CAS 878111-17-2; (<i>s</i>)-(+)-3,3′-双(3,5-双(三氟甲基)苯基)-1,1′-联萘-2,2′-二基磷酸氢酯

CAS:

878111-17-2

分子式:

C₃₆H₁₇F₁₂O₄P

分子量:

772.5

熔点:

171-177°C

中文名称:

(s)-(+)-3,3′-双(3,5-双(三氟甲基)苯基)-1,1′-联萘-2,2′-二基磷酸氢酯

(s)-(+)-3,3′-bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

(11bs)-2,6-bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-dinaphtho[2,1-d:1′,2′-f]-1,3,2-dioxaphosphepin 4-oxide

(s)-3,3′-bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol cyclic monophosphate

(s)-3,3′-双(3,5-双(三氟甲基)苯基)-1,1′-二-2-萘酚环一磷酸酯

(11bs)-2,6-双[3,5-双(三氟甲基)苯基]-4-羟基-二萘并[2,1-d:1′,2′-f]-1,3,2-二噁磷杂庚英 4-氧化物

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

S854196

MACKLIN

(S)-3,3'-双[3,5-二(三氟甲基)苯基]-1,1'-联萘酚膦酸酯

98%

216元/50mg; 316元/100mg;

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储存：室温,干燥

15-1367

Strem

(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

98%, , (99% ee)

2040元/100mg;

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Technical Note:

1.Friedel-Crafts Alkylation: Chiral phosphoric acids were used as catalysts for the Friedel-Crafts alkylations of indolyl enones while both a ruthenium complex and chiral phosphoric acids were used as catalysts for sequential olefin cross-metathesis and Friedel-Crafts alkylations of allyloxymethyl or allylaminomethyl indoles and enones.

Reference:

1. Angew. Chem. Int. Ed., 2009, 48, 7428-7431.

Y17982

Alfa Aesar

(S)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-2,2'-dihydroxy-

930元/50mg; 1273元/100mg;

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基本信息

分子量
772.47

681520

Sigma-Aldrich

(S)-(+)-3,3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate

95%

1128.43元/100 MG;

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基本信息

经验(实验)分子式	C₃₆H₁₇F₁₂O₄P
分子量	772.47
PubChem化学物质编号	24885639
NACRES	NA.22

产品性质

测定	95%
mp	171-177 ℃
SMILES string	CC(C)(C)OC(=O)N1CCc2cccc(C(O)=O)c12
InChI	1S/C14H17NO4/c1-14(2,3)19-13(18)15-8-7-9-5-4-6-10(11(9)15)12(16)17/h4-6H,7-8H2,1-3H3,(H,16,17)
InChI key	SUAMIYWLXFROHE-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves