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CAS: 866641-66-9
分子式: C22H30AuF6NPSb
分子量: 772.17
熔点: 198-203 °C (D)
中文名称: 
2-(二叔丁基膦基)-1,1'-联苯(乙腈)金(i)六氟锑酸盐
英文名称: 
2-(di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(i) hexafluoroantimonate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
A801427MACKLIN(乙腈)[(2-联苯)二叔丁基膦]六氟锑酸金(I)98%721元/100mg;   984元/250mg;   2990元/1g;   展开
储存:2-8°C, 惰性气体保存
状态:白色到米黄色粉末或晶体
79-0352Strem2-(Di-t-butylphosphino))-1,1'-biphenyl(acetonitrile)gold(I) hexafluoroantimonate99%1530元/250mg;   4605元/1g;   展开

Technical Notes:

1.Goid catalyst used in the regio -and stereoselective synthesis of functionalized benzoboxepines.

2.Gold catalyst used in the cyclization reactions of o-(buta-1.,3-diyn-1-yl-)-substituted N-aryl ureas

3.Gold catalyst used in the cycloisomerization of 1,7 -enyne esters to structurally diverse cis-tetrahydropyridin-4-ylketones

4.Catalyst used in the synthesis of coum arin- containing natural products.

5. Catalyst used in the synthesis of benzo4, 5imidazo1,2-aquinazolinones.

References: 1.Org. Lett, 2012, 14, 4742. 2.Org. Lett.,2013,15,2616 3.J. Org. Chem., 2013, 78, 3183. 4.J.Org.Chem.,2013,78,9876 5.J. Org. Chem., 2013, 78, 4312.
697575Sigma-Aldrich(Acetonitrile)[(2-biphenyl)di-tert-butylphosphine]gold(I) hexafluoroantimonate1245.97元/250 MG;   3825.46元/1 G;   展开

产品说明

应用

Gold Catalysts — 21st Century ′Gold Rush′

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

经验(实验)分子式C22H30AuF6NPSb
分子量772.17
MDL编号MFCD11045449
PubChem化学物质编号329761933
NACRESNA.22

产品性质

质量水平100
reaction suitabilitycore: gold
reagent type: catalyst
mp198-203 ℃ (D)
SMILES string[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.CC(C)(C)P(c1ccccc1-c2ccccc2)C(C)(C)C
InChI1S/C20H27P.C2H3N.Au.6FH.Sb/c1-19(2,3)21(20(4,5)6)18-15-11-10-14-17(18)16-12-8-7-9-13-16;1-2-3;;;;;;;;/h7-15H,1-6H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI keyADQOZROJMVWPRI-UHFFFAOYSA-H

安全信息

象形图GHS07GHS09
警示用语:Warning
危险声明H302 + H332 - H411
预防措施声明P273 - P301 + P312 + P330 - P304 + P340 + P312
危险分类Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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