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CAS: 88-14-2
分子式: C5H4O3
分子量: 112.08
沸点: 230-232℃
熔点: 129-133℃
中文名称: 
2-糠酸
呋喃甲酸
焦粘液酸
β-呋喃甲酸
糠酸
2-呋喃甲酸
麸酸
2-呋喃羧酸
焦粘酸
英文名称: 
2-furoic acid
2-carboxyfuran
2-furancarboxylic acid
alpha-furancarboxylic acid
alpha-furoic acid
kyselina 2-furoova
kyselina pyroslizova
pyromucic acid
Furancarbonylic acid
Furan-2-carboxylic acid
α-Furancarbonsαure
2-Furancarbosylic acid
a-Furoic acid
furan carboxylic acid
展开更多英文名
性质描述: 白色单斜长梭形结晶。熔点133-134℃。沸点230-232℃,141-144℃(2.62kPa)。1g该品可溶于26ml冷水或4ml沸水,易溶于乙醇和乙醚。在130-140℃(6.65-8kPa)升华。
生产方法: 由糖醛经空气氧化而得。反应在45℃,强烈搅拌下进行。将反应物过滤回收催化剂氧化铜,滤液用50%硫酸酸化至pH为3-2.5,吸滤,水洗,烘干即得糠酸。将糠醛在中性或碱性介质中,用次氯酸钠或高锰酸钾氧化2h,再用盐酸酸化,也可制得糠酸,收率右达98%。
用途: 糠酸用于合成甲基呋喃,糠酰胺及糠酸酯和盐。在塑料工业中可用于增塑剂,热固性树脂等。在食品工业中用作防腐剂,也用作涂料添加剂,医药。香料等的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
F809683MACKLIN糠酸98%52元/100g;   156元/500g;   557元/2.5kg;   展开
储存:室温
状态:白色到棕褐色粉末
折射率:n20/D 1.531(lit.)
F797814MACKLIN糠酸10mM in DMSO185元/1ml;   展开
储存:-20°C
F0081TCI2-Furancarboxylic Acid>98.0%(GC)(T)165元/25G;   795元/500G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C5H4O3 = 112.08
外观与形状(20℃)固体
Reaxys-RN110149
PubChem物质ID87569882
SDBS (AIST Spectral DB)1
Merck Index (14)4307
MDL编号MFCD00003238

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point130.0 to 133.0 ℃

物性(参考值)

熔点132 ℃
沸点232 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#LV1763000
124066J&K2-Furoic Acid98%61元/25G;   190元/100G;   698元/500G;   展开

基本信息

分子式C5H4O3
分子量112.08
熔点128-132
沸点230-232
闪点137
MDL编码MFCD00003238
Beilstein110149
Merck14,4307
EINECS 编号201-803-0

安全信息

图形或危害标志
提示语Warning
危险说明H316
H320
H335
防范说明P281
P305+P351+P338
WGK3
RTECSLV1763000
TSCA
A11454Alfa Aesar2-Furoic Acid98%450元/100g;   1678元/500g;   展开

基本信息

MDL
MFCD00003238

EINECS
201-803-0

分子式
C5H4O3

分子量
112.08

熔点
127-132°

沸点
230-232° subl.

闪点
137°(278°F)

灵敏度
Ambient temperatures.

形态
Crystalline powder

Beilstein
110149

Merck
14,4307

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H318-H335
Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P280-P305+P351+P338-P337+P313
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If eye irritation persists: Get medical advice/attention.

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-36/37/39
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.

RTECS
LV1763000

TSCA

C11982Alfa Aesar2-Furoic Acid98%395元/5g;   898元/100g;   3242元/500g;   14048元/2.5kg;   展开

基本信息

Ref#
11982

MDL
3238

分子式
C5 H4 O3

分子量
112.08

闪点
137

57552Supelco2-Furoic Acidanalytical standard1145.96元/100 MG;   展开

产品说明

应用

有关合适的仪器技术的更多信息,请参阅产品的分析证书。想要获得更多支持,请联系技术服务部。

基本信息

经验(实验)分子式C5H4O3
分子量112.08
Beilstein110149
EC 号201-803-0
MDL编号MFCD00003238
PubChem化学物质编号329758318
NACRESNA.24

产品性质

质量水平100
等级analytical standard
测定≥97.0% (GC)
97.0-103.0% (T)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
bp230-232 ℃ (lit.)
mp128-132 ℃ (lit.)
application(s)cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
格式neat
SMILES stringOC(=O)c1ccco1
InChI1S/C5H4O3/c6-5(7)4-2-1-3-8-4/h1-3H,(H,6,7)
InChI keySMNDYUVBFMFKNZ-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Corr. 1C
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)282.7 °F - closed cup
闪点(C)139.3 ℃ - closed cup
F20505Sigma-Aldrich2-Furoic Acid98%269.97元/5 G;   357.49元/100 G;   1104.8元/500 G;   展开

产品说明

应用

2-糠酸可用于以下应用:

  • 合成一种单分子磁体,基于Mn11Gd2的高核异金属络合物。
  • 合成口服活性抗糖尿病氧钒基络合物,双(α-呋喃羧酸)氧钒(IV)。
  • 作为配体,用于合成发光4f-3d异金属一维配位聚合物。
  • 合成生物相容性多功能葡聚糖糠酸盐纳米球。

包装

5 g in glass bottle
100, 500 g in poly bottle

基本信息

经验(实验)分子式C5H4O3
分子量112.08
Beilstein110149
EC 号201-803-0
MDL编号MFCD00003238
PubChem化学物质编号24894811
NACRESNA.22

产品性质

质量水平100
测定98%
bp230-232 ℃ (lit.)
mp128-132 ℃ (lit.)
SMILES stringOC(=O)c1ccco1
InChI1S/C5H4O3/c6-5(7)4-2-1-3-8-4/h1-3H,(H,6,7)
InChI keySMNDYUVBFMFKNZ-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P260 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Corr. 1C
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)282.7 °F - closed cup
闪点(C)139.3 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
093393FluorochemFuran-2-carboxylic acid95%220元/100g;   展开

基本信息

CAS Number88-14-2
MDL NumberMFCD00003238
Melting Point130-133℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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