基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 : 吞咽有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。

相关法规

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	1
RTECS	OO1100000
TSCA	是

应用
Diethyl ethoxymethylenemalonate is used for synthesis of pyrido[3,2-e]pyrimido[1,2-c]pyrimidines. Initially, it was used to monitor lysine decarboxylase activity. It is useful in the determination of amino acids by precolumn derivatization by using reversed-phase high-performance liquid chromatography (HPLC). It plays an important role in the Gould-Jacobs reaction to prepare quinolines. For example, anile reacts with this reagent to give 4-hydroxyquinoline. It acts as an intermediate in the production of flumequine, which is a fluoroquinolone antibiotic.

备注
Incompatible with acids, bases, oxidizing agents and reducing agents.

基本信息

MDL
MFCD00009148

EINECS
201-725-7

分子式
C₁₀H₁₆O₅

分子量
216.23

熔点
-33°

沸点
136-139°/10mm

闪点
144°(291°F)

密度
1.080

折射率
1.4620

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with chloroform, dichloromethane and methanol. Immiscible with water.

Beilstein
880058

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H334-H317
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause an allergic skin reaction.

Precautionary Statements
P284-P261-P280a-P305+P351+P338-P304+P340-P501a
Wear respiratory protection.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/38-42/43
Harmful if swallowed.Irritating to eyes and skin.May cause sensitization by inhalation and skin contact.

安全等级
23-24-26-36/37-45
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).Avoid contact with skin.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
OO1100000

TSCA
是

基本信息

Ref#
11434

MDL
9148

分子式
C10 H16 O5

分子量
216.23

闪点
144

密度
1.08

形态
Liquid

产品说明

应用

二乙基乙氧基甲基烯丙基酯可用作合成嘧啶酮、噻唑并嘧啶、噻唑并嘧啶酮、三唑并 [1,5-a] 嘧啶、嘧啶并 [2,1-b] 苯并噻唑和 3-氨基-5-氧代异恶唑烷-4-羧酸乙酯衍生物的前体。

包装

100, 500 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H302 - H315 - H317 - H319 - H410
预防措施声明	P261 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1A
储存分类代码	10 - Combustible liquids
WGK	WGK 1
闪点(F)	291.2 °F - closed cup
闪点(C)	144 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .