CAS 885701-71-3; (11as)-(-)-10,11,12,13-四氢二茚并[7,1-de:1′,7′-fg][1,3,2] 二氧磷杂八环-5-苯氧基苯基-[(S)-1,1-螺二氢茚-7,7-二基]亚磷酸酯; (11as)-(-)-10,11,12,13-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy

CAS:

885701-71-3

分子式:

C₂₃H₁₉O₃P

分子量:

374.4

沸点:

454.8±45.0 °C

熔点:

102-103 °C

中文名称:

(11as)-(-)-10,11,12,13-四氢二茚并[7,1-de:1′,7′-fg][1,3,2] 二氧磷杂八环-5-苯氧基苯基-[(S)-1,1-螺二氢茚-7,7-二基]亚磷酸酯

英文名称:

(11as)-(-)-10,11,12,13-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy

推荐供应商

货号	品牌	产品名称	规格	包装、参考价格	详情
P906642	MACKLIN	(11AS)-(-)-10,11,12,13-四氢二茚并[7,1-DE:1′,7′-FG][1,3,2] 二氧磷杂八环-5-苯氧基苯基-[(S)-1,1-螺二氢茚-7,7-二基]亚磷酸酯	98%	587元/50mg;	展开
储存：2-8°C
15-5157	Strem	(11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy	min. 98%	1695元/100mg; 6780元/500mg;	展开
Technical Notes: 1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids. 2.Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids 3.Chiral ligands for rhodium-catalyzed arylation of a-ketoesters with arylboronic acids. 4.Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes . 5.Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-ß-arylenamides. References: 1.Org. Lett. 2006, 8, 1479. 2.Org. Lett. 2006, 8, 2567 . 3.Angew. Chem. Int. Ed. 2008, 47, 4351. 4.Chem. Sci. 2011, 2, 1135. 5.Tetrahedron 2012, 68, 7685.