for the rhodium-catalyzed asymmetric alkylation of alpha, beta-unsaturated carbonyl compounds as well as in the synthesis of beta-alkynylated nitroalkanes. It is utilized in the preparation of bromoethynyl-triisopropyl-silane in the presence of the reagents such as N-bromo succinimide and silver nitrate. It is actively in involved in Sonogashira coupling reaction with 1-bromo-3-iodo-5-tertbutylbenzene.

备注
Incompatible with strong acids, strong bases and strong oxidizing agents.

基本信息

MDL
MFCD00075452

分子式
C₁₁H₂₂Si

分子量
182.38

沸点
50-52°/0.6mm

闪点
56°(133°F)

密度
0.813

折射率
1.4527

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with organic solvents.

Beilstein
3536241

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C36874

Alfa Aesar

(Triisopropylsilyl)acetylene

97%

1853元/5g; 5389元/25g;

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基本信息

Ref#
36874

MDL
75452

分子式
C11 H22 Si

分子量
182.38

闪点
56

密度
0.813

形态
Colorless to yellow liquid

安全信息

危险等级
3

包装组
III

979695

Amethyst

(Triisopropylsilyl)acetylene

97%, 用于合成

82元/1ML; 176元/5ML; 572元/25ML; 2069元/100ML;

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基本信息

分子式	C₁₁H₂₂Si
分子量	182.38
沸点	50-52
闪点	56
密度	0.813
折光率(n20D)	1.4527
MDL编码	MFCD00075452

安全信息

图形或危害标志
提示语	Warning
危险说明	H226 H315 H319 H335
防范说明	P261 P305+P351+P338
UN号码	1993
危险分类	3
包装等级	III
WGK	3

S18000

Fluorochem

(Triisopropylsilyl)acetylene

98%

528元/5g; 1364元/25g; 4400元/100g;

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基本信息

CAS Number	89343-06-6
MDL Number	MFCD00075452
Boiling Point	50-52℃ / 0.6 mmHg
Density	0.813

安全信息

图形或危害标志
危险性说明	H226: Flammable liquid and vapour. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use CO2, extinguishing powder or water jet for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P403 + P235: Store in a well-ventilated place. Keep cool. P405: Store locked up. P501: Dispose of contents/container to local regulations.