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CAS: 89-73-6
分子式: C7H7NO3
分子量: 153.14
熔点: 177-185℃
中文名称: 
水杨基羟肟酸
水杨酸肟酸
水杨醛肟酸
N-羟基邻羟基苯甲酰胺
N,2-二羟基苯甲酰胺
水杨羟肟酸
英文名称: 
salicylohydroxamic acid
2-hydroxybenzhydroxamic acid
2-hydroxybenzohydroxamic acid
n,2-dihydroxy-benzamid
n,2-dihydroxybenzamide
nsc 5088
o-hydroxybenzohydroxamic acid
salicylhydroxamic acid
salicylohydroximic acid
sha
Benzamide,N,2-dihydroxy-
展开更多英文名
性质描述: 白色针状结晶。熔点168℃(缓慢加热),176-178℃(急热)。溶于醇和醚,能升华。在空气中逐渐渐变红。
生产方法: 由邻羟基苯甲酸甲酯与盐酸羟胺在氢氧化钠存在下缩合,再经酸化而得。
用途: 医药中间体。化学分析沉淀剂,分析铋、铜、镍和铜的试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
S817724MACKLIN水杨羟肟酸99%31元/1g;   59元/5g;   210元/25g;   775元/100g;   3000元/500g;   展开
储存:室温
状态:白色到粉色到浅红色粉末
S0008TCISalicylhydroxamic Acid>98.0%(T)(HPLC)265元/5G;   510元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C7H7NO3 = 153.14
外观与形状(20℃)固体
Reaxys-RN1210520
PubChem物质ID87575639
SDBS (AIST Spectral DB)3460
Merck Index (14)8331
MDL编号MFCD00002110

技术规格

AppearanceWhite to Light red to Green powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点173 ℃(dec.)
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P405 : 存放处须加锁。

相关法规

RTECS#VO6870000
435450J&KSalicylhydroxamic Acid98%112元/5G;   437元/25G;   1440元/100G;   展开

基本信息

分子式C7H7NO3
分子量153.14
熔点177
MDL编码MFCD00002110
Merck14,8331
EINECS 编号201-934-3

安全信息

图形或危害标志
提示语Warning
危险说明H312
H315
H319
H332
H335
H351
防范说明P261
P280
P305+P351+P338
WGK3
RTECSVO6870000
TSCA
A11528Alfa AesarSalicylhydroxamic Acid99%550元/10g;   1063元/25g;   2072元/50g;   3975元/100g;   展开

应用
It is widely used for a variety of roles in biology and medicine as a chelating therapy. It inhibits bacterial or fungi growth by interfering with iron uptake. It is also active as a inhibitor of enzyme involved in tumour growths. These compounds are used as extractants for the separation of valuable metals or minerals including copper, lead, gold, other rare earth metals and kaolin. Hydroxamic acids are also used to produce corresponding isocyanates by dehydration followed by rearrangement reaction. It is also used as a common ligand utilized in the synthesis of metallacrowns.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible to Strong bases. Stable under normal conditions.

基本信息

MDL
MFCD00002110

EINECS
201-934-3

分子式
C7H7NO3

分子量
153.14

熔点
ca 170° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
It is soluble in water.

Beilstein
1210520

Merck
14,8331

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H341-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.Suspected of causing genetic defects.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38-68
Irritating to eyes, respiratory system and skin.Possible risk of irreversible effects.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

RTECS
VO6870000

TSCA

C13262Alfa AesarSalicylhydroxamic Acid99%474元/5g;   2143元/25g;   展开

基本信息

Ref#
13262

MDL
2110

分子式
C7 H7 N O3

分子量
153.14

形态
Cream or pink to pale brown powder

S607Sigma-AldrichSalicylhydroxamic Acid99%406.12元/5 G;   958.53元/25 G;   展开

产品说明

应用

水杨羟肟酸可用于:

  • 制备色谱用苯硼酸生物偶联物。
  • 作为合成Fe(III)、Cu(II)、Ni(II)和Zn(II)配合物的配体。
  • 在氧化物矿物浮选法离析中作为选择性捕收剂。 

包装

5 g in glass bottle
25 g in poly bottle

基本信息

线性分子式HOC6H4CONHOH
分子量153.14
EC 号201-934-3
MDL编号MFCD00002110
PubChem化学物质编号24899684
NACRESNA.22

产品性质

质量水平200
测定99%
mp177 ℃ (dec.) (lit.)
SMILES stringONC(=O)c1ccccc1O
InChI1S/C7H7NO3/c9-6-4-2-1-3-5(6)7(10)8-11/h1-4,9,11H,(H,8,10)
InChI keyHBROZNQEVUILML-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H312 + H332 - H315 - H319 - H335 - H351
预防措施声明P202 - P280 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Dermal - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
079691FluorochemSalicylhydroxamic Acid95%286元/5g;   506元/10g;   924元/25g;   展开

基本信息

CAS Number89-73-6
MDL NumberMFCD00002110
Melting Point173℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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