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CAS: 88-05-1
分子式: C9H13N
分子量: 135.21
沸点: 233℃
熔点: -5℃
中文名称: 
2,4,6-三甲基苯胺
均三甲苯胺
英文名称: 
Benzenamine,2,4,6-trimethyl-
2,4,6-Trimethyl-aniline
2,4,6-Trimethyl-phenylamine
aniline,2,4,6-trimethyl-
2,4,6-Trimethylaniline
2,4,6-trimethyl-Benzenamine
2,4,6-trimethyl-anilin
1-amino-2,4,6-trimethylbenzen
1-amino-2,4,6-trimethylbenzen (czech)
2,4,6-trimethylbenzenamine
2-amino-1,3,5-trimethylbenzene
2-aminomesitylene
aminomesitylene
2,4,6-trimethyl-benzenamin
mesidin
mesidine
mesitylamine
2-amino-mesitylen
展开更多英文名
性质描述: 淡黄色油状物。沸点232-233℃,108-110℃(1.47kPa),闪点96℃,相对密度0.963,折光率1.551,98%工业品的熔点-4--2℃。
生产方法: 将硫酸、硝酸配成混酸,与均三甲苯在10℃以下常压硝化4h,静置分层,放掉废酸。将得到的2,4,6-三甲基硝基苯、铁粉、盐酸和水按1:3.74:0.9:2.22(mol比)配料在100-105℃还原反应8h。然后从还原物蒸馏出粗均三甲苯胺,再用蒸馏提纯。
用途: 弱酸性染料普拉兰RAW的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T819072MACKLIN2,4,6-三甲基苯胺98%35元/25ml;   81元/100ml;   319元/500ml;   1350元/2.5L;   展开
储存:室温
状态:无色到黄色到棕色液体
折射率:n20/D 1.551(lit.)
T0467TCI2,4,6-Trimethylaniline>99.0%(GC)220元/25ML;   390元/100ML;   1150元/500ML;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C9H13N = 135.21
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN636559
PubChem物质ID87576410
SDBS (AIST Spectral DB)1643
MDL编号MFCD00007740

技术规格

AppearanceColorless to Yellow to Orange clear liquid
Purity(GC)min. 99.0 %
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

沸点230 ℃
闪点96 ℃
比重0.96
折射率1.55
水溶性不溶

安全信息

图形或危害标志
信号词危险
危险性说明H330 : 吸入致命。
H311 : 皮肤接触会中毒。
H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#BZ0700000

运输信息

UN编号UN2810
类别6.1
包装类别 II
监管条件代码(*)
504919J&K2,4,6-Trimethylaniline99%88元/25G;   264元/100G;   1017元/500G;   展开

基本信息

分子式C9H13N
分子量135.21
沸点233
闪点96
密度0.963
折光率(n20D)1.5510
MDL编码MFCD00007740
Beilstein636559
EINECS 编号201-794-3

安全信息

图形或危害标志
提示语Danger
危险说明H302
H312
H315
H319
H330
防范说明P260
P280
P284
P305+P351+P338
P310
UN号码2810
危险分类6.1
包装等级II
WGK3
RTECSBZ0700000
TSCA
A13049Alfa Aesar2,4,6-Trimethylaniline98%497元/100g;   2124元/500g;   9601元/2500g;   展开

应用
2,4,6-Trimethylaniline is useful for the preparation of Grubbs' catalyst. It is used as a precursor to dyes. It undergoes condensation reaction with glyoxal to prepare glyoxal-bis(mesitylimine). It is also involved in the preparation of 1,3-diketimines ligands by condensation with 1,3-diketones. Further, it is used for the production of Acid Blue 129 dye, which is useful in histochemistry studies. In addition to this, it serves as a building block to various bulky ligands.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00007740

EINECS
201-794-3

分子式
C9H13N

分子量
135.21

熔点
-5°

沸点
232-234°

闪点
96°(204°F)

密度
0.962

折射率
1.5510

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Slightly miscible with carbon tetrachloride. Immiscible with water.

Beilstein
636559

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
21/22-23-36/37/38
Harmful in contact with skin and if swallowed.Toxic by inhalation.Irritating to eyes, respiratory system and skin.

安全等级
26-28-36/37-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
BZ0700000

TSCA

C15796Alfa Aesar2,4,6-Trimethylaniline97%739元/100g;   2894元/500g;   10747元/2.5kg;   展开

基本信息

Ref#
15796

MDL
7740

分子式
C9 H13 N

分子量
135.21

闪点
96

密度
0.96

形态
Liquid

安全信息

危险等级
6.1

包装组
III

132179Sigma-Aldrich2,4,6-Trimethylaniline98%242.42元/25 ML;   476.6元/100 ML;   展开

基本信息

线性分子式(CH3)3C6H2NH2
分子量135.21
Beilstein636559
EC 号201-794-3
MDL编号MFCD00007740
PubChem化学物质编号24847550
NACRESNA.22

产品性质

质量水平200
测定98%
形式liquid
折射率n20/D 1.551 (lit.)
bp108-110 ℃/11 mmHg (lit.)
233 ℃ (lit.)
密度0.963 g/mL at 25 ℃ (lit.)
SMILES stringCc1cc(C)c(N)c(C)c1
InChI1S/C9H13N/c1-6-4-7(2)9(10)8(3)5-6/h4-5H,10H2,1-3H3
InChI keyKWVPRPSXBZNOHS-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H302 + H312 - H315 - H319 - H330
预防措施声明P260 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)204.8 °F - closed cup
闪点(C)96 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
236741Fluorochem2,4,6-Trimethylaniline95%220元/1g;   352元/25g;   880元/100ml;   2332元/500g;   展开

基本信息

CAS Number88-05-1
MDL NumberMFCD00007740
Density0.965

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H330: Fatal if inhaled.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P284: Wear respiratory protection. .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P320: Specific treatment is urgent (see . on this label).
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P361: Remove/Take off immediately all contaminated clothing.
P363: Wash contaminated clothing before reuse.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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