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CAS: 88-19-7
分子式: C7H9NO2S
分子量: 171.22
沸点: 143℃(10
熔点: 156-145℃
中文名称: 
邻甲苯磺酰胺
2-甲苯磺酰胺
英文名称: 
O-Toluenseslfonamide
Benzenesulfonamide,2-methyl-
2-Toluene sulfonamide
2-methyl-Benzenesulfonamide
o-toluenesulfonamide
2-methylbenzenesulfonamide
2-methylbenzenesulphonamide
2-toluenesulfonamide
2-tolylsulfonamide
2-methyl-benzenesulfonamid
methyl-2 benzenesulfonamide
o-methylbenzenesulfonamide
o-methylbenzenesulphonamide
o-toluenesulphonamide
ortho-toluol-sulfonamid
toluene-2-sulfonamide
toluene-2-sulphonamide
o-Toluene sulfonamide
展开更多英文名
性质描述: 无色棱状结晶。熔点156℃。溶于乙醇和碱溶液,微溶于水和乙醚。
生产方法: 由邻甲苯磺酰氯与氨水和60℃反应2h,氨化生成邻甲苯磺酰胺。将反应物冷却,过滤,得到粗品,再经活性炭脱色、酸碱精制而得成品。
用途: 用于制造糖精、增塑剂、粘合剂、农药、医药等产品。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819143MACKLIN邻甲基苯磺胺98%34元/25g;   54元/100g;   148元/500g;   539元/2.5kg;   展开
储存:室温
状态:白色粉末或晶体
T0280TCIo-Toluenesulfonamide>98.0%(HPLC)(N)155元/25G;   760元/500G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)(N)
分子式/分子量C7H9NO2S = 171.21
外观与形状(20℃)固体
Reaxys-RN1102362
PubChem物质ID87576256
SDBS (AIST Spectral DB)2969
MDL编号MFCD00007934

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(with Total Nitrogen)min. 98.0 %
Melting point155.0 to 159.0 ℃

物性(参考值)

熔点155 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H319 : 造成严重眼刺激。
H351 : 怀疑致癌。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P405 : 存放处须加锁。

相关法规

RTECS#XT4900000
400336J&Ko-Toluenesulfonamide98%347元/100G;   1129元/500G;   展开

基本信息

分子式C7H9NO2S
分子量171.22
熔点156-158
MDL编码MFCD00007934
Beilstein1102362
EINECS 编号200-741-1

安全信息

图形或危害标志
提示语Warning
危险说明H319
H351
防范说明P281
P305+P351+P338
WGK2
RTECSXT5075000
B20544Alfa Aesaro-Toluenesulfonamide99%480元/10g;   1353元/50g;   展开

应用
o-Toluene sulfonamide was mainly produced as a chemical intermediate for the production of saccharin. A mixture of o-Toluene sulfonamide with the p-isomer is used as a plasticizer for hot -melt adhesives, a chemical intermediate for fluorescent pigments and a chemical intermediate for plasticizer resins. (S080800). Studies suggest that o-Toluene sulfonamide has potential mutagenic activity.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents, bases and acids.

基本信息

MDL
MFCD00007934

EINECS
201-808-0

分子式
C7H9NO2S

分子量
171.22

熔点
156°

沸点
210°/1mm

闪点
178°(352°F)

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in water (1.6 g/L at 25°C).

Beilstein
1102362

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H351-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.Suspected of causing cancer.May cause respiratory irritation.

Precautionary Statements
P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38-40
Irritating to eyes, respiratory system and skin.Limited evidence of a carcinogenic effect.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
XT4900000

TSCA

257990Sigma-Aldricho-Toluenesulfonamide99%314.77元/25 G;   1196.15元/100 G;   展开

产品说明

一般描述

甲苯磺酰胺是含有糖精的人造甜味物质中的一种主要杂质。 已报道可通过反相HPLC方法测定糖精和糖精钠中的甲苯磺酰胺。

包装

25, 100 g in poly bottle

其他说明

斯克里普斯代谢组学和质谱技术中心独立生成的串联质谱数据可在PDF 257990.pdf 中查看或下载。斯克里普斯代谢物组学和质谱技术中心的METLIN代谢物数据库中有测试代谢物。要了解更多信息,请访问sigma.com/metlin。

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
EC 号201-808-8
MDL编号MFCD00007934
PubChem化学物质编号24855621
NACRESNA.22

产品性质

质量水平200
测定99%
形式powder
mp156-158 ℃ (lit.)
SMILES stringCc1ccccc1S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-4-2-3-5-7(6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyYCMLQMDWSXFTIF-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H319 - H351
预防措施声明P201 - P305 + P351 + P338 - P308 + P313
危险分类Carc. 2 - Eye Irrit. 2
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
PHR1473Supelcoo-ToluenesulfonamidePharmaceutical Secondary Standard; Certified Reference Material1246.77元/500 MG;   展开

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards. o-Toluenesulfonamide is a major impurity in artificial sweetening substances containing saccharin.

应用

These Secondary Standards are qualified as Certified Reference Materials. These are suitable for use in several analytical applications including but not limited to pharma release testing, pharma method development for qualitative and quantitative analyses, food and beverage quality control testing, and other calibration requirements.
o-Toluenesulfonamide has been used as a pharmaceutical secondary standard for the determination of the analyte in pharmaceutical packaging systems using gas chromatography-flame ionization detection (GC-FID) and gas chromatography-mass spectrometry (GC-MS).

分析说明

These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAA3021 in the slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
EC 号201-808-8
MDL编号MFCD00007934
PubChem化学物质编号329823402

产品性质

质量水平300
等级certified reference material
pharmaceutical secondary standard
CofAcurrent certificate can be downloaded
包装pkg of 500 mg
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp156-158 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
药典可追溯性traceable to USP 1672010
储存温度2-30℃
SMILES stringCc1ccccc1S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-4-2-3-5-7(6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyYCMLQMDWSXFTIF-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H319 - H351
预防措施声明P201 - P305 + P351 + P338 - P308 + P313
危险分类Carc. 2 - Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
1672010USPo-ToluenesulfonamideUnited States Pharmacopeia (USP) Reference Standard5548.38元/200 MG;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.For further information and support please go to the website of the issuing Pharmacopoeia.

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

线性分子式CH3C6H4SO2NH2
分子量171.22
MDL编号MFCD00007934
PubChem化学物质编号329751350
NACRESNA.24

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameUSP
mp156-158 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
SMILES stringCc1ccccc1S(N)(=O)=O
InChI1S/C7H9NO2S/c1-6-4-2-3-5-7(6)11(8,9)10/h2-5H,1H3,(H2,8,9,10)
InChI keyYCMLQMDWSXFTIF-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H319 - H351
预防措施声明P201 - P305 + P351 + P338 - P308 + P313
危险分类Carc. 2 - Eye Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
403351Fluorochem2-Methylbenzene-1-sulphonamide97242元/25g;   616元/100g;   1474元/500g;   展开

基本信息

CAS Number88-19-7
MDL NumberMFCD00007934

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H351: Suspected of causing cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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