| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| Z815426 | MACKLIN | (±)苄基氧基羰基-a-膦酰甘氨酸三甲酯 | 97% | 29元/1g; 32元/5g; 123元/25g; 466元/100g; 2250元/500g; | 展开 |
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| C2440 | TCI | N-Benzyloxycarbonyl-2-phosphonoglycine Trimethyl Ester | >98.0%(HPLC)(N) | 165元/1G; 450元/5G; | 展开 |
基本信息 | 纯度/分析方法 | >98.0%(HPLC)(N) | | 分子式/分子量 | C13H18NO7P = 331.26 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 4203148 | | PubChem物质ID | 125307266 | | SDBS (AIST Spectral DB) | 52878 | | MDL编号 | MFCD00043304 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(HPLC) | min. 98.0 area% | | Purity(with Total Nitrogen) | min. 98.0 % | | Melting point | 78.0 to 82.0 ℃ |
物性(参考值) |
| 155290 | J&K | (±)-Methyl-2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl) acetate | 97% | 157元/1G; 218元/5G; 785元/25G; | 展开 |
基本信息 | 分子式 | C13H18NO7P | | 分子量 | 331.26 | | 熔点 | 77-80 | | MDL编码 | MFCD00043304 | | Beilstein | 5764460 |
安全信息 | 图形或危害标志 |  | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P280
P302+P352
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| B22506 | Alfa Aesar | (±)-Benzyloxycarbonyl-alpha-phosphonoglycine trimethyl ester | 97% | 1006元/1g; 2166元/5g; 13311元/25g; | 展开 |
应用
(?±)-Z-α-Phosphonoglycine trimethyl ester is the starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes, the dehydroamino acids can be stereo selectively reduced to amino acids. 备注
Store in cool, dry place in tightly closed containers. Store away from strong oxidizing agents. 基本信息 MDL
MFCD00043304 分子式
C13H18NO7P 分子量
331.27 熔点
76-80° 灵敏度
Ambient temperatures. 形态
Powder 溶解性
Soluble in methanol. GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| C37004 | Alfa Aesar | (n)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetate | 95% | 3295元/5g; | 展开 |
基本信息 Ref#
37004 MDL
43304 分子式
C13 H18 N O7 P 分子量
331.26 |
| 376353 | Sigma-Aldrich | Z-α-Phosphonoglycine trimethyl ester | 97% | 678.93元/5 G; | 展开 |
产品说明 包装 5 g in glass bottle 应用 通过与醛发生 Wittig-Horner 反应合成 (Z)-脱氢氨基酸的原料；脱氢氨基酸可发生立体选择性还原反应生成氨基酸。 基本信息 | 线性分子式 | (CH3O)2P(O)CH(NHCO2CH2C6H5)CO2CH3 | | 分子量 | 331.26 | | Beilstein | 5764460 | | MDL编号 | MFCD00043304 | | PubChem化学物质编号 | 24863436 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 97% | | reaction suitability | reaction type: solution phase peptide synthesis | | mp | 77-80 ℃ (lit.) | | application(s) | peptide synthesis | | SMILES string | COC(=O)C(NC(=O)OCc1ccccc1)P(=O)(OC)OC | | InChI | 1S/C13H18NO7P/c1-18-12(15)11(22(17,19-2)20-3)14-13(16)21-9-10-7-5-4-6-8-10/h4-8,11H,9H2,1-3H3,(H,14,16) | | InChI key | GSYSFVSGPABNNL-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H302 | | 危险分类 | Acute Tox. 4 Oral | | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
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| 049045 | Fluorochem | Cbz-alpha-Phosphono-DL-glycine trimethyl ester | 97% | 220元/1g; 462元/5g; 748元/10g; 1210元/25g; 4356元/100g; | 展开 |
基本信息 | CAS Number | 88568-95-0 | | MDL Number | MFCD00043304 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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