| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| B830601 | MACKLIN | 二氯二叔丁基-(4-二甲基氨基苯基)磷钯(II) | 98%，pd 15% | 91元/250mg; 317元/1g; 1000元/5g; 4680元/25g; | 咨询 |
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| B799339 | MACKLIN | 二氯二叔丁基-(4-二甲基氨基苯基)磷钯(II) | 95% | 173元/1g; 832元/5g; 3748元/25g; | 咨询 |
储存：室温, 惰性气体 状态：黄色到非常暗黄色和橙色到非常暗橙色粉末或块状 |
| B6255 | TCI | Bis[di-tert-butyl(4-dimethylaminophenyl)phosphine]dichloropalladium(II) | >98.0%(T) | 1990元/1G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(T) | | 分子式/分子量 | C32H56Cl2N2P2Pd = 708.08 | | 外观与形状(20℃) | 固体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气,加热 | | 包装和容器 | 1G-带有塑料内管的玻璃瓶 (查看图片) | | Reaxys-RN | 19190458 | | MDL编号 | MFCD09265123 |
技术规格 | Appearance | Light yellow to Yellow to Orange powder to crystal | | Purity(Chelometric Titration) | min. 98.0 % |
安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 789202 | J&K | Pd(amphos)Cl2 | 15% 钯, Umicore制造 | 625元/250MG; 1964元/1G; | 咨询 |
基本信息 | 分子式 | C32H56Cl2N2P2Pd | | 分子量 | 708.08 | | MDL编码 | MFCD09265123 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 46-0825 | Strem | Dichlorobis{[4-(N,N-dimethylamino)phenyl]di-t-butylphosphino}palladium(II) | min. 98% | 705元/250mg; 1990元/1g; 8460元/5g; 27000元/25g; | 咨询 |
Technical Notes: 1.Useful catalyst for the Suzuki Cross-Coupling of dioxolanylethyltrifluorborate and aryl/heteroaryl chlorides . 2.Useful catalyst for the Suzuki Cross-Coupling of benzyloxye thyltrifluoro borate . References: 1. Org. L ett., 2013, 15, 1536 2. J. Org Chem., 2012, 77, 10399. |
| 045511 | Alfa Aesar | Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) | Pd 15% | 3531元/1g; | 咨询 |
应用
Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides. 备注
Stable under normal conditions. Incompatible with oxidizing agents. 基本信息 MDL
MFCD09265123 分子式
C32H56Cl2N2P2Pd 分子量
708.08 灵敏度
Ambient temperatures. 形态
Crystalline 溶解性
Insoluble in water. GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste TSCA
否 |
| C44789 | Alfa Aesar | Bis[di-tert-butyl(4-dimethylaminophenyl)phosphine]dichloropalladium | 95% | 3162元/1g; 12455元/5g; | 咨询 |
基本信息 Ref#
44789 MDL
09265123 分子式
C32 H56 Cl2 N2 P2 Pd 分子量
708.07 |
| 678740 | Sigma-Aldrich | Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) | | 2494.42元/1 G; 6651.04元/5 G; 47497.1元/50 G; | 咨询 |
产品说明 应用 钯催化交叉偶联反应应用指南
用于与芳基卤(包括 5- 和 6-元杂芳基氯化物)进行 Suzuki-Miyaura 交叉偶联反应的高活性、空气稳定催化剂。 包装 1, 5, 50 g in glass bottle 基本信息 | 经验(实验)分子式 | C32H56Cl2N2P2Pd | | 分子量 | 708.07 | | MDL编号 | MFCD09265123 | | PubChem化学物质编号 | 24885453 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | reaction suitability | core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings | | 官能团 | phosphine | | SMILES string | Cl[Pd]Cl.CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C.CN(C)c2ccc(cc2)P(C(C)(C)C)C(C)(C)C | | InChI | 1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;/q;;;;+2/p-2 | | InChI key | DWOZNANUEDYIOF-UHFFFAOYSA-L |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 051339 | Fluorochem | Bis(4-(di-tert-Butylphosphanyl)-N,N-dimethylaniline)-palladium chloride | 98% | 2090元/1g; 6600元/5g; | 咨询 |
基本信息 | CAS Number | 887919-35-9 | | MDL Number | MFCD09265123 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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