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CAS: 87199-15-3
分子式: C7H9BO3
分子量: 151.95
熔点: 95-99℃
中文名称: 
3-(羟基甲基)苯硼酸
3-羟甲基苯硼酸
英文名称: 
3-Hydroxymethylphenylboronic acid
(3-hydroxymethylphenyl)boronic acid
3-(Hydroxymethyl)phenylboronic acid
3-(Hydroxymethyl)benzeneboronic acid
推荐供应商
货号品牌产品名称规格包装、参考价格详情
H810777MACKLIN3-羟甲基苯硼酸>98%32元/1g;   52元/5g;   205元/25g;   805元/100g;   展开
储存:室温
H1244TCI3-(Hydroxymethyl)phenylboronic Acid (contains varying amounts of Anhydride)120元/1G;   390元/5G;   展开

基本信息

分子式/分子量C7H9BO3 = 151.96
外观与形状(20℃)固体
Reaxys-RN8832019
PubChem物质ID87560197
MDL编号MFCD01317846

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Neutralization titration)97.0 to 113.0 %

物性(参考值)

熔点99 ℃
水溶性微溶
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
235050J&K3-(Hydroxymethyl)phenylboronic acid98%164元/1G;   513元/5G;   展开

基本信息

分子式C7H9BO3
分子量151.96
熔点95-99
MDL编码MFCD01317846
Beilstein8832019

安全信息

防范说明P262
WGK3
TSCA
L15193Alfa Aesar3-(Hydroxymethyl)benzeneboronic Acid98%1116元/1g;   3226元/5g;   展开

应用
Reactant used for copper-mediated trifluoromethylation, copper-catalyzed transformations from arylboronic acids in water, Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylate. Reactant involved in the synthesis of biologically active molecules including Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions, HIV protease inhibitors with antiviral activity against drug-resistant viruses, Pyrrole derivatives for use as PDE4B inhibitors.

备注
Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

基本信息

MDL
MFCD01317846

分子式
C7H9BO3

分子量
151.96

熔点
93-98°

灵敏度
Ambient temperatures.

溶解性
Soluble in water.

Beilstein
8832019

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

512834Sigma-Aldrich3-(Hydroxymethyl)phenylboronic acid≥95%994.52元/10 G;   展开

产品说明

应用

Reactant involved in:

  • Copper-mediated trifluoromethylation
  • Copper-catalyzed transformations from arylboronic acids in water
  • Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylate

Reactant involved in the synthesis of biologically active molecules including:
  • Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions
  • HIV protease inhibitors with antiviral activity against drug-resistant viruses
  • Pyrrole derivatives for use as PDE4B inhibitors

包装

1, 10 g in glass bottle

其他说明

含有不定量的酸酐

基本信息

线性分子式HOCH2C6H4B(OH)2
分子量151.96
MDL编号MFCD01317846
PubChem化学物质编号24873658
NACRESNA.22

产品性质

质量水平100
测定≥95%
mp95-99 ℃ (lit.)
SMILES stringOCc1cccc(c1)B(O)O
InChI1S/C7H9BO3/c9-5-6-2-1-3-7(4-6)8(10)11/h1-4,9-11H,5H2
InChI keyHGTDLKXUWVKLQX-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
016258Fluorochem3-(Hydroxymethyl)phenylboronic acid98%220元/1g;   220元/5g;   374元/10g;   770元/25g;   2970元/100g;   11858元/500g;   展开

基本信息

CAS Number87199-15-3
MDL NumberMFCD01317846
Melting Point95-99℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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